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Full-Text Articles in Physical Sciences and Mathematics
Effect Of Strain On Muon Diffusion And Trapping In Metal By Bassam Salim Hitti, Bassam Salim Hitti
Effect Of Strain On Muon Diffusion And Trapping In Metal By Bassam Salim Hitti, Bassam Salim Hitti
Dissertations, Theses, and Masters Projects
Positive muons implanted in metal distort the surrounding lattice; therefore, in addition to electronic interactions, the elastic forces have to be considered in determining the muon state. to explore the elastic and electronic diffusion and trapping mechanisms, we studied AlCu(,420ppm), AlMg(,1000ppm) and AlAg(,1000ppm) alloys. These alloys were selected for the different effects on the host lattice of these impurities; Cu contracts the Al lattice, Mg expands it and Ag has nearly no effect. On the other hand Cu and Ag are monovalent while Mg is divalent. For AlCu between 5K and 14K the temperature exponent (beta) of the two-state-model trapping …
Determination Of The Vacancy Migration Energy Of Aluminum By Nmr, Terry William Gullion
Determination Of The Vacancy Migration Energy Of Aluminum By Nmr, Terry William Gullion
Dissertations, Theses, and Masters Projects
Monovacancy diffusion is a thermally activated process characterized by an activation energy E(,d). The diffusion of atoms requires the formation and migration of vacancies. The concentration of vacancies n/N is given by n/N (DBLTURN) exp(-E(,f)/kT). It can be shown that the activation energy E(,d) is the sum of the energy to form a vacancy E(,f) and the energy required for an atomic jump E(,m): E(,d) = E(,f) + E(,m). Furthermore, the atomic jump rate (omega)(,j) can be shown to be thermally activated and given by (omega)(,j) (DBLTURN) (nu)(,o)(n/N)exp(-E(,m)/kT) ((nu)(,o) is the attempt frequency).;NMR offers many techniques to measure the activation …
A Nuclear Magnetic Resonance Study Of Deuterated Poly(Vinylidene Fluoride) And A Copolymer Of Deuterated Vinylidene Fluoride And Tetrafluoroethylene, Montee A. Doverspike
A Nuclear Magnetic Resonance Study Of Deuterated Poly(Vinylidene Fluoride) And A Copolymer Of Deuterated Vinylidene Fluoride And Tetrafluoroethylene, Montee A. Doverspike
Dissertations, Theses, and Masters Projects
Pulsed deuterium NMR experiments have been performed on deuterated samples of poly(vinylidene fluoride), PVF(,2), repeat unit CH(,2)CF(,2) and the copolymer poly(vinylidene fluoride)-tetrafluoroethylene (80-20), (PVF(,2)-F(,4)E). A deuterium line shape study has been employed to characterize the orientational distribution of the dipole moments in both poled and unpoled samples. In addition, the orientational distributions of chain axis alignment has been measured in stretched samples.;PVF(,2) and PVF(,2)-F(,4)E exhibit unique piezoelectric and pyroelectric properties which are due to their crystalline components (approximately 50% in typical material). Four crystalline phases exist in the homopolymer PVF(,2), the (alpha), (beta), (gamma), and the (delta). The relatively electrically …