Physical Sciences and Mathematics Commons^™

Modeling Spatial Distributions Of Tidal Marsh Blue Carbon Using Morphometric Parameters From Lidar, Bonnie Turek

Masters Theses

Tidal marshes serve as important “blue carbon” ecosystems that accrete large amounts of carbon with limited area. While much attention has been paid to the spatial variability of sedimentation within salt marshes, less work has been done to characterize spatial variability in marsh carbon density. Driven by tidal inundation, surface topography, and sediment supply, soil properties in marshes vary spatially with several parameters, including marsh platform elevation and proximity to the marsh edge and tidal creek network. We used lidar to extract these morphometric parameters from tidal marshes to map soil organic carbon (SOC) at the meter scale. Fixed volume …

Manganese Bioavailability Drives Organic Matter Transformations Across Oxic-Anoxic Interfaces Via Biotic And Abiotic Pathways, Nathan A. Chin

Masters Theses

Soil organic matter decomposition is a critical process that affects nutrient cycling, CO₂ emissions, and carbon storage in terrestrial environments. Recent evidence suggests reactive manganese (Mn) phases, potent oxidants that depolymerize compounds like lignocellulose in soil organic matter, act as critical drivers of organic matter decomposition in soil and sediment environments. Furthermore, oxic-anoxic interfaces (OAIs) have been shown to be crucial hotspots for the formation of reactive Mn(III) species and associated organic matter degradation. However, the extent to which microbially mediated Mn(III) formation and subsequently Mn(III)-driven organic matter oxidation depends on Mn availability remains largely unknown. Additionally, the relative …

Microbial Extracellular Enzymes In Marine Sediments: Methods Development And Potential Activities In The Baltic Sea Deep Biosphere, Jenna Marie Schmidt

Masters Theses

The deep biosphere is defined as the subsurface ecosystem in which little energy is available to microorganisms and microorganisms can live for thousands of years. Heterotrophic microbes survive in the deep biosphere even though organic matter is limited and highly recalcitrant in nature. Measuring microbial extracellular enzyme activity provides a potential means to evaluate the rate at which microorganisms are performing carbon remineralization in the energy limited sediment beneath the seafloor. Extracellular enzymes breakdown organic compounds so that the nutrients can move inside the cell and be used for energy. This study explored the role extracellular enzymes play in the …

Incorporating Carbon Nanotubes Into Carbon Fiber Via Surface Modification, Robert Benjamin Ripy

Masters Theses

Ever more advanced materials need to be designed to further the exploration of avenues of science and engineering. Metals and traditional composites are not meeting the needs of today’s stringent demands for lightweight and strong materials. There is a need for advanced materials that are lighter and stronger to replace conventional materials; carbon fiber composites became the obvious choice because of their outstanding mechanical properties. Polyacrylonitrile (PAN) based carbon fiber has reached its apex in terms of its strength to weight ratio. Carbon nanotubes (CNTs) offer a lightweight and potentially stronger alternative to PAN based fibers. However, it is difficult …

Long-Term Impacts Of Conservation Management Practices On Soil Carbon Storage, Stability, And Utilization Under Cotton Production In West Tennessee, Candace Brooke Wilson

Masters Theses

Biogeochemical cycling of soil carbon (C) is heavily influenced by conservation agricultural (CA) practices. This study examined SOC stability under three CA practices: reduced nitrogen (N) fertilizer application rate, cover cropping, and zero-tillage implemented for 31 years. Respiration rates measured from a 602-day incubation period were fitted to a double-pool first order exponential model of SOC decomposition. The active [respired] SOC pool showed distinct differences between applications of reduced (34N kg ha^-1 [-1]) and high fertilization rates (101N kg ha^-1) combined with tillage, and suggest that high fertilizer applications with conventional tillage allocated more C into a …

Diatomic Carbon Measurements With Laser-Induced Breakdown Spectroscopy, Michael Jonathan Witte

Masters Theses

In this thesis, investigation of well-known carbon Swan spectra is of primary interest. Combustion processes and/or explosion of hydrocarbon fuels cause occurrence of the Swan band system that originates from diatomic carbon. Physical characteristics of low-temperature stars and the interstellar medium can also reveal the Swan bands. The diatomic carbon molecule shows that its lowest rotational levels are sensitive to temperature variation, and higher rotational levels are sensitive to the surrounding gas density and the radiation field. In addition, carbon is a crucial element for life and is the 4th most abundant element; therefore, it is important to ascertain accurately …

Co2 Injection Into A Deep Saline Aquifer: Porosity Measurements, Numerical Modeling, And Costs Associated With Uncertainty Of Petrophysical Parameters, Michael John Gragg

Masters Theses

Anthropogenic levels of atmospheric greenhouse gases, particularly carbon dioxide (CO₂) have increased rapidly over the last several decades and coincide with rising temperatures globally. One possible solution is to capture CO₂ before it is released into the atmosphere by large point sources, such as fossil fuel power plants. Once captured, the CO₂ can be condensed and transported to a storage facility. Of the available options for storage of condensed CO₂, geologic sequestration in deep saline aquifers is considered the most viable option.

Porosity measurements were obtained for nearly 100 core samples of the Knox …