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Missouri University of Science and Technology

2001

Articles 1 - 30 of 42

Full-Text Articles in Physical Sciences and Mathematics

Effect Of Rare Locally Ordered Regions On A Disordered Itinerant Quantum Antiferromagnet With Cubic Anisotropy, Rajesh S. Narayanan, Thomas Vojta Dec 2001

Effect Of Rare Locally Ordered Regions On A Disordered Itinerant Quantum Antiferromagnet With Cubic Anisotropy, Rajesh S. Narayanan, Thomas Vojta

Physics Faculty Research & Creative Works

We study the quantum phase transition of an itinerant antiferromagnet with cubic anisotropy in the presence of quenched disorder, paying particular attention to the locally ordered spatial regions that form in the Griffiths region. We derive an effective action where these rare regions are described in terms of static annealed disorder. A one-loop renormalization-group analysis of the effective action shows that for order-parameter dimensions p<4, the rare regions destroy the conventional critical behavior, and the renormalized disorder flows to infinity. For order-parameter dimensions p>4, the critical behavior is not influenced by the rare regions; it is described by the conventional dirty cubic fixed point. We also discuss the influence of the rare regions on the fluctuation-driven first-order transition …

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Electron-Impact Excitation To The 4p⁵5s And 4p⁵5p Levels Of Kr | Using Different Distorted-Wave And Close-Coupling Methods, Arati K. Dasgupta, Klaus Bartschat, D. Vaid, Alexei N. Grum-Grzhimailo, Don H. Madison, Milan Blaha, John L. Giuliani Nov 2001

Electron-Impact Excitation To The 4p⁵5s And 4p⁵5p Levels Of Kr | Using Different Distorted-Wave And Close-Coupling Methods, Arati K. Dasgupta, Klaus Bartschat, D. Vaid, Alexei N. Grum-Grzhimailo, Don H. Madison, Milan Blaha, John L. Giuliani

Physics Faculty Research & Creative Works

Electron-impact excitation of the 4p55s and 4p55p levels of Kr I has been investigated in detail by calculating cross sections using distorted-wave and close-coupling approaches. The results are presented from the excitation thresholds up to 50 eV incident energy. They are contrasted among the different calculations and compared with other theoretical predictions and experimental data. Significant disagreement is found with many of the recent experimental data of Chilton et al. [Phys. Rev. A 62, 032714 (2000)].

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Three-Body Coulomb Problem Probed By Mapping The Bethe Surface In Ionizing Ion-Atom Collisions, Robert Moshammer, Appathurai N. Perumal, Michael Schulz, V. D. Rodriguez, Holger Kollmus, Rido Mann, Siegbert Hagmann, Joachim Hermann Ullrich Nov 2001

Three-Body Coulomb Problem Probed By Mapping The Bethe Surface In Ionizing Ion-Atom Collisions, Robert Moshammer, Appathurai N. Perumal, Michael Schulz, V. D. Rodriguez, Holger Kollmus, Rido Mann, Siegbert Hagmann, Joachim Hermann Ullrich

Physics Faculty Research & Creative Works

The three-body Coulomb problem has been explored in kinematically complete experiments on single ionization of helium by 100 MeV / u C 6 + and 3.6 MeV / u u 5 3 + impact. Low-energy electron emission (E e < 150 eV ) as a function of the projectile deflection ϑ p (momentum transfer), i.e., the Bethe surface [[15]], has been mapped with Δ ϑ p ± 25 nanoradian resolution at extremely large perturbations (3.6 MeV / uAu53+ ) where single ionization occurs at impact parameters of typically 10 times the He K -shell radius. The experimental data are not in agreement with state-of-the-art continuum distorted wave-eikonal initial state theory.

