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Gas Phase Laser Induced Fluorescence Spectroscopy Of Cfcl, Stephen E. Bialkowski, David S. King, John C. Stephenson
Gas Phase Laser Induced Fluorescence Spectroscopy Of Cfcl, Stephen E. Bialkowski, David S. King, John C. Stephenson
Stephen E. Bialkowski
The CFCl radical has been produced in the gas phase by both IR multiphotonphotolysis of C2F3Cl and He metastable reaction with C2F3Cl. Single vibronic level fluorescence and excitation spectra taken of this species have yielded sufficient information to determine certain vibronic constants. The excited state was found to have an origin of T0=25 283±5 cm−1 with vibrational frequencies: ω2′=394±3 cm−1 and ω3′=739±5 cm−1. In the ground state, the vibrational frequencies were found to be: ω3″=118±10 cm−1, ω2″=448±6 cm …