Physical Sciences and Mathematics Commons^™

Testing The Limits Of Hyperspectral Airborne Remote Sensing By Mapping Eelgrass In Elkhorn Slough, Kelley J. Bostrom

Master's Theses

Seagrass ecosystems are a valuable resource, but vulnerable to changing conditions in the coastal ocean. Quantification of seagrass density and distribution from aerial imagery can be applied as a tool in resource management and ecosystem health and stability monitoring. This study investigates analytical methods for mapping eelgrass beds in an optically complex shallow, turbid estuary. Hyperspectral imagery (HSI) of Elkhorn Slough, CA was collected by the Spectroscopic Aerial Mapper with Onboard Navigation (SAMSON) instrument. In-situ data of water column and benthic optical properties and Hydrolight Radiative Transfer model were used to create a spectral library describing the reflectance of Elkhorn …

Collisional Reactivation Of Rift Margin Fracture Zones, Taiwan And The Taconic Allochthon, David C. Mirakian

Master's Theses

Chapter I. Transverse Topographic Development due to the Reactivation of a Partially-Subducted Fracture Zone: The Southwest Hsüehshan Range, Central Taiwan

Abstract — The southwest flank of the Hsüehshan Range is defined by a topographic break which cuts across regionally mapped structures in central Taiwan. The mountain front trends ~345°, slightly oblique to the Sanyi-Puli seismic zone which has been previously interpreted as a reactivated continental margin fracture zone. Structural data collected along the length of the topographic break reveal two populations of cross-cutting faults with distinct fault-zone materials and a series of southwest-plunging folds. Paleostress axes were reconstructed using the …

Simulated Effects Of Varied Landscape-Scale Fuel Treatments On Carbon Dynamics And Fire Behavior In The Klamath Mountains Of California, Kevin J. Osborne

Master's Theses

I utilized forest growth model (FVS-FFE) and fire simulation software (FlamMap, Randig), integrated through GIS software (ArcMap9.3), to quantify the impacts varied landscape-scale fuel treatments have on short-term onsite carbon loss, long-term onsite carbon storage, burn probability, conditional flame length, and mean fire size. Thirteen fuel treatment scenarios were simulated on a 42,000 hectare landscape in northern California: one untreated, three proposed by the US Forest Service, and nine that were spatially-optimized and developed with the Treatment Optimization Model in FlamMap. The nine scenarios developed in FlamMap varied by treatment intensity (10%, 20%, and 30% of the landscape treated) and …

Chemical, Biological, And Preliminary In Vitro Studies Of Novel Vanadium(Iv) Complexes With Schiff Bases And Thiosemicarbazone Ligands, Nerissa Abigail Lewis

Master's Theses

9-Anthraldehyde-N(4)-methylthiosemicarbazone (MeATSC), potassium (E)-2-(2-hydroxybenzylideneamino)-3-(1H-indol-3-yl)propanoate (K[(Sal-L-tryp)] and 2-(2-hydroxybenzylamino)-3-(1H-indol-3-yl)propanoic acid (the reduced Schiff base) were prepared using known synthetic procedures. Two novel thiosemicarbazone ligands, (E)-N-ethyl-2-(4-hydroxy-3-methoxybenzylidene)hydrazinecarbothioamide (N-Ethhymethohcarbthio) and (E)-N-ethyl-2-(1-(thiazol-2-yl)ethylidene)hydrazinecarbothioamide (acetylethTSC), were also prepared. All ligands were characterized by FT IR and electrochemistry. N-Ethhymethohcarbthio were characterized by elemental analysis whereas the reduced Schiff base and K[(Sal-L-tryp)] were characterized by ESI MS. X-ray crystallography was also used to characterize acetylethTSC. The ligands were then reacted with [VO(Sal-L-tryp)(H2O)] (1) (Sal-L-tryp = N-salicylidene-L-tryptophanate) to produce the …

Continuous Analysis Of Photocatalytic Activity In Thin-Films And Coatings, Steven Michael Allee

Master's Theses

Materials that undergo photocatalytic reactions create evolved gases due to ultraviolet light decomposition. Current methods of measuring these gases typically result in destruction of the sample. A test fixture was developed to measure evolved gases in a nondestructive manner through the utilization of a flow-through sensor array system. Preliminary testing indicates responsive measurements down to parts-per-billion sensitivity for some gases and will be compared with mass spectrometry measurements. Further development of this process could lead to the ability to measure photocatalytic reaction gases on a continuous basis without interruption of the process or destruction of materials introduced to the system.

