Physical Sciences and Mathematics Commons^™

Structural Analysis Of The Northwest Wind Mountain Quadrangle, New Mexico: Proterozoic Shearing To Cenozoic Brittle Faulting In The Burro Mountains, Jensen Kohl Angelloz

Electronic Theses and Dissertations

Preliminary investigation of the Bullard Peak metamorphic series (BPMS) in the northwestern Wind Mountain quadrangle within the Burro Mountains of southwestern New Mexico suggests a possible previously unidentified shear zone, prompting detailed (1:12,000) geologic mapping and collection of structural data. The study area has a complex tectonic history, including 1) ~1.65 Ga metamorphism during accretion of the Mazatzal terrane to Laurentia’s southern margin; 2) ~1.4 Ga intrusion of Granite and Rhyolite Province granitoids; 3) significant uplift during the formation of the Ancestral Rockies (~300 Ma) and the Rocky Mountains (~70-50 Ma); and 4) inversion tectonics with reactivation of compressional faults …

Geology Of The Northern Alto Relex Area, Big Bend National Park, Brewster County, Texas, Robert Schoen

Electronic Theses and Dissertations

Detailed, 1:12,000-scale geologic field mapping was conducted around Alto Relex in the northern Sierra Del Carmen Mountains in Big Bend National Park. Alto Relex is a prominent, near vertical, ~1000 foot-high fault-line scarp. Cretaceous rocks in the area were folded and faulted by Laramide compression, intruded by Tertiary sills and overprinted by high-angle normal faults from Basin and Range extension. During the Laramide Orogeny and Basin and Range extension, the underlying basement shear zone called, the Texas Lineament, was reactivated creating a transpressional and transtensional regimes. The general geology of this area was outlined by Moustafa (1988) working primarily from …

Evaluating Potential For Water Quality Decline In Maine Lakes, Kaci N. Fitzgibbon

Electronic Theses and Dissertations

Understanding lake vulnerability with respect to eutrophication and loss of water quality is important for sustainability of aquatic ecosystems. This project aims at identifying and quantifying the effects of relevant physiochemical, climate, and watershed characteristics on lake vulnerability in order to develop management decision tools for the Maine Department of Environmental Protection (MEDEP). In a changing chemical and physical environment, using independent variables from each of these categories and then relating them to the summer lake epilimnetic phosphorus (P) concentrations allows for development of models to inform stakeholders of lake vulnerability to eutrophication problems.

We studied 24 lakes covering a …

Cellulose Nanofiber-Reinforced Impact Modified Polypropylene: Assessing Material Properties From Fused Layer Modeling And Injection Molding Processing, Jordan Elliott Sanders

Electronic Theses and Dissertations

The purpose of this research was to investigate the use of cellulose nanofibers (CNF) compounded into an impact modified polypropylene (IMPP) matrix. A IMPP was used because it shrinks less than a PP homopolymer during FLM processing. An assessment of material properties from fused layer modeling (FLM), an additive manufacturing (AM) method, and injection molding (IM) was conducted. Results showed that material property measurements in neat PP were statistically similar between IM and FLM for density, strain at yield and flexural stiffness. Additionally, PP plus the coupling agent maleic anhydride (MA) showed statistically similar results in comparison of IM and …

Geological Framework Of The Continental Shelf Of South Carolina Winyah Bay: Paleodrainage, Transgressions And Essential Fish Habitat, Amanda Roach

Electronic Theses and Dissertations

A regional geophysical survey of the inner continental shelf off central South Carolina was completed on a cooperative cruise between NOAA and Coastal Carolina University in July 2015. An integrated mapping suite comprised of subbottom echosounder, side scan, multibeam and split beam sonars was used to define the regional geologic framework, including paleodrainage patterns across the shelf and to identify potential fish habitat locations that will provide additional inputs to a thematic habitat mapping routine developed by NOAA. Results from the thematic mapper characterization suggest that large-scale framework elements such as paleochannel networks may play a role in determining benthic …

Graph Analytics Methods In Feature Engineering, Theophilus Siameh

Electronic Theses and Dissertations

High-dimensional data sets can be difficult to visualize and analyze, while data in low-dimensional space tend to be more accessible. In order to aid visualization of the underlying structure of a dataset, the dimension of the dataset is reduced. The simplest approach to accomplish this task of dimensionality reduction is by a random projection of the data. Even though this approach allows some degree of visualization of the underlying structure, it is possible to lose more interesting underlying structure within the data. In order to address this concern, various supervised and unsupervised linear dimensionality reduction algorithms have been designed, such …