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Highly Plasma Etch-Resistant Photoresist Composition Containing A Photosensitive Polymeric Titania Precursor, Tony D. Flaim, Douglas J. Guerrero, Michelle R. Fowler, William Joseph James, Vladimir Petrovsky, Harlan U. Anderson Oct 2001

Highly Plasma Etch-Resistant Photoresist Composition Containing A Photosensitive Polymeric Titania Precursor, Tony D. Flaim, Douglas J. Guerrero, Michelle R. Fowler, William Joseph James, Vladimir Petrovsky, Harlan U. Anderson

Chemistry Faculty Research & Creative Works

A composition is derived from an addition polymerizable organotitanium polymer which upon exposure to an oxygen plasma or baking in air, is converted to titanium dioxide (titania) or is converted to a mixed, titanium-containing metal oxide. The metal oxide formed in situ imparts etch- resistant action to a patterned photoresist layer. The composition may also be directly deposited and patterned into permanent metal oxide device features by a photolithographic process.

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Magnetic Properties Of The Mnbi Intermetallic Compound, Jinbo Yang, Kishore Kamaraju, William B. Yelon, William Joseph James, Qingsheng Cai, A. Bollero Sep 2001

Magnetic Properties Of The Mnbi Intermetallic Compound, Jinbo Yang, Kishore Kamaraju, William B. Yelon, William Joseph James, Qingsheng Cai, A. Bollero

Physics Faculty Research & Creative Works

A MnBi alloy containing over 90 wt% low-temperature phase (LTP) has been obtained by high-temperature sintering and magnetic purification. The coercivity of the bonded MnBi magnet increases with increasing temperatures. A coercivity of 2.0 T has been achieved at 400 K. The maximum energy product (BH)max; of the magnet is 7.7 MGOe (61 kJ/m3) and 4.6 MGOe (37 kJ/m3) at room temperature and 400 K, respectively. Neutron diffraction and magnetic data reveal a spin reorientation, which gives rise to low anisotropy fields and coercivity at lower temperatures for the LTP MnBi alloy.

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Nature Of Charge Carriers In Disordered Molecular Solids: Are Polarons Compatible With Observations?, Paul Ernest Parris, Vasudev M. Kenkre, David H. Dunlap Sep 2001

Nature Of Charge Carriers In Disordered Molecular Solids: Are Polarons Compatible With Observations?, Paul Ernest Parris, Vasudev M. Kenkre, David H. Dunlap

Physics Faculty Research & Creative Works

Polaronic theories for charge transport in disordered organic solids, particularly molecularly doped polymers, have been plagued by issues of internal consistency related to the magnitude of physical parameters. We present a natural resolution of the problem by showing that, in the presence of correlated disorder, polaronic carriers with binding energies Δ ~ 50 - 500 meV and transfer integrals J ~ 1 - 20 meV are completely consistent with the magnitudes of field and temperature dependent mobilities observed.

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Tunable Local Polariton Modes In Semiconductors, Michael G. Foygel, Alexey Yamilov, Lev I. Deych, Alexander A. Lisyansky Sep 2001

Tunable Local Polariton Modes In Semiconductors, Michael G. Foygel, Alexey Yamilov, Lev I. Deych, Alexander A. Lisyansky

Physics Faculty Research & Creative Works

We study the local states within the polariton band gap that arise due to deep defect centers with strong electron-phonon coupling. Electron transitions involving deep levels may result in alteration of local elastic constants. In this case, substantial reversible transformations of the impurity polariton density of states occur, which include the appearance/disappearance of the polariton impurity band, and its shift and/or the modification of its shape. These changes can be induced by thermo- and photoexcitation of the localized electron states or by trapping of injected charge carriers. We develop a simple model, which is applied to the Op center …

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Strong Enhancement Of Superconducting TC In Ferromagnetic Phases, Theodore R. Kirkpatrick, Dietrich Belitz, Thomas Vojta, Rajesh S. Narayanan Sep 2001

Strong Enhancement Of Superconducting TC In Ferromagnetic Phases, Theodore R. Kirkpatrick, Dietrich Belitz, Thomas Vojta, Rajesh S. Narayanan

Physics Faculty Research & Creative Works

It is shown that the critical temperature for spin-triplet, p-wave superconductivity mediated by spin fluctuations is generically much higher in a Heisenberg ferromagnetic phase than in a paramagnetic one, due to the coupling of the magnons to the longitudinal magnetic susceptibility. Together with the tendency of the low-temperature ferromagnetic transition in very clean Heisenberg magnets to be of first order, this qualitatively explains the phase diagram recently observed in UGe2.

