Physical Sciences and Mathematics Commons^™

Heat Flow In The Southern Margin Of Salar De Atacama: Deep Groundwater Temperature Distributions And The Implications For Subsurface Flow And Land Surface Energy Budgets, Graham Thomas

Masters Theses

Salar de Atacama (SdA) located in Northern Chile is home to one of the planet’s largest salar systems and lithium resources. Managing groundwater resources in salars is not obvious due to the lack of scientific understanding on the connectivity between the freshwater and brine systems. Using heat as a tracer in SdA provides a cost-effective method to further investigate groundwater flow in salars. This study employs 372 temperature-depth profiles from 90 boreholes between 2013-18 to understand the distinct thermal zones and flow between them in SdA. Three thermal zones exist within the southern margin of SdA’s thermal regime, at higher …

Per- And Polyfluoroalkyl Substances (Pfas) In Treated Sewage Sludge From Michigan Wastewater Treatment Plants, Garrett Wesley Link

Masters Theses

Concentrations, compositions, and variability of Per- and Polyfluoroalkyl Substances (PFAS) in sewage sludge are characterized using an extensive dataset of 350 samples from 190 wastewater treatment plants (WWTPs) across Michigan. All samples are comprised of final treated sewage sludge generated at the end of the wastewater treatment process. Concentrations of Σ₂₄ PFAS are log normally distributed with a range of 1 to 3200 ng/g dry wt. and of average 108 ± 277 ng/g dry wt. Compounds with carboxyl and sulfonic functional groups comprised 29% and 71% of Σ₂₄ PFAS concentrations, respectively, on average. Primary sample variability is associated …

Per- And Polyfluoroalkyl Substances (Pfas) In Treated Sewage Sludge From Michigan Wastewater Treatment Plants, Garrett Wesley Link

Masters Theses

Concentrations, compositions, and variability of Per- and Polyfluoroalkyl Substances (PFAS) in sewage sludge are characterized using an extensive dataset of 350 samples from 190 wastewater treatment plants (WWTPs) across Michigan. All samples are comprised of final treated sewage sludge generated at the end of the wastewater treatment process. Concentrations of Σ₂₄ PFAS are log normally distributed with a range of 1 to 3200 ng/g dry wt. and of average 108 ± 277 ng/g dry wt. Compounds with carboxyl and sulfonic functional groups comprised 29% and 71% of Σ24 PFAS concentrations, respectively, on average. Primary sample variability is associated with …

Modeling Spatial Distributions Of Tidal Marsh Blue Carbon Using Morphometric Parameters From Lidar, Bonnie Turek

Masters Theses

Tidal marshes serve as important “blue carbon” ecosystems that accrete large amounts of carbon with limited area. While much attention has been paid to the spatial variability of sedimentation within salt marshes, less work has been done to characterize spatial variability in marsh carbon density. Driven by tidal inundation, surface topography, and sediment supply, soil properties in marshes vary spatially with several parameters, including marsh platform elevation and proximity to the marsh edge and tidal creek network. We used lidar to extract these morphometric parameters from tidal marshes to map soil organic carbon (SOC) at the meter scale. Fixed volume …

Factors Affecting Groundwater Nitrate Concentration In Madinah Area, Saudi Arabia, Majed M. Almutairi

Masters Theses

High levels of nitrate in groundwater are a serious problem in Madinah Area, Saudi Arabia. Identifying factors affecting groundwater nitrate contamination is important for managing groundwater quality. This study examined factors that have significant impacts on the high level of groundwater nitrate in Madinah Area. Factors examined included well-depth and land cover. Relationships between variables were explored using three statistical approaches: the Kruskal-Wallis test and two types of regression (ordinary least squares [OLS] and geographically weighted regression [GWR]).