A Framework For Clustering And Adaptive Topic Tracking On Evolving Text And Social Media Data Streams., Gopi Chand Nutakki

Electronic Theses and Dissertations

Recent advances and widespread usage of online web services and social media platforms, coupled with ubiquitous low cost devices, mobile technologies, and increasing capacity of lower cost storage, has led to a proliferation of Big data, ranging from, news, e-commerce clickstreams, and online business transactions to continuous event logs and social media expressions. These large amounts of online data, often referred to as data streams, because they get generated at extremely high throughputs or velocity, can make conventional and classical data analytics methodologies obsolete. For these reasons, the issues of management and analysis of data streams have been researched extensively …

Functional Data Analysis Methods For Predicting Disease Status., Sarah Kendrick

Electronic Theses and Dissertations

Introduction: Differential scanning calorimetry (DSC) is used to determine thermally-induced conformational changes of biomolecules within a blood plasma sample. Recent research has indicated that DSC curves (or thermograms) may have different characteristics based on disease status and, thus, may be useful as a monitoring and diagnostic tool for some diseases. Since thermograms are curves measured over a range of temperature values, they are often considered as functional data. In this dissertation we propose and apply functional data analysis (FDA) techniques to analyze DSC data from the Lupus Family Registry and Repository (LFRR). The aim is to develop FDA methods to …

Chemoselective Reagents For Derivatization Of Trace--Level Volatile Carbonyl Compounds Using A Microreactor Approach., Mumiye A. Ogunwale

Electronic Theses and Dissertations

Detection and analysis of trace level volatile aldehydes and ketones has become a significant research frontier because of the applicability for environmental monitoring and assessment, noninvasive diseases diagnosis, and in food safety assessment for the US Food and Drug Administration. The number of derivatization reagents for detection of aldehydes and ketones has increased considerably over the last decade. However, the majority of these derivatization reagents are not efficient in derivatizing unsaturated carbonyl compounds due to the presence of electron withdrawing groups adjacent to the reactive functional moieties making them insufficiently nucleophilic. The analysis of trace-level carbonyl compounds challenges existing analytical …

Sample Size Calculations And Normalization Methods For Rna-Seq Data., Xiaohong Li

Electronic Theses and Dissertations

High-throughput RNA sequencing (RNA-seq) has become the preferred choice for transcriptomics and gene expression studies. With the rapid growth of RNA-seq applications, sample size calculation methods for RNA-seq experiment design and data normalization methods for DEG analysis are important issues to be explored and discussed. The underlying theme of this dissertation is to develop novel sample size calculation methods in RNA-seq experiment design using test statistics. I have also proposed two novel normalization methods for analysis of RNA-seq data. In chapter one, I present the test statistical methods including Wald’s test, log-transformed Wald’s test and likelihood ratio test statistics for …

Artificial Olfactory System For Multi-Component Analysis Of Gas Mixtures., Alexander Aleksandrovich Larin

Electronic Theses and Dissertations

Gas analysis is an important part of our world and gas sensing technology is becoming more essential for various aspects of our life. A novel approach for gas mixture analysis by using portable gas chromatography in combination with an array of highly integrated and selective metal oxide (MOX) sensors has been studied. We developed a system with small size (7 x 13 x 16 inches), low power consumption (~10 W) and absence of special carrier gases designed for portable field analysis (assuming apriori calibration). Low ppb and even sub-ppb level of detection for some VOCs was achieved during the analysis …

Nonspreading Solutions In Integro-Difference Models With Allee And Overcompensation Effects., Garrett Luther Otto

Electronic Theses and Dissertations

Previous work in Integro-Difference models have generally considered Allee effects and over-compensation separately, and have either focused on bounded domain problems or asymptotic spreading results. Some recent results by Sullivan et al. (2017 PNAS 114(19), 5053-5058) combining Allee and over-compensation in an Integro-Difference framework have shown chaotic fluctuating spreading speeds. In this thesis, using a tractable parameterized growth function, we analytically demonstrate that when Allee and over-compensation are present solutions which persist but essentially remain in a compact domain exist. We investigate the stability of these solutions numerically. We also numerically demonstrate the existence of such solutions for more general …