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Quantum Phase Transition Of Itinerant Helimagnets, Thomas Vojta, Rastko Sknepnek Aug 2001

Quantum Phase Transition Of Itinerant Helimagnets, Thomas Vojta, Rastko Sknepnek

Physics Faculty Research & Creative Works

We investigate the quantum phase transition of itinerant electrons from a paramagnet to a state which displays long-period helical structures due to a Dzyaloshinskii instability of the ferromagnetic state. In particular, we study how the self-generated effective long-range interaction recently identified in itinerant quantum ferromagnets is cut off by the helical ordering. We find that for a sufficiently strong Dzyaloshinskii instability the helimagnetic quantum phase transition is of second order with mean-field exponents. In contrast, for a weak Dzyaloshinskii instability the transition is analogous to that in itinerant quantum ferromagnets, i.e., it is of first order, as has been observed …

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Magnetic And Conversion Electron Mössbauer Spectral Study Of Amorphous Thin Films Of Dyₓfe₁₀₀₋ₓ And Dy₂₀Fe80-YCoY, Karl Fleury-Frenette, Jacques P. Delwiche, Fernande Grandjean, Denis Vandormael, Gary J. Long Aug 2001

Magnetic And Conversion Electron Mössbauer Spectral Study Of Amorphous Thin Films Of Dyₓfe₁₀₀₋ₓ And Dy₂₀Fe80-YCoY, Karl Fleury-Frenette, Jacques P. Delwiche, Fernande Grandjean, Denis Vandormael, Gary J. Long

Chemistry Faculty Research & Creative Works

Amorphous thin films of DyxFe100-x and Dy20Fe80-yCoy, with various x and y values and of ~40 nm thickness, have been prepared by sputtering on polyimide films. Their magnetization curves and the Mössbauer spectra indicate that at 295 K the iron moments are preferentially oriented parallel to the film in Dy2Fe98 and that Dy6Fe94 is paramagnetic. The DyxFe100-x thin films, where x is 17, 20, 24, 29, 32, 35, and 37, show perpendicular magnetic anisotropies and moderate coercive fields of at most 150 …

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Local Polariton Modes And Resonant Tunneling Of Electromagnetic Waves Through Periodic Bragg Multiple Quantum Well Structures, Lev I. Deych, Alexey Yamilov, Alexander A. Lisyansky Jul 2001

Local Polariton Modes And Resonant Tunneling Of Electromagnetic Waves Through Periodic Bragg Multiple Quantum Well Structures, Lev I. Deych, Alexey Yamilov, Alexander A. Lisyansky

Physics Faculty Research & Creative Works

We study analytically defect polariton states in Bragg multiple quantum well structures and defect-induced changes in transmission and reflection spectra. Defect layers can differ from the host layers in three ways: exciton-light coupling strength, exciton resonance frequency, and interwell spacing. We show that a single defect leads to two local polariton modes in the photonic band gap. These modes cause peculiarities in reflection and transmission spectra. Each type of defect can be reproduced experimentally, and we show that each of these plays a distinct role in the optical properties of the system. For some defects, we predict a narrow transmission …

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Mantle Deformation Beneath Southern Africa, Paul G. Silver, Stephen S. Gao, Kelly H. Liu, Kaapvaal Seismic Group Jul 2001

Mantle Deformation Beneath Southern Africa, Paul G. Silver, Stephen S. Gao, Kelly H. Liu, Kaapvaal Seismic Group

Geosciences and Geological and Petroleum Engineering Faculty Research & Creative Works