Nitrate concentration data show that 73% of obtained groundwater samples exceeded the United States Environmental Protection Agency (EPA) maximum contaminant level (MCL) …

Pressure Relief Wells: Analysis Of Subsurface Heterogeneity To Evaluate Relief Well Locations For Mississippi River Levees, Emma Marie Young

Masters Theses

“When designing pressure relief well systems, it is imperative to understand what major geomorphology and heterogenies features are present, such as buried oxbow lakes, especially when the feature is parallel to the source, such as the Mississippi River. When present, there is a notable greater increase in head pressures, especially on the landward tow of the levee. This can cause erosional features that originally thought of to have been protected from by installing pressure relief wells. When comparing the effective hydraulic conductivities of horizontal clay layers and vertical clay layers spanning the length of the model, little to no noticeable …

Quantifying Surface Water Capture By Municipal Pumping Wells In An Urban Watershed Impacted By Road Salt, Austen York

Masters Theses

The Spring Valley sub-watershed is located within the Kalamazoo Township contains Spring Valley Lake, a man-made impoundment that ultimately discharges into the Kalamazoo River. Elevated chloride levels in pumped water from the Kalamazoo Station 14 municipal wellfield, located along the shoreline of Spring Valley Lake, has resulted in less than ideal corrosivity values for the water distribution system. Specific project objectives include: (1) identifying the cause of elevated chloride, (2) assessing surface water capture by the Station 14 wellfield, and (3) characterizing of water quality in Spring Valley Lake. Monitoring along a series of sampling transects spanning the sub-watershed, focused …

Hydrologic Controls On Phosphorus Speciation And Mobilization In A Subalpine Watershed (East River, Colorado), Lucia Isobel Arthen-Long

Masters Theses

The cycling of phosphorus (P) through floodplain environments is critical to ecosystem productivity and has significant implications on both water quality and soil fertility. P export from soils in response to saturation has been well documented, but the relative vulnerability of specific P pools to mobilization remains poorly constrained, as do the mechanisms mediating its release. The prediction of P availability in and export from mountainous floodplain soils is of great importance as global climate change is projected to significantly alter precipitation regimes in alpine systems. This study combined a thorough characterization of P distribution across a hillslope to floodplain …

Testing The Impact Of A Freshwater Wetland Restoration On Water Table Elevation And Soil Moisture Using A Parametric Groundwater Modeling Approach, Erika T. Ito

Masters Theses

Wetlands are now recognized for the many social, environmental, ecological, and economic benefits they provide. They improve water quality, support biodiversity, abate floods and storms, and provide local recreational areas. Historically, many wetlands have been drained or altered for residential, commercial, or agricultural use. Effective wetland restoration projects reestablish ecosystem services and mitigate legacy effects of land use change to create self-sustaining systems. However, a persisting lack of scientifically-vetted methodological and evaluation guidelines in the field of restoration ecology has caused many restoration efforts to fail to restore natural wetland hydrologic conditions. By definition, wetlands must be saturated, permanently or …

Coastal Groundwater Catchments Of The Gulf Of Alaska, Aeon Russo

Masters Theses

High latitude mountain environments are experiencing disproportionately adverse effects in a currently changing climate. The Gulf of Alaska (GoA) region is an exemplar of this. Dramatic shifts are occurring in the region’s freshwater reservoirs as glaciers retreat more with each passing year. Research in the region places much focus on observing and predicting climate driven shifts in glacier mass balance, surface discharge, and associated nutrient fluxes to the ocean. On the other hand, coastal groundwater discharge (CGD) is given very little attention. Global and near-global estimates of CGD indicate variable results spanning an order of magnitude. Focusing on regionally specific …

Using Low-Flow Sampling Data To Estimate Hydraulic Conductivity In Aquifers, Joy Kiefer

Masters Theses

Hydrogeologists sample wells to test aquifer water quality and use slug tests to estimate aquifer permeability. Robbins et al. (2009) proposed a more efficient way to obtain the goals of the two tests—the use of low-flow sampling and the use of the resulting flow rate and drawdown data to estimate aquifer hydraulic conductivity (K). The Robbins et al. method calculates K by using the slope of the best fit line from the graph of flow rate vs. drawdown for all low-flow pumping data collected at a well. When the method was applied to low-flow data from four Kalamazoo, MI, it …

Agricultural Irrigation Induced Evaporation In A Temperate Study Area: A Stable Isotope Approach, Lincoln Grevengoed

Masters Theses

In regions where groundwater is used for irrigation, significant water losses take place due to evaporation. Previous studies demonstrated the utility of stable oxygen and hydrogen isotopes in estimating evaporative water loss experienced during return flow back to an aquifer. Unlike arid regions where the other studies took place, this study examined the region around Kalamazoo, Michigan, the United States, which experiences a more temperate climate. Irrigation in the Kalamazoo area primarily uses center-pivot systems supplied by wells, unlike flood irrigation in previous study areas. Water samples were taken periodically from wells close to center-pivot irrigation systems. Water losses due …