Numerical Investigation Of Drop Impingement On Dry And Wet Surfaces., Yisen Guo

Electronic Theses and Dissertations

In-flight icing due to supercooled large droplets (SLDs) imposes great danger on aviation safety. Because of the large size, SLDs have different characteristics than typical cloud droplets that most icing encounters involve. As a result, SLDs more likely hit the wing surface and move into areas not protected by de-icing devices to form ice, which can lead to loss of lift, increase in drag, altered controllability, and eventually stall and loss of control of the aircraft. The phenomenon of droplet splashing is considered as the most important aspect of the SLD icing accretion problem. Although previous studies have established splashing …

Greater London In The 21st Century : Assessing Coastal Flooding Mitigation Preparedness And Regional Population Risk In The Face Of Projected Sea-Level Rise., Nathan K Wright

Electronic Theses and Dissertations

Recent projections of +6-9m sea-level rise (SLR) over the next several decades present many social challenges for coastal regions during the 21^st century. These projections were applied to Greater London, UK as areal interpolated historical census data was overlaid on a 50m DEM alongside a polyline projection of the Thames Barrier. Population was projected to milestones of 2041, 2071, and 2101 using a capped, aggregated growth rate for each polygon while SLR was simulated for 1m, 5m, and 9m scenarios. The Thames Barrier maintained integrity for 1m and 5m scenarios but was breached at 9m. Population continued to increase …

Evaluating Ligand Assisted Activation Of Small Molecules Through Proton Reduction And Alcohol Oxidation., Rahul Jain

Electronic Theses and Dissertations

Hydrogen is a potential alternate to the carbon fuels to meet the future demands for energy in an eco-friendly manner. Hydrogen produced by the electrolysis of water is stored in fuel cells which on demand can be converted into electrical energy upon the reaction with oxygen. In the quest for economically viable electrocatalysts for hydrogen evolution, the work in this dissertation describes evaluation of nickel based catalysts coordinated to redox active ligands, dialkyl/diarylphosphine benzenethiol and bis(thiosemicarbazone) for their ability to generate hydrogen with external acids as a proton source. A nickel complex with the benzenethiol ligand framework follows a traditional …

All-Optical Switching In Ferromagnetic Superlattices., Faren Hoveyda Marashi

Electronic Theses and Dissertations

The unexpected observation of ultrafast demagnetization (UDM) and subsequent time-resolved studies of laser-induced magnetization switching opened a new door to both fundamental physics and technological applications of magnetic materials. All-optical switching (AOS) can be initiated faster than the precession limit, hinting to its potential in increasing the writing speed and data storage density. However, notwithstanding considerable research interest, the mechanism of AOS in ferromagnetic materials remained unclear.

Ferromagnetic superlattices were deposited on glass substrates with e-beam evaporation and sputtering. Magnetization curves were measured in magneto-optical and vibrating sample magnetometer experiments. A femtosecond Ti:S laser was utilized in a writing setup …

Geophysical Delineation Of Megaporosity And Fluid Migration Pathways For Geohazard Characterization Within The Delaware Basin, Culberson County, Texas, Jonathan David Woodard

Electronic Theses and Dissertations

ABSTRACT

Differential dissolution of gypsum karst within the Delaware Basin poses a significant threat to infrastructure that society depends on. The study area is located in Culberson County, Texas and traverses a distance of approximately 54 kilometers along RM 652 within the Gypsum Plain which is situated on the northern margin of the Chihuahua Desert and includes outcrops of Castile and Rustler strata that host karst geohazards. Regions of karst geohazard potential have been physically surveyed proximal to the study area in evaporites throughout the Castile Formation outcrop; minimal hazards, in comparison to the Castile Formation, have been documented in …

Water Chemistry Dynamics In Four Vernal Pools In Maine, Usa, Lydia H. Kifner

Electronic Theses and Dissertations

Vernal pools are small seasonal wetlands that are a common landscape feature that contribute to biodiversity in northeastern North American forests. However, even basic information about their biogeochemical functions, such as carbon cycling, is limited. Dissolved gas concentrations (CH₄, CO₂) and other water chemistry parameters were monitored weekly at the bottom and surface of four vernal pools in central and eastern Maine, USA, from April to August 2016. The vernal pools were supersaturated with respect to CH₄ and CO₂ at all sampling dates and locations. Concentrations of dissolved CH₄ and CO₂ ranged …

Transformation Of Nonlinear Waves In The Presence Of Wind, Current, And Vegetation, Haifei Chen

