Physical Sciences and Mathematics Commons^™

An Investigation Of Some Free Radicals.|Ni.|Pdecomposition Of Nitrosyl Disulfonate Ion In Polar Non-Aqueous Solvents.|Nii.|Preaction Between 2,2-Diphenyl -1- Picryl Hydrazyl And Nitrosyl Disulfonate Ion Free Radicals, Janan Mary Hayes

Theses and Dissertations

Part I reports the stud y of the decomposition of nitrosyl disulfonate ion in DMSO, acetonitrile, and dichloromethane. A multi-step mechanism involving sulfite ion, sulfite ion radical, and nitrosyl monosulfonate radical as intermediates is proposed. The products of the decomposition are nitrosonium ion, hydroxylamine disulfonate ion, and hydroxylamine trisulfonate ion. A competitive chain reaction was observed when the decomposition occurred in DMSO. The chain reaction was insignificant in carefully dried acetonitrile and dichloromethane. Part II reports the study of the reaction between 2,2-diphenyl-1-picryl hydrazyl (DPPH) and nitrosyl disulfonate ion. Product analysis and kinetic data obtained from stopped-flow procedures suggest that …

Studies Of Pig Brain Thiamin Pyrophosphokinase, James Weldon Peterson

Theses and Dissertations

Pig brain thiamin pyrophosphokinase (TPK) (ATP: thiamin pyrophosphotransferase, EC 2.7.6.2) was purified 260-fold over extracts of brain acetone powder. The purification was followed using a direct, radiometric assay. As determined in an analytical ultracentrifuge and by disc-gel electrophoresis, the most highly purified enzyme preparations were not homogeneous. The purified enzyme has a broad pH optimum extending from 8.3 to 9.3 in phosphate-glycylglycine buffer. It has an isoelectric point at about pH 4.2. For optimal enzymatic activity, the ratio of magnesium to ATP must be 0.6. Any deviation from this ratio causes a rapid drop in enzymatic activity. A study of …

The Thermal Decomposition Of 2,2'-Azoisobutane, Mervin Dewain Atwood

Theses and Dissertations

Nitrogen, isobutane, isobutylene and 2,2,3,3-tetramethylbutane are the only products found in the thermal decomposition of 2,2'-azoisobutane. They are the results of the direct free radical dimerization and disproportionation. Ratio of the rate constants of disproportionation to dimerization was found to be 1.9 at 268°C and 4.5% azobutane in helium. This compared with Blackham and Eatough's value of 1.4 at 243°C and 3.6 at 290°C with 4% azobutane in helium. The ratio of the disproportionation to dimerization increased with an increase in temperature. A change in contact time affected the ratio at lower reaction temperatures but had little effect on it …

Solid-Liquid Phase Equilibria Studies :|Bi. Several Charge Transfer Systems ; Ii. A Metallic System ; Iii. A Liquid Crystal, Dee Edward Oyler

Theses and Dissertations

Solid-liquid phase equilibria studies were used to investigate possible compound formation in solutions of (i) N,N-dimethylformamide (DMF) and (ii) N,N-dimethylacetamide (DMA) with a series of halogenated hydrocarbons that were selected to give a wide range of acceptor properties. Solid 1:1 intermolecular compounds were identified from solutions of (i) DMF and (ii) DMA with CCl_4, CBrCl_3, and C_6H_5CCl_3. The intermolecular compounds (DMF)_2•CCl_4 and (DMF)_2•CBrCl_3 were also found. The results suggest charge transfer from DMF or DMA to the chlorine atoms of the acceptor molecule as the process for compound formation. Thermal methods were used to determine with high precision the solid-liquid …

Solid-Liquid Phase Equilibria Of The Potassium-Rubidium And Rubidium-Cesium Alloy Systems, Elisabeth M. Delawarde

Theses and Dissertations

Thermal methods of high precision were used to determine the solid-liquid phase equilibria diagrams for the potassium-rubidium and the rubidium-cesium systems. Both form minima in the liquidus curves occurring at 307.00° K with 0.667 mole fraction rubidium in the potassium-rubidium system and 282.85° K with 0.530 mole fraction cesium in the rubidium-cesium system. In the potassium-rubidium system, the liquidus and solidus points are very close together, giving a very narrow temperature range for the two phase region. The freezing point minimum in the potassium-rubidium system occurs at 0.667 mole fraction rubidium, suggesting the possible formation of a KRb2 intermetallic compound.