Adhesion And Durability Of Coatings On Polypropylene Exterior Sidings, Logan Riekio Stark

Master's Theses

Plastics have become a universal material for use in a myriad of commercial and consumer products. One such product, exterior siding, is the focus of this project. Although siding products were originally made from wood, vinyl siding, which offered superior performance, was introduced in the 1950’s. More recently, polypropylene (PP) siding has been introduced; PP provides a stronger product, which allows for deeper patterns and better edge detailing. PP siding, compared to traditional wood siding, doesn’t warp, crack, or degrade as easily with extended exposure to the elements, and is cheaper to maintain. However, even plastic siding must be coated. …

Unusual Electron Transfer Rate Effects Due To Pyridyl Ring Substituents And Trace Group Viii B Hexacyano Complexes As Added Salts, Faisal Mehmood

Master's Theses

The rates of pseudo-self-exchange electron transfer reactions between [(NH₃)₅Ru^IIL]²⁺ and [(NH₃)₅Ru^IIIL’]³⁺ at reactant concentrations of 1.0 х 10^-4 M (where L, L’ = substituted pyridines) and the reaction between [(NH₃)₅Ru^IIPy]²⁺ and [(NH₃)₅Ru^III3FPy]²⁺ at different reactant concentrations in the presence of various salts added were studied by using the stopped-flow kinetic spectroscopy. Marcus theory rate vs. driving force plots yielded distinct families of lines depending on whether a 3- or 4- …

Quantification Of Nitrate Sources And Sinks Using A Water Quality Network In Morro Bay Estuary, California, Johanna Nadia Jean Weston

Master's Theses

Using an instrumented water quality network in Morro Bay Estuary, California from 2007 to 2010 (15 min sampling frequency), this study addressed the two objectives of constructing a nitrate budget and assessing the influence of sampling frequency on water quality parameters. These two objectives led to the submission of an original report of research (Appendix A) and a note (Appendix B) to peer-reviewed journals.

The first objective was to characterize the high spatial and temporal variation in physical parameters and nitrate concentrations and to construct a nitrate budget quantifying sources and sinks of nitrate from the ocean, streams, and groundwater, …

Stromatolitic Knobs In Storrs Lake, San Salvador, Bahamas: Insights Into Organomineralization, Alexandre J. Fowler

Master's Theses

Storrs Lake, a hypersaline lake on the east coast of San Salvador Island, Bahamas, contains well-developed microbial mats, some of which have developed calcified structures called microbialites. Many of these microbialites are laminated, and therefore classified as stromatolites. This study focuses on small stromatolitic knobs located in the southern portion of Storrs lake, which are still actively forming, to gain insights into the early stages of stromatolite formation. These knobs appear to be forming as the result of in situ micritic precipitation mediated by both photosynthetic and heterotrophic microbial metabolisms. By comparing these small stromatolitic knobs to larger stromatolitic heads …

Synthesis, Field Emission And Associated Degradation Mechanisms Of Tapered Zno Nanorods, Gregory M. Wrobel Mr.

Master's Theses

Equation 1..... 4

Equation 2..... 4

Equation 3..... 6

Equation 4..... 7

Equation 5..... 9

Equation 6..... 10

Equation 7..... 11

Equation 8..... 12

Equation 9..... 14

Equation 10..... 40

Equation 11..... 51

Synthesis, Field Emission and Associated Degradation Mechanisms of Tapered ZnO Nanorods

Gregory Michael Wrobel, M.S.

University of Connecticut, 2011

Modern development of field emitter arrays (FEA) has been made possible, partly thanks to the synthesis and development of one-dimensional (1D) nanostructures. High aspect ratio 1D nanostructures effectively amplify the electric field at the emitter tips, allowing electrons to be extracted at relatively low electric field. An inexpensive …

"Buy Local" Consumer Behavior And Wood Products: A Case Study, Charlotte C. Rand

Master's Theses

Consumers in the United States are increasingly interested in buying locally grown/produced (LG/P) agricultural products (Connor et al. 2009). In comparison, consumer interest in buying local wood products is not evident. In the same way that the LG/P agriculture phenomenon has helped preserve farmland and foster awareness of where food originates, expanding local production of forest products may also create similar benefits for forestland both locally and globally. However, studies examining the “Buy Local” phenomenon and its potential to inform the local production of wood products are not apparent in the literature.