Electronic Theses and Dissertations

Accurate prediction of extreme wave events is crucial for the safe maritime activities and offshore operations. Improved knowledge of wave dissipation mechanisms due to breaking and vegetation leads to accurate wave forecast, protecting life and property along the coast. The scope of the thesis is to examine the wave transformations in the presence of wind, current, and vegetation, using a two-phase flow solver based on the open-source platform OpenFOAM. The Reynolds-Averaged Navier-Stokes (RANS) equations are coupled with a Volume of Fluid (VOF) surface capturing scheme and a turbulence closure model. This RANS-VOF model is adapted to develop a numerical wind-wave-current …

Authorship Identification Of Translation Algorithms., Keishin Nishiyama

Electronic Theses and Dissertations

Authorship analysis is a process of identifying a true writer of a given document and has been studied for decades. However, only a handful of studies of authorship analysis of translators are available despite the fact that online translations are widely available and also popularly employed in automatic translations of posts in social networking services. The identification of translation algorithms has potential to contribute to the investigation of cybercrimes, involving translation of scam messages by algorithmic translations to reach speakers of foreign languages. This study tested bag of words (BOW) approach in authorship attribution and the existing approaches to translator …

Only The Earth Remains: Exploring The Machine In Selected Lyric Poetry Of Robinson Jeffers, Mark Hutton

Electronic Theses and Dissertations

In The Machine in the Garden: Technology and the Pastoral Idea in America, Leo Marx “evaluates the uses of the pastoral ideal in the interpretation of American experience” (Marx 4). While Marx explores ways that pastoralism has been impacted by factors such as industrialism, it is the purpose of this project to explore Marx’s assertion regarding the presence of the figurative and literal machine within the poetry of Robinson Jeffers.

Jeffers’ poetry is generally located within the landscapes of California. His lyric poetry has a distinct connection to the land and is driven by inhumanism, which works to shift …

Study Of 2,5-Diaminoimidazolone, A Mutagenic Product Of Oxidation Of Guanine In Dna, Hannah Catherine J. Pollard

Electronic Theses and Dissertations

2,5-diaminoimidazolone (Iz) is an important product of a 4-electron oxidation of guanine. The present research focuses on the mechanisms of formation of Iz via pathways initiated by guanine oxidation by one-electron oxidants (OEOs) generated by X-ray radiolysis in aqueous solutions. The kinetics of formation and yields of Iz in reactions of native highly polymerized DNA with different OEOs have been compared using an HPLC-based quantitative analysis of low-molecular products generated from the reaction of DNA-bound Iz with primary amines. Mechanisms of Iz formation in DNA have been investigated including oxygen and superoxide dependence as well as the hypothesis that 8-oxo-G, …

Spatially Explicit Model Of Areas Between Suitable Black Bear Habitat In East Texas And Black Bear Populations In Louisiana, Arkansas, And Oklahoma, Caitlin M. Glymph, Christopher Comer, Daniel Scognamillo, Daniel Unger, Yanli Zhang

Electronic Theses and Dissertations

Although black bears (Ursus americanus, Ursus americanus luteolus) were once found throughout the south-central United States, unregulated harvest and habitat loss resulted in severe range retractions and by the beginning of the twentieth century populations in Oklahoma, Louisiana, Texas and Arkansas were nearing extirpation. In response to these losses, translocation programs were initiated in Arkansas (1958-1968 & 2000-2006) and Louisiana (1964-1967 & 2001-2009). These programs successfully restored bears to portions of Louisiana and Arkansas, and, as populations in Arkansas began dispersing, to Oklahoma. In contrast, east Texas remains unoccupied despite the existence of suitable habitat in the region.

To facilitate …

The Sequence Stratigraphic Context Of Mixed Basin Margin Evaporites In The Harrisburg Member Of The Permian Kaibab Formation, Northern Arizona And Southern Utah, Cole Hendrickson

Electronic Theses and Dissertations

The Kaibab Formation is a mixed carbonate system including evaporites and siliciclastics deposited on a westward dipping epeiric carbonate ramp during the middle Permian in northern Arizona, southern Utah, and eastern Nevada. It consists of the Fossil Mountain Member deposited in open-marine conditions and the overlying Harrisburg Member deposited in restricted conditions. The Harrisburg Member includes facies and depositional environments ranging from open-marine shallow-subtidal wackestone - packstone, restricted subtidal dolomitic mudstone, dolomitic sandstone, peritidal oolitic grainstone as well as gypsum and red siltstones deposited in a sabkha environment.