Seismic anisotropy from the southern African mantle has been inferred from shear-wave splitting measured at 79 sites of the Southern African Seismic Experiment. These data provide the most dramatic support to date that Archean mantle deformation is preserved as fossil mantle anisotropy. Fast polarization directions systematically follow the trend of Archean structures and splitting delay times exhibit geologic control. The most anisotropic regions are Late-Archean in age (Zimbabwe craton, Limpopo belt, western Kaapvaal craton), with delay times reduced dramatically in off-craton regions to the southwest and Early-Archean regions to the southeast. While thin lithosphere can account for weak off-craton splitting, …

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Separation Of Recollision Mechanisms In Nonsequential Strong Field Double Ionization Of Ar: The Role Of Excitation Tunneling, Bernold Feuerstein, Daniel Fischer, Alexander Dorn, Claus Dieter Schroter, J. Deipenwisch, Jose R. Crespo Lopez-Urrutia, C. Hohr, Paul B. Neumayer, Horst Rottke, Christoph Trump, M. Wittmann, Georg Korn, Wolfgang Sandner, Robert Moshammer, Joachim Hermann Ullrich Jul 2001

Separation Of Recollision Mechanisms In Nonsequential Strong Field Double Ionization Of Ar: The Role Of Excitation Tunneling, Bernold Feuerstein, Daniel Fischer, Alexander Dorn, Claus Dieter Schroter, J. Deipenwisch, Jose R. Crespo Lopez-Urrutia, C. Hohr, Paul B. Neumayer, Horst Rottke, Christoph Trump, M. Wittmann, Georg Korn, Wolfgang Sandner, Robert Moshammer, Joachim Hermann Ullrich

Physics Faculty Research & Creative Works

Vector momentum distributions of two electrons created in double ionization of Ar by 25 fs, 0.25PW/cm2 laser pulses at 795 nm have been measured using a “reaction microscope.” At this intensity, where nonsequential ionization dominates, distinct correlation patterns are observed in the two-electron momentum distributions. A kinematical analysis of these spectra within the classical “recollision model” revealed an (e,2e)-like process and excitation with subsequent tunneling of the second electron as two different ionization mechanisms. This allows a qualitative separation of the two mechanisms demonstrating that excitation-tunneling is the dominant contribution to the total double ionization yield.

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Resummation Of The Divergent Perturbation Series For A Hydrogen Atom In An Electric Field, Ulrich D. Jentschura Jul 2001

Resummation Of The Divergent Perturbation Series For A Hydrogen Atom In An Electric Field, Ulrich D. Jentschura

Physics Faculty Research & Creative Works

We consider the resummation of the perturbation series describing the energy displacement of a hydrogenic bound state in an electric field (known as the Stark effect or the LoSurdo-Stark effect), which constitutes a divergent formal power series in the electric-field strength. The perturbation series exhibits a rich singularity structure in the Borel plane. Resummation methods are presented that appear to lead to consistent results even in problematic cases where isolated singularities or branch cuts are present on the positive and negative real axis in the Borel plane. Two resummation prescriptions are compared: (i) a variant of the Borel-Pad'e resummation method, …

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Scaling In One-Dimensional Localized Absorbing Systems, Lev I. Deych, Alexey Yamilov, Alexander A. Lisyansky Jun 2001

Scaling In One-Dimensional Localized Absorbing Systems, Lev I. Deych, Alexey Yamilov, Alexander A. Lisyansky

Physics Faculty Research & Creative Works

Numerical study of the scaling of transmission fluctuations in the one-dimensional localization problem in the presence of absorption is carried out. Violations of single-parameter scaling for lossy systems are found and explained on the basis of a new criterion for different types of scaling behavior derived by Deych et al.