This study examined consumer attitudes and beliefs that …

Amibe: An Imperative Programming Language With First Class Continuations, Yuting Wang

Master's Theses

A continuation represents the future of an execution. It is often used as an intermediate representation(IR) to compile functional programming languages, make control flow explicit and full beta-reduction(function inlining) possible. Continuations are also a language feature that gives user the ability to completely control the execution control flow(first class continuation). Efficient implementation of first class continuation is important for languages that need non-determinism and backtracking(e.g., COMET). We present a prototype imperative programming language with first class continuation -- AMIBE. AMIBE uses the LLVM compiler infrastructure which is attractive for its optimizing tools and overall modern organization. However, LLVM does not …

Development Of An Approach To Evaluate Fractured Crystalline Bedrock Water Resource Supply And Sustainability, Helen E. Spera

Master's Theses

Groundwater derived from fractured crystalline bedrock is an important resource in Connecticut. Despite its importance we know very little about this resource. This study was conducted at the Plant Science and Landscape Architecture Research and Education Facility, University of Connecticut, Storrs, CT. The objectives of this study were: to improve the characterization of the hydrogeology of the facility; to develop a method to determine the amount of recharge to the bedrock from the overburden during pumping and non-pumping periods; and to develop an approach that can be used in evaluating the sustainability and zone of contribution of bedrock pumping wells. …

Effects Of High-Density, Short-Duration Planned Livestock Grazing On Soil Carbon Sequestration Potentials In A Coastal California Mixed Grassland, Kristina Michelle Wolf, Marc Horney, Brent Hallock, Robert T. Rutherford, Anthony T. O'Geen, Royce Larsen, William Plummer

Master's Theses

Planned grazing management in rangelands may improve carbon sequestration potential of soils by increasing plant biomass and the rate of nutrient cycling, which might mitigate global warming. The effects of high-intensity, short-duration planned grazing of sheep on several soil and ecosystem properties were investigated on a mixed grassland in San Luis Obispo, CA. The objectives of this study were to (a) identify soil properties related to soil C sequestration in rangelands; (b) determine if planned grazing improved soil carbon sequestration; (c) quantify changes in identified variables in grazed and rested plots; and (d) analyze any changes in plant species composition …

Effect Of Au Content On Microstructural Evolution Of Snagcu Solder Joints That Undergo Isothermal Aging And Reliability Testing, Patrick J. Hyland

Master's Theses

Electronics, especially, printed circuit boards (PCBs) are a widespread technology. Metal coatings or “surface finishes” are often added to PCB board pads and component leads during manufacturing to improve their performance. Electroplated nickel/gold over copper is a popular surface finish for printed circuit boards and component leads. The presence of gold in solder joints, however, is known to have detrimental effects referred to as gold embrittlement. It is generally understood that tin-lead solder joints with less than 3 weight percent (wt%) of gold will not experience reliability issues. The acceptable level of gold in lead-free solder joints, however, is less …

An Examination Of The Yang-Baxter Equation, Alexandru Cibotarica

Master's Theses

The Yang-Baxter equation has been extensively studied due to its application in numerous fields of mathematics and physics. This thesis sets out to analyze the equation from the viewpoint of the algebraic product of matrices, i.e., the composition of linear maps, with the intent of characterizing the solutions of the Yang-Baxter equation.

We begin by examining the simple case of 22 matrices where it is possible to fully characterize the solutions. We connect the Yang-Baxter equation to the Cecioni-Frobenius Theorem and focus on obtaining solutions to the Yang-Baxter equation for special matrices where solutions are more easily found. Finally, …

A Comparison Of Two Different Methods For Solving Biharmonic Boundary Valve Problems, Megan Lashea Richardson

Master's Theses

We use the methods of compactly supported radial basis functions (CS-RBFs) and Delta-shaped basis functions (DBFs) to obtain the numerical solution of a two-dimensional biharmonic boundary value problem. The biharmonic equation is difficult to solve due to its existing fourth order derivatives, besides it requires more than one boundary conditions on the same part of the boundary. In this thesis, we use either a one-level or a two-level technique for constructing the approximate solution in the context of Kansa’s collocation method. This thesis will compare the accuracy of the methods of CS-RBFs and DBFs when applied to the biharmonic boundary …