Fourteen stratigraphic sections were measured across northern Arizona and southern Utah to …

Integrated Environment And Proximity Sensing For Uav Applications, Shawn S. Brackett

Electronic Theses and Dissertations

As Unmanned Aerial Vehicle (UAV), or “drone” applications expand, new methods for sensing, navigating and avoiding obstacles need to be developed. The project applies an Extended Kalman Filter (EKF) to a simulated quadcopter vehicle though Matlab in order to estimate not only the vehicle state but the world state around the vehicle. The EKF integrates multiple sensor readings from range sensors, IMU sensors, and radiation sensors and combines this information to optimize state estimates. The result is an estimated world map to be used in vehicle navigation and obstacle avoidance.

The simulation handles the physics behind the vehicle flight. As …

Using Hydroacoustics To Investigate Biological Responses In Fish Abundance To Restoration Efforts In The Penobscot River, Maine, Constantin C. Scherelis

Electronic Theses and Dissertations

Spatiotemporal advantages linked to hydroacoustic sampling techniques have caused a surge in the use of these techniques for fisheries monitoring studies applied over long periods of time in marine systems. Dynamic physical conditions such as tidal height, boat traffic, floating debris, and suspended particle concentrations result in unwanted noise signatures that vary in intensity and location within a hydroacoustic beam over time and can be mixed with the acoustic returns from intended targets (e.g., fish). Typical processing filters applied over long term datasets to minimize noise and maximize signals do not address spatiotemporal fluctuations of noise in dynamic systems. We …

Renewable Hydrogels From Norbornene-Functionalized Carboxymethyl Cellulose And A Short Dithiol Crosslinked Via A Thiol-Ene Reaction, Thomas Mcoscar

Electronic Theses and Dissertations

Cellulose-based hydrogels - three dimensional "solid" structures composed primarily of liquid water and held together by an interconnected polymer network - were created by first functionalizing carboxymethyl cellulose (CMC), a cellulose derivative, with carbic anhydride in a basic aqueous reaction with the intent of developing novel hydrogels from renewable materials. The product of this reaction, carbic CMC (cCMC), had a new norbornene group as a subsection of the carbic group. Norbornene is a reactive alkene structure that allows for further chemistry with cCMC, such as crosslinking. cCMC was crosslinked with 2,2'-(ethylenedioxy)diethathiol to create hydrogels using a water-soluble, UV-sensitive radical initiator …

Oyster Aquaculture Site Selection Using Landsat 8-Derived Sea Surface Temperature, Turbidity, And Chlorophyll A., Jordan Snyder

Electronic Theses and Dissertations

Remote sensing data is useful for selection of aquaculture sites because it can provide water-quality products mapped with no cost to users. However, the spatial resolution of most ocean color satellites is too coarse to provide usable data within many estuaries. The more recently launched Landsat 8 satellite has both the spatial resolution and the necessary signal to noise ratio to provide temperature, as well as ocean color derived products along complex coastlines. The state of Maine (USA) has an abundance of estuarine indentations (~3,500 miles of tidal shoreline within 220 miles of coast), and an expanding aquaculture industry, which …

Creating Renewable Tunable Polymers From Hydroxymethylfurfural, Meredith C. Allen

Electronic Theses and Dissertations

The research here deals with the conversion of 5-hydroxymethylfurfural (HMF) into a tunable polymer. HMF is a known derivative that can be acquired from biomass via hydrolysis of cellulose followed by isomerization and finally selective dehydration. The process considered here is being developed to create tunable polymers from HMF and involves several different steps, three of which are covered here. The first step, an etherification, is the reaction of HMF with an alcohol. This step is significant because in this step the R-group from the alcohol is added to HMF and the branching portion formed is carried over to the …

In Situ Dating Of Multiple Events In Granulite-Facies Rocks Of The Larsemann Hills, Prydz Bay, East Antarctica Using Electron Microprobe Analysis Of Monazite, Steven K. Spreitzer

Electronic Theses and Dissertations

The metamorphic rocks exposed along the southeast coast of Prydz Bay were affected by several metamorphic and plutonic events associated with collision in the Neoproterozoic and Cambrian. Critical units exposed in the Larsemann Hills and nearby ice-free areas include (1) basement Søstrene Orthogneiss, (2) cover sequence Brattstrand Paragneiss and (3) anatectic pegmatites intrusive into the Brattstrand Paragneiss. Zircon U-Pb data from previous studies yielded a maximum depositional age of 1023 ± 19 Ma for the Brattstrand Paragneiss, but only approximate ca. 900 Ma to ca. 1000 Ma and ca. 530 Ma ages for two metamorphic events. In order to constrain …