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Electronic Structure Of Superconducting Mgb₂ And Related Binary And Ternary Borides, Nadezhda I. Medvedeva, Alexander L. Ivanovskii, Julia E. Medvedeva, Arthur J. Freeman Jun 2001

Electronic Structure Of Superconducting Mgb₂ And Related Binary And Ternary Borides, Nadezhda I. Medvedeva, Alexander L. Ivanovskii, Julia E. Medvedeva, Arthur J. Freeman

Physics Faculty Research & Creative Works

First-principles full potential linear muffin-tin orbital-generalized gradient approximation electronic structure calculations of the new medium-Tc superconductor (MTSC) MgB2 and related diborides indicate that superconductivity in these compounds is related to the existence of Px,y-band holes at the γ point. Based on these calculations, we explain the absence of medium-Tc superconductivity for BeB2, AlB2, ScB2, and YB2. The simulation of a number of MgB2-based ternary systems using a supercell approach demonstrates that (i) the electron doping of MgB2 (i.e., MgB2-yXy with X=Be, …

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Electron Self-Energy For The K And L Shells At Low Nuclear Charge, Ulrich D. Jentschura, Peter J. Mohr, Gerhard Soff Apr 2001

Electron Self-Energy For The K And L Shells At Low Nuclear Charge, Ulrich D. Jentschura, Peter J. Mohr, Gerhard Soff

Physics Faculty Research & Creative Works

A nonperturbative numerical evaluation of the one-photon electron self-energy for the K- and L-shell states of hydrogenlike ions with nuclear charge numbers Z =1 to 5 is described. Our calculation for the 1S1/2 state has a numerical uncertainty of 0.8 Hz in atomic hydrogen, and for the L-shell states (2S1/2 , 2P1/2 , and 2P3/2) the numerical uncertainty is 1.0 Hz. The method of evaluation for the ground state and for the excited states is described in detail. The numerical results are compared to results based on known terms in the expansion of the self-energy …

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Surfactant-Assisted Synthesis Of Semiconductor Nanotubes And Nanowires, Chintamani Nagesa Ramachandra Rao, A. Govindaraj, F. L. Deepak, N. A. Gunari, Manashi Nath Mar 2001

Surfactant-Assisted Synthesis Of Semiconductor Nanotubes And Nanowires, Chintamani Nagesa Ramachandra Rao, A. Govindaraj, F. L. Deepak, N. A. Gunari, Manashi Nath

Chemistry Faculty Research & Creative Works

Nanotubes and nanowires of CdSe and CdS have been obtained from solutions containing a surfactant such as Triton 100-X. They have been characterized by x-ray diffraction, electron microscopy, and optical spectroscopy.

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Open Strings, 2d Gravity, And Ads/Cft Correspondence, Mariano Cadoni, Marco Cavaglia Mar 2001

Open Strings, 2d Gravity, And Ads/Cft Correspondence, Mariano Cadoni, Marco Cavaglia

Physics Faculty Research & Creative Works

We present a detailed discussion of the duality between dilaton gravity on AdS2 and open strings. The correspondence between the two theories is established using their symmetries and field theoretical, thermodynamic, and statistical arguments. We use the dual conformai field theory to describe two-dimensional black holes. In particular, all the semiclassical features of the black holes, including the entropy, have a natural interpretation in terms of the dual microscopic conformai dynamics. The previous results are discussed in the general framework of the anti-de Sitter/conformal field theory dualities.

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Non-Sequential Double Ionization Of Ne In Intense Laser Pulses: A Coincidence Experiment, Robert Moshammer, Bernold Feuerstein, Daniel Fischer, Alexander Dorn, Claus Dieter Schroter, J. Deipenwisch, Jose R. Crespo Lopez-Urrutia, C. Hohr, Paul B. Neumayer, Joachim Hermann Ullrich, Horst Rottke, Christoph Trump, M. Wittmann, Georg Korn, Wolfgang Sandner Mar 2001

Non-Sequential Double Ionization Of Ne In Intense Laser Pulses: A Coincidence Experiment, Robert Moshammer, Bernold Feuerstein, Daniel Fischer, Alexander Dorn, Claus Dieter Schroter, J. Deipenwisch, Jose R. Crespo Lopez-Urrutia, C. Hohr, Paul B. Neumayer, Joachim Hermann Ullrich, Horst Rottke, Christoph Trump, M. Wittmann, Georg Korn, Wolfgang Sandner

Physics Faculty Research & Creative Works

The dynamics of Neon double ionization by 25 fs, 1.0 PW/cm2 laser pulses at 795 nm has been studied in a many particle coincidence experiment. The momentum vectors of all ejected atomic fragments (electrons and ions) have been measured using combined electron and recoil-ion momentum spectroscopy. Electron emission spectra for double and single ionization will be discussed. In both processes the mean electron energies differ considerably and high energetic electrons with energies of more than 120 eV have been observed for double ionization. The experimental results are in qualitative agreement with the rescattering model.