Eutrophication Of Small Lakes, Lynn T. Kenison

Theses and Dissertations

An estimate was made to determine the amount of nitrate and phosphate entering Utah Lake in 1968. To make this estimate, the flow data for 1968 and the nitrate and phosphate concentrations for 1970 were used. This was done because of the lack of information. The results show that the total nitrate added to Utah Lake in 1968 was 7,638,000 pounds. The total phosphate added was 1,740,200 pounds. Of this amount, 12,4 per cent of the nitrate and 18.0 per cent of the phosphate was released from the lake through the Jordan River. The rest remained in the lake to …

A Calorimetric Study Of Metal Ion Cyclic Polyether Interaction :|Bi. Cation Binding Properties Of Macrocyclic Polyethers In Aqueous Solution As A Function Of Temperature ; Ii. Effect Of Solvent Dielectric Constant On The Binding Properties Of Cyclic Polyethers For Na[Superscript +] And K[Superscript +], Dennis Pershing Nelson

Theses and Dissertations

The complexation properties of the two isomers of the cyclic polyether dicyclohexyl-18-crown-6 are examined in aqueous solution for a series of metal ions at various reaction temperatures. The results are discussed in terms of size relationships and salvation characteristics of both polyether and metal ions. ΔCp° values are determined from the temperature dependence of the ΔH° values. A discussion of the errors involved in the determination of ΔH° from the temperature dependence of log K values is also included. Comparisons are made between the results of this study and those of a similar study by H. K. Frensdorff, E. I. …

The Roles Of Chlorine Azide In Chemical Lasers, Walter Wood Rice

Theses and Dissertations

ClN_3 was photolyzed in various gas mixtures to transform its chemical energy into laser radiation. Reaction mechanisms, energy distribution in reaction products, and relative reaction rates were deduced from the laser emission. Flash photolysis of ClN_3-H_2 mixtures produced HCl laser emission; however, due to a narrow range of operating conditions and many competing reactions, the laser output was less than that obtained from comparable Cl_2-H_2 mixtures. The rate constants for H + ClN_3 —> HCl* (v=n) + N_3 were determined to be 0.45 ± 0.05 of the corresponding rate constants for H + Cl_2 —> HCl* (v=n) + Cl. Chlorine …

An Easy Access Interactive Statistical System For Use And Training In Biometry, Amos Addison Slaymaker Jr.

Theses and Dissertations

One of the most important tools of the applied statistician is the digital computer. It is natural, therefore, for the instructor in applied statistics to want his students to become familiar with the use of computers. If his students are going to get actual experience in using a computer for statistical analysis, he often has only two alternatives. The students can be required to write their own statistical programs or they can use programs already available through a computer facility.

If the course is to be taught such that each student is responsible for his own programs, the instructor must …

Group Sequential Methods For Clinical Trials Applied To The Logistic Regression Model, Joy Duci Mele

Theses and Dissertations

The objectives of this thesis are

1. to provide a comprehensive guide to using Pocock's group sequential method for clinical trials and

2. to show by computer simulations that the group sequential method is appropriate when using the logistic regression model.

In section 1.2, clinical trials are defined with an emphasis on Phase III clinical trials. The primary intent of sections 1.2 and 1.3 is to describe clinical trial characteristics which suggest that interim analyses are desirable. In section 1.4, it is shown that interim analyses should not consist of performing the usual significance tests. Chapter 1, then, describes the …

Geology Of Mclean County, North Dakota, John P. Bluemle

Theses and Dissertations

McLean County, in west-central North Dakota on the east side of the Williston Basin, is covered by 8,500 to 13,000 feet of Paleozoic, Mesozoic, and Cenozoic rocks, which dip to the west at low angles. The Tertiary Tongue River and Sentinel Butte Formations are widely exposed in McLean County, and the Tertiary Cannonball Formation is exposed in a few places. Glacial drift, assigned to a new formation, the Coleharbor Formation, occurs throughout the county and reaches a maximum thickness of at least 400 feet in certain preglacial valleys.

The eastern part of McLean County, part of the Missouri Coteau, is …

Quantitative Geomorphology And Hydrology Of The Cass River Basin, New Zealand, Frank J. Schulte

Theses and Dissertations

The Cass River drainage basin is in the Southern Alps in the central part of the South Island of New Zealand. The Alps are composed of complexly folded greywacke which is still actively rising. The basin has been modified by several glacial advances during Pleistocene time.

The Cass basin has a temperate climate characterized by a steep precipitation gradient. Its vegetation includes plants of the forest grassland, shrubland, swamp, rock, and river-bed associations.