High-Resolution Timeseries Analysis Of Dynamic Geochemistry: A 27-Well Survey Of Contaminated Groundwater Downstream Of The Former S-3 Ponds, Oak Ridge, Tennessee, Emma Dixon

Masters Theses

Spatiotemporal variability of geochemistry of contaminated groundwater has large implications on overall water quality and ability to respond to remedial applications. Gaining knowledge of how geochemistry changes over time in an area can help establish response trends to changing external conditions like weather and level of contamination. In this study, a spatiotemporal survey was performed on 27 wells at the Y-12 Complex in Oak Ridge, Tennessee. This was completed to measure diurnal fluxes in geochemistry from seasonal changes and extreme weather conditions in three areas of historically different contamination levels from a single point contamination source. Measurements were gathered over …

Influence Of Living Plant Roots And Mycorrhizal Hyphae On Soil Hydraulic Properties, Katelyn M. Marcacci

Masters Theses

The interrelationships between vegetation, soil, and water are fundamental in evaluating the projected impacts of global climate change. Many predictive models require soil hydraulic parameters as inputs. As most hydraulic parameter datasets are for repacked soil, the influence of vegetation on hydraulic parameters is not thoroughly understood. Living roots and mycorrhizal fungi cause physicochemical alterations in soils. Quantifying how vegetation influences soil hydraulic parameters is necessary to more accurately simulate soil water dynamics in climate models.

Laboratory experiments were conducted to test if the presence of roots and roots inoculated with mycorrhizal fungi have a significant effect on the saturated …

Processes, Patterns, And Predictions Of Soil Moisture Variation In Upland And Peatland Cranberry Farms In Massachusetts, Rebecca Brennan

Masters Theses

The American Cranberry (Vaccinium macrocarpon Ait.) represents a vital sector of the economy of southeastern Massachusetts. Due to the hydrogeological and edaphic characteristics of peatlands, variations in soil drainage and soil moisture represent major management challenges for growers in Massachusetts. An emerging trend of upland (mineral soil) cranberry farms planted with new hybrid cultivars has the potential to enhance the profitability and long-term viability of cranberry production in Massachusetts. However, sparse data exist on soil moisture characteristics of peatland and upland cranberry farms. The purpose of this research was to elucidate the differences in soil moisture between upland and …

Field And Numerical Evaluation Of Nitrogen Transport From Septic Systems In Surfical Aquifer Systems To Charlotte Harbor, Florida, Tanten T. Buszka

Masters Theses

Shallow water tables in coastal surficial aquifers limit effective treatment of septic effluent which can result in excess nutrient loading into nearby surface water bodies. Approximately 45,000 septic systems in Charlotte County, Florida transmit effluent into an under studied surficial aquifer and contribute to harmful algal blooms and outbreaks of E. coli. An undeveloped field site was characterized using standard hydrogeologic methods, including a one-year duration natural gradient tracer test, to obtain representative lithology of the sandy surficial aquifer and estimates of groundwater velocity, flow directions, effective porosity and dispersion. These data were used to support the development of a …

An Analysis Of Large Displacement Pneumatic Slug Tests For The Characterization Of Aquifer Parameters – Guidelines For An Alternative Field Procedure, Madison E. Wayt

Masters Theses

Variations in hydraulic conductivity (K) between larger scale aquifer tests and smaller scale slug tests, and within individual aquifer tests, have been linked to method bias and aquifer heterogeneity. The impacts of varying slug sizes on K, which represents K dependence on a smaller scale, is not as well understood. To examine the relationship between K and slug size, a series of slug tests with a range of initial displacements were performed in three intermediate to high K, unconfined aquifers encompassing homogeneous, mildly heterogeneous, and moderate to highly heterogeneous conditions. Slug test estimated K values at Asylum Lake are compared …

Aquatic Plants And Their Application To Successful Floating Treatment Wetlands, Katherine May Mazanec

Masters Theses

“This research aims to mitigate eutrophication of freshwater habitats affected by urban stormwater runoff. Two highly impacted urban ponds near the Missouri S&T campus in Rolla were the focus of this research on the application of floating treatment wetlands (FTWs). An FTW consists of a man-made floating mat that is planted with emergent or floating macrophytes. The plants grow on the mat and their roots extend into the water column below the mat. Plant tissues, especially roots in direct contact with the water, take up nutrients, act as biofilm growth sites, and may facilitate precipitation of nutrients. With urbanization, ponds …