Detection Of Hydrogen In A Two-Phase Cryogen Flow Stream With Thermal Protection Design Configurations, Anton Dmitrievitch Netchaev

Master's Theses

All commercial liquid-propelled rockets use hydrogen as means to reach outer space. These rocket boosters are tested on the ground and use hydrogen as means of purging the remaining explosive gasses left in the test tanks. To conserve helium, a non-renewable resource, a test fixture was developed to characterize and test sensors that could improve the accuracy and response of the current system. By improving response time of the system, helium waste during the purge process can be minimized. The test fixture was constructed to simulate temperatures and pressures that are encountered at the testing facilities. The test fixture is …

To Shift Or Not To Shift: Maximizing The Efficiency Of A Wireless Sensor Network Using Multiple Sinks, Chabli Boler

Master's Theses

Energy efficiency is a vital part of wireless sensor networks (WSN). Using correct techniques, we can improve the overall data throughput of the network and, at the same time, cut down the cost of running it. The efficient utilization of the life of the sensor node in a WSN is a critical problem. This is a problem since the sensor nodes closest to the sink node expend more energy because they send more messages, mostly for routing, than any other node on the network.

This decreases the life of those sensor nodes and will lead to dead spots in the …

Mammalian Fauna From The Fullerton Gravel Pit (Ogallala Group, Late Miocene), Morton County, Kansas, Michael Anthony Calvello

Master's Theses

The Fullerton Gravel Pit, Morton County, Kansas is one of many sites in western Kansas at which the Ogallala Group crops out. The Ogallala Group was deposited primarily by streams flowing from the Rocky Mountains. Evidence of water transport is observable at the Fullerton Gravel Pit through the presence of allochthonous clasts, cross-bedding, pebble alignment, and fossil breakage and subsequent rounding. Fluvial mechanisms also played an important role in the distribution of fossil material. When the fossils from the Fullerton Gravel Pit are placed in Voorhies Groups, it appears that a majority of them were removed from suspension gradually and …

Investigation Of The Effect Of Xanthophyll Composition On Energy Transfer And Quenching In Light-Harvesting Complexes From The Diatom, Phaeodactylum Tricornutum, Jose L. Robinson Duggon

Master's Theses

No abstract provided.

Model Based Assessment Of Potential Impacts Of Climate Change On The Flow Of The Main Headwaters Of The Nile River: Equatorial Lakes Region And Blue Nile Basins, Fisseha G. Berhane

Master's Theses

Berhane Fisseha. Model based assessment of potential impacts of climate change on the flow of the main headwaters of the Nile River: Equatorial Lakes Region and Blue Nile basins (Under the direction of Dr. Richard Anyah).

Spatially and temporally detailed assessment of the hydrologic processes of the main sources of the Nile River headwaters (Blue Nile basin and Equatorial Lakes Region) is vital for basin-wide scale management to cope with the pressing water problems due to burgeoning populations, a growing demand for electricity, irrigation for food production and possible climate change.

The main objectives of this study were to use …

Point-Based Color Bleeding With Volumes, Christopher J. Gibson

Master's Theses

The interaction of light in our world is immensely complex, but with mod-

ern computers and advanced rendering algorithms, we are beginning to reach

the point where photo-realistic renders are truly difficult to separate from real

photographs. Achieving realistic or believable global illumination in scenes with

participating media is exponentially more expensive compared to our traditional

polygonal methods. Light interacts with the particles of a volume, creating com-

plex radiance patterns.

In this thesis, we introduce an extension to the commonly used point-based

color bleeding (PCB) technique, implementing volume scatter contributions. With

the addition of this PCB algorithm extension, we …

Development Of A Cubesat Instrument For Microgravity Particle Damper Performance Analysis, John Trevor Abel

Master's Theses

Spacecraft pointing accuracy and structural longevity requirements often necessitate auxiliary vibration dissipation mechanisms. However, temperature sensitivity and material degradation limit the effectiveness of traditional damping techniques in space. Robust particle damping technology offers a potential solution, driving the need for microgravity characterization. A 1U cubesat satellite presents a low cost, low risk platform for the acquisition of data needed for this evaluation, but severely restricts available mass, volume, power and bandwidth resources. This paper details the development of an instrument subject to these constraints that is capable of capturing high resolution frequency response measurements of highly nonlinear particle damper dynamics.