The Cass basin may be divided into four geomorphic areas: bedrock areas, high-angle fans, moderate-angle fans, and a low-angle fan. The bedrock areas consist of fractured greywacke; …

Gastropoda Of The Fox Hills Formation (Maestrichtian) Of North Dakota, J. Mark Erickson

Theses and Dissertations

The Fox Hills Formation (Maestrichtian, Upper Cretaceous) in North Dakota contains a gastropod fauna of thirty-seven species. Five species, loganensis n. sp., Piestochilus feldmanni n. sp., Hercorhyncus (Hercorhyncus) hollandi n. sp., cvancarai n. sp., and Cancellaria siouxensis n. sp. , and genus, Dakotia, are newly described. Twenty-four genera in eighteen families representing four orders and two subclasses of Gastropoda are present. Eleven species in a like number of genera are newly reported from the Fox Hills For mation. Goniocylichna bisculnturata and rectilabrum occur in common with the gastropod fauna of the Ripley Formation of the Mississippi Embayment, which has the …

Concretions And Nodules In The Hell Creek Formation, Southwestern North Dakota, Gerald H. Groenwold

Theses and Dissertations

The Hell Creek Formation (Upper Cretaceous) in southwestern North Dakota consists of lagoonal and floodplain deposits and contains abundant concretions and nodules. Representative specimens of the concretions and nodules and their corresponding enclosing sediments were analyzed by thin section and by quantitative and qualitative x-ray diffraction methods.

Fourteen types of concretions and three types of nodules, classified according to shape and composition, have thus been defined. Concretionary types include calcareous sandstone lenses, “logs”, and irregular masses; sideritic sandstone lenses and irregular masses; calcareous and sideritic lignitic sandstone lenses; bone-cored rounded masses; coprolite-cored masses; jarosite bodies; pyrite spheres; baritic sandstone lenses; …

Groundwater Flow, Hydrochemistry, And Uranium Deposition In The Powder River Basin, Wyoming, J. Ladd Hagmaier

Theses and Dissertations

The relation between regional groundwater flow, hydrochemistry, and uranium distribution in the Powder River Basin indicates that uranium was deposited during the Tertiary Period in groundwater recharge areas where the groundwater changed from a sulfate-bicarbonate water to a bicarbonate-rich water.

The regional recharge and discharge areas of present-day groundwater-flow systems have about the same location as the recharge and discharge areas of the Tertiary groundwater-flow systems. The present-day groundwater is recharged in the eastern, western, and especially in the southern margins of the basin and is discharged in the valley of the Powder River, especially in the north. Flow nets …

Erosion And Sedimentation In Lake Ashtabula, Southeastern North Dakota, Darryll T. Pederson

Theses and Dissertations

Erosion along the shore of Lake Ashtabula and nearshore and offshore sedimentation were studied from May 1969 to December 1970. The lake, located in the southeastern part of North Dakota, was formed when the Baldhill Dam stopped the flow of the Sheyenne River in 1950. Maximum depth of the lake is 45 feet in the inundated river channel immediately above the dam. The lake is 27 miles long and ranges in width from 1/3 to 1/2 mile.

Shoreline erosion, measured at stations located at 100-foot intervals around the margins of the lake, was found to be a major source of …

The Petroleum Geology Of The Midale Subinterval In North Central North Dakota, Kent A. Johnson

Theses and Dissertations

The Mississippian Midale subinterval is the basal unit of the Ratcliffe interval of the Madison Group. The Midale subinterval, an important petroleum producing unit in North Dakota, is a dolomitized limestone which is approximately 40 feet thick. A detailed study of 17 oil fields in north central North Dakota was conducted to determine the petroleum geology of the Midale subinterval. The study was done with the use of 563 mechanical well logs and core samples from 10 wells.

The anhydrite and dolomite units of the Rival subinterval, which underlie the Midale, and the Ratcliffe interval, which over lies the Midale, …

Origin And Distribution Of Selenium In The Upper Cretaceous Niobrara And Pierre Formations, Northeastern North Dakota, Robert M. Novak

Theses and Dissertations

High concentrations of selenium, often as much as 28 ppm, have been found in the bentonitic zones near the contact of the Niobrara and Pierre Formations of Cretaceous age in northeastern North Dakota. A 64-foot section in the Pembina Hills area reveals that the highest selenium content occurs in shale and marlstone beds adjacent to the bentonite beds which, themselves, contain comparatively little selenium. Higher concentrations of selenium were found in the brown shale than in the black, with a small variation in color making a big difference in selenium content.

The selenium content of the shale and marlstone drops …

Attitudes Concerning Birth Control And Abortion As Related To Lds Religiosity Of Brigham Young University Students, Erlend D. Peterson

Theses and Dissertations

This study was an analysis of the relationship between LDS religiosity of college students and their attitudes concerning birth control and abortion.

The respondents in this research were LDS college students attending Brigham Young University Fall Semester 1970. Goodman and Kruskal's gamma and a difference of means test were used to measure association and difference to determine the statistical significance of the responses as related to religiosity and attitudes concerning birth control and abortion.

The results of the study showed that (1) there was a positive relationship between conservative attitudes toward birth control and abortion and one's degree of measured …