Defining And Addressing Interconnected Goals In Groundwater Management Planning Across The Usa, Allison Gage

Masters Theses

Groundwater accounts for approximately 99% of the available freshwater on Earth, and is an important resource for irrigation, potable water, and domestic use in the United States. However, the overuse of groundwater has led to aquifer depletion in several basins across the USA, resulting in storage reduction, contamination, salt water intrusion, and depletion of surface waters. To properly manage groundwater for the future, there is a need for well-informed Groundwater Management Plans (GWMPs) in order to prevent further depletion and erosion of the resource. Previous studies have focused on groundwater management relative to groundwater laws, regulations, and institutional arrangements. This …

Spatial And Temporal Mapping Of Distributed Precipitation, Surface And Groundwater Stable Isotopes Enables Insights Into Hydrologic Processes Operating At A Catchment Scale, Alison Cole

Masters Theses

Isotopic analyses of d¹⁸O and d²H of water through the hydrologic cycle have allowed hydrologists to make better interpretations related to climate and relationships between precipitation, surface water, and groundwater. In this study 394 precipitation samples 1917 surface water samples and 1405 groundwater samples across Massachusetts was used to create an isoscape for each respective water. All samples have been collected by volunteers throughout Massachusetts. A state meteoric water line: d²H = 7.7*d¹⁸O + 9.8, surface water line: d²H = 5.7*d¹⁸O – 4.2, and groundwater line: d^{2 …}

Hydrologic Structure And Function Of Vernal Pools In South Deerfield, Massachusetts, Charlotte Axthelm

Masters Theses

Vernal pools are small, ephemeral wetlands lacking an inlet or outlet. These wetlands, also known as seasonal pools, are found in a wide range of biomes, and their characteristics vary based on location. While the vegetation of western U.S. pools, and amphibians of eastern U.S. pools have been extensively studied, many aspects of vernal pools have not been fully characterized. In particular, although the general seasonal wetting and drying cycle is understood qualitatively, few studies have attempted to quantify the hydrological regime of vernal pools in New England. As water level variation drives many, if not all, of the characteristics …

The Climatic And Hydrostratigraphic Controls On Brine-To-Freshwater Interface Dynamics In Hyperarid Climates: A 2-D Parametric Groundwater Modeling Study, Sarah Mcknight

Masters Theses

Density dependent flow occurs in areas where high-salinity groundwater interacts with low-salinity groundwater to create a brine-to-freshwater interface that defies common assumptions about groundwater movement. Yet the geologic and hydrologic factors that impact interface dynamics and migration remain poorly defined. With less than 20 mm•yr^-1 of precipitation and with an extremely dense (i.e. 1.2 g•cm^-3) naturally occurring brine, Chile’s Salar de Atacama (SdA) provides an excellent analog for exploring interface dynamics in other arid regions. Site-specific 2-D models of the interface in the southeastern region of SdA, with interpretations of the hydrostratigraphic framework, provide an analysis for …

Temporal Changes Of Nutrients Within The Lower Grand River Watershed And Selected Sites, Weston Scott Duley

Masters Theses

"This report presents the results of a study carried out in collaboration with the U.S. Geological Survey (USGS) and the Missouri Department of Natural Resources (MDNR) to estimate total nitrogen (TN) and total phosphorus (TP) at five USGS monitoring sites within Lower Grand River Watershed (LGRW) and two monitoring sites on the Missouri River. The objective of this study was to quantify temporal changes in TN and TP concentrations and compare those to best management practices (BMPs).

In this study, the approach to the analysis of long-term surface water-quality data by using Weighted Regressions on Time, Discharge and Seasons models …

Modeling Channel Response To Dam Removal In Lansing, Michigan, Using Swat, Ryan Filbin

Masters Theses

The removal of dams has increased in recent decades in the United States, largely resulting from decaying infrastructure and greater efforts to restore rivers to a more natural, free-flowing state. Dam removal presents the opportunity for increased public safety, improved environmental prosperity, and improved economic prosperity in conjunction with riverfront revitalization projects. The City of Lansing, Michigan, contains two moderate-to high-risk dams along the Grand River that pose a significant risk to the surrounding area in the event of structural failure.