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Two-Dimensional Black Holes As Open Strings: A New Realization Of The Ads/Cft Correspondence, Mariano Cadoni, Marco Cavaglia Feb 2001

Two-Dimensional Black Holes As Open Strings: A New Realization Of The Ads/Cft Correspondence, Mariano Cadoni, Marco Cavaglia

Physics Faculty Research & Creative Works

We show that weak-coupled two-dimensional dilation gravity on anti-de Sitter space can be described by the dynamics of an open string. Neumann and Dirichlet boundary conditions for the string lead two different realizations of the anti-de Sitter/Conformal Field Theory correspondence. In particular, in the Dirichlet case the thermodynamical entropy of two-dimensional black holes can be exactly reproduced by counting the string states.

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Fully Differential Cusp Electron Production Cross Sections For 75-Kev H₂⁺ + He Collisions, L. An, Kh Khayvat, Michael Schulz Feb 2001

Fully Differential Cusp Electron Production Cross Sections For 75-Kev H₂⁺ + He Collisions, L. An, Kh Khayvat, Michael Schulz

Physics Faculty Research & Creative Works

A kinematically complete experiment on single ionization for 75-keV H2+ + H e collisions was performed by measuring the fully momentum analyzed projectiles and recoil ions in coincidence. The electron momentum was deduced from momentum conservation. Clear signatures of the postcollision interaction between the outgoing projectiles and the electrons were observed in the momentum spectra of all collision products simultaneously.

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Synthons And Design In Metal Phosphates And Oxalates With Open Architectures, Chintamani Nagesa Ramachandra Rao, Srinivasan R. Natarajan, Amitava Choudhury, Sharma Neeraj, Ramamurthy Vaidhyanathana Feb 2001

Synthons And Design In Metal Phosphates And Oxalates With Open Architectures, Chintamani Nagesa Ramachandra Rao, Srinivasan R. Natarajan, Amitava Choudhury, Sharma Neeraj, Ramamurthy Vaidhyanathana

Chemistry Faculty Research & Creative Works

We briefly describe the structures of open-framework metal phosphates with different dimensionalities, such as the one-dimensional linear-chain and ladder structures, two-dimensional layer structures and three-dimensional structures with channels. We demonstrate the role of the zero-dimensional four-membered ring monomer and of the one-dimensional ladder structure as the starting building units or synthons involved in the formation of the complex architectures. Thus, we show how the one-dimensional ladder structure transforms to two- and three-dimensional structures under mild conditions. The two-dimensional layer structures also transform to three-dimensional structures, while the zero-dimensional monomer transforms to layered and three-dimensional structures under ordinary reaction conditions. These …

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A Degree Of Nonlocal Connectedness, J. J. Charatonik, W. J. Charatonik Jan 2001

A Degree Of Nonlocal Connectedness, J. J. Charatonik, W. J. Charatonik

Mathematics and Statistics Faculty Research & Creative Works

To any continuum X weassign an ordinal number (or the symbol ∞) s(X), called the degree of nonlocal connectedness of X. We show that (1) the degree cannot be increased under continuous surjections; (2) for hereditarily unicoherent continua X, the degree of a subcontinuum of X is less than or equal to s(X); (3) s(C(X)) ≤ s(X), where C(X) denotes the hyperspace of subcontinua of a continuum X. We also investigate the degrees of Cartesian products and inverse limits. As an application weconstruct an uncountable family of metric continua X homeomorphic to C(X).