A Study Of Semi-Automated Tracing, Jeffrey Holden

Master's Theses

Requirements tracing is crucial for software engineering practices including change analysis, regression testing, and reverse engineering. The requirements tracing process produces a requirements traceability matrix(TM) which links high- and low-level document elements. Manually generating a TM is laborious, time consuming, and error-prone. Due to these challenges TMs are often neglected. Automated information retrieval(IR) techniques are used with some efficiency. However, in mission- or safety-critical systems a human analyst is required to vet the candidate TM. This introduces semi-automated requirements tracing, where IR methods present a candidate TM and a human analyst validates it, producing a final TM. In semi-automated tracing …

Synthesis And Characterization Of Linear And Branched Polylactic Acid For Use In Food Packaging Applications, Kyle C. Bentz

Master's Theses

Polylactic acid (PLA) resins of various molecular weights and molecular weight distributions were synthesized. Linear, narrow molecular weight distribution (MWD) PLA resins were synthesized, as well as resins containing both high molecular weight branched structures and low molecular weight chains and oligomers. Narrow MWD resins were synthesized for use as adhesives for corrugated paperboard and broad MWD resins were synthesized for use as a waterborne coating. PLA resins were dispersed for use as a waterborne coating. Success has been made at forming films utilizing various plasticizers and surfactants as well as polyvinyl alcohol as dispersing agents. A cold dispersion procedure …

Onboard Video Stabilization For Unmanned Air Vehicles, Nicholas Stewart Cross

Master's Theses

Unmanned Air Vehicles (UAVs) enable the observation of hazardous areas without endangering a pilot. Observational capabilities are provided by on-board video cameras and images are relayed to remote operators for analysis. However, vibration and wind cause video camera mounts to move and can introduce unintended motion that makes video analysis more difficult. Video stabilization is a process that attempts to remove unwanted movement from a video input to provide a clearer picture.

This thesis presents an onboard video stabilization solution that removes high-frequency jitter, displays output at 20 frames per second (FPS), and runs on a Blackfin embedded processor. Any …

Developing Digital Field Guides For Plants: A Study From The Perspective Of Users, Emily Roseanne Schwarz

Master's Theses

A field guide is a tool to identify an object of natural history. Field guides
cover a wide range of topics from plants to fungi, birds to mammals, and shells to minerals. Traditionally, field guides are books, usually small enough to be carried outdoors . They enjoy wide popularity in modern life; almost every American home and library owns at least one field guide, and the same is also true for other areas of the world.

At this time, companies, non-profits, and universities are developing computer
technologies to replace printed field guides for identifying plants. This thesis
examines the state …

Part A: The Use Of Nonionic Associative Polymers For The Thickening And Emulsifying Of Personal Care Products/ Part B: The Synthesis Of A Manganese Sod Mimetic For Reactive Coatings, Mallory Lynn Mcmahon

Master's Theses

Part A

The use of nonionic associative thickeners was proposed for personal care applications. Various limitations of current rheology modifiers used in personal care were discussed. Nonionic associative polymers were examined as both thickeners and emulsifiers. The structure/property relationship for nonionic polymers and their ability to thicken and emulsify were fully examined. Results showed an increase in thickening efficiency for nonionic associative polymers with higher log(P) (partition coefficient) values. This was due to the formation of smaller aggregates and increased bridging between aggregates. The connection between oil polarity, log(P) of the associative polymer, and emulsion stability showed no relationship however; …

Go Farm, Goleta: Urban Agriculture Protection For Eastern Goleta Valley, Eli M. Krispi

Master's Theses

This paper explores two potential land use planning strategies that can be used to preserve and enhance the economic viability of agricultural operations surrounded by suburban development in Santa Barbara County’s Eastern Goleta Valley: buffers between agriculture and other land uses, and agritourism. In the case of buffers, academic literature is examined to determine how effective buffers are at various tasks (filtering runoff, mitigating dust and wind, providing habitat, etc.) and how to construct buffers to maximize their effectiveness. Land use plans and codes from several California jurisdictions are studied to see how buffers are put to use. Academic literature …