The Soil and Water Assessment Tool (SWAT) is applied to model the impacts of the Moores Park Dam and …

Development Of A Variogram Approach To Spatial Outlier Detection Using A Supplemental Digital Elevation Model Dataset, Zane Daniel Helwig

Masters Theses

"When developing a ground water model, the quality of the dataset should first be evaluated. Spatial outliers can lead to predictions which are not representative of actual conditions. In order to isolate misrepresentative points, a method is presented which examines the experimental variogram of a ground water elevation dataset. To define a threshold variance between pairs of ground water elevation measures, ground elevation values from a digital elevation model (DEM) are used to determine a maximum reasonable variance expected to occur on the experimental variogram. To determine appropriate DEM parameters, a separate study was also done which observed characteristic behavior …

Extent Of Capillary Rise In Sands And Silts, Rachel Lynn Salim

Masters Theses

The values reported in literature for the height of capillary rise in fine sands, silts, and clays are contradictory. Most of the values were based on mathematical models, which used estimated rather than measured input data. This work measured capillary rise values in laboratory experiments in fine-grained sands and silts.

Two uniform sands with grains 0.35--0.7 mm in diameter and 0.3-0.6 mm in diameter, silt with an average grain size below 40 microns, and 0.35--0.7 mm sand coated with a water-repellant spray were carefully packed into two-inch diameter glass columns. These columns were placed into clear plastic tanks with water …

Characterizing Groundwater Recharge And Streamflow Using Stable Isotopes Of Oxygen And Hydrogen, Chanse M. Ford

Masters Theses

Potential changes to climate and precipitation patterns from anthropogenic influences like global climate change could have an impact on Michigan’s groundwater resources. Indirectly this could have an effect on Michigan’s surface waters as well, since groundwater and surface waters are intimately linked to form one system.

This investigation utilized stable isotopes of oxygen and hydrogen found in precipitation, groundwater and surface waters to better understand the contribution of different types of precipitation to recharge of a shallow aquifer in Manistee National Forest, MI. The study also examines the contribution of this shallow groundwater to streamflow in the nearby White River. …

Lnfluence Of Persulfate On Solidification/Stabilization Characteristics Of Iss Treatment, Jeffrey M. Hudson

Masters Theses

Two environmental remediation technologies that lend themselves well to being combined in a single application are In Situ Chemical Oxidation (ISCO) using activated persulfate (PS), and In Situ Stabilization (ISS). Persulfate can be activated by increasing the pH to 10.5 and/or increasing temperatures to 30ºC. Many common ISS amendments increase temperature to 30°C and/or pH to 10.5 when in contact with soil water. Laboratory experiments were conducted with various soils to determine the ability of eight ISS amendments to activate persulfate. All eight ISS amendments activated persulfate. This work also showed that the relative contribution of heat vs. alkaline activation …

Slug Tests In Unconfined Aquifers, Rozkar Izzaddin Ismael

Masters Theses

This research presents a hydraulic conductivity (K) analysis of unconfined aquifers using slug tests. Slug tests are used to determine in situ aquifer hydraulic conductivity more quickly and economically than by a pump test. This study examines how to best conduct a slug test using a physical slug. Different common slug test analysis methods are compared, including Bouwer and Rice (1976), Hvorslev (1951), Dagan (1978) and Kansas Geological Survey (KGS, 1994). Questions that motivated this study include: Which methods are better for performing and analyzing slug tests? Does the size of the physical slug affect the results? Do large initial …

Sources Of Water And Solutes To The Salar De Atacama, Chile: A Coupled Hydrologic, Geochemical, And Groundwater Modeling Study, Lilly G. Corenthal

Masters Theses

Focused groundwater discharge in endorheic basins provides opportunities to investigate mechanisms for closing hydrologic budgets in arid regions. The Salar de Atacama (SdA), a closed basin in northern Chile, has accumulated over 1800 km³ of halite and a lithium-rich brine since the late Miocene primarily through evapotranspiration of groundwater. The hydrologic balance of SdA and sources of water and solutes required to explain this deposit are not well constrained. An adapted chloride mass balance method drawing on a database of over 200 water sample sites is applied to a remotely-sensed precipitation dataset to estimate spatially-distributed modern groundwater recharge. Comparing …