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Adaptive Web Sites By Web Usage Mining, Mario Rodney Creado Jan 2001

Adaptive Web Sites By Web Usage Mining, Mario Rodney Creado

Masters Theses

The World Wide Web has become a very popular marketing medium during the recent years. Many businesses use it extensively to publicize their products. Initially it began with static web sites. However as web sites got bigger and better, their maintenance became problematic. Just as business strategies change, so also will the orgainization of their web sites change. Hence the need of the hour is an adaptive web site (i.e. a web site that can organize itself based upon its usage). For this purpose, web usage mining techniques are used. The characteristics of the user's activity on the web site …

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Structural, Electronic, And Magnetic Properties Of Lani₅₋ₓtₓ (T = Fe, Mn) Compounds, Jinbo Yang, Chiu-Ying Tai, G. K. Marasinghe, George Daniel Waddill, Oran Allan Pringle, William Joseph James, Y. Kong Jan 2001

Structural, Electronic, And Magnetic Properties Of Lani₅₋ₓtₓ (T = Fe, Mn) Compounds, Jinbo Yang, Chiu-Ying Tai, G. K. Marasinghe, George Daniel Waddill, Oran Allan Pringle, William Joseph James, Y. Kong

Physics Faculty Research & Creative Works

Structures and magnetic properties of the LaNi5-xFex and LaNi5-xMnx compounds have been investigated using neutron diffraction and first-principles tight-binding-linear-muffin-tin-orbital methods. Both neutron diffraction refinement data and total energy calculations show that the Fe and Mn atoms preferentially occupy the 3g sites in the hexagonal CaCu5-type structure. The calculated magnetic moments of Fe and Ni atoms are of 2.4-2.5μB and 0.2-0.5μB in LaNi5-xFex, respectively. The magnetic structure exhibits more localized moments at Fe atoms in LaNi5-xFex when x ≤ 1.0. Electronic structure calculations indicate …

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Dynamics Of Poly(Vinyl Acetate)-D₃ On Silica, Robert D. O'Connor, Frank D. Blum, Gu Xu Jan 2001

Dynamics Of Poly(Vinyl Acetate)-D₃ On Silica, Robert D. O'Connor, Frank D. Blum, Gu Xu

Mechanical and Aerospace Engineering Faculty Research & Creative Works

Poly(vinyl acetate) (PVAc) is an important polymer in applications because of both its bulk and surface characteristics. Its chain architecture gives it a low Tg and, generally, good qualities for processing and applications, which include paints, adhesives, thin films and surface coatings. In this study, we investigate the surface dynamics of PVAc absorbed onto silica with deuterium nuclear magnetic resonance (2H NMR). For dynamics studies, 2H NMR is an excellent technique because it uses an innocuous probe that can report on correlation times (τc) from approximately 10-8 s to 10 s. We report the use of two-dimensional exchange NMR (2D-X) …

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Boundary Layers In Channel Flow With Injection And Suction, R. Temam, X. Wang Jan 2001

Boundary Layers In Channel Flow With Injection And Suction, R. Temam, X. Wang

Mathematics and Statistics Faculty Research & Creative Works

We present a rigorous result regarding the boundary layer associated with the incompressible Newtonian channel flow with injection and suction. © 2000 Elsevier Science Ltd. All rights reserved.

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Constraining The Crystallization And Post-Crystallization History Of The Wallamatogus Pluton, Maine, Using Compositional Data From Garnet, Biotite And Muscovite, Joy Kathleen Drake Jan 2001

Constraining The Crystallization And Post-Crystallization History Of The Wallamatogus Pluton, Maine, Using Compositional Data From Garnet, Biotite And Muscovite, Joy Kathleen Drake

Masters Theses

"The Wallamatogus Pluton, Maine, exhibits systematic variation in grain size, mineralogy, and phenocryst abundance (alkali-feldspar) from the margin to the center of the pluton. Three facies are recognized: 1) outermost, seriate, coarse-grained (Owe), 2) porphyritic medium- to fine-grained (Dwp ), 3) innermost, fine-grained equigranular (Dwf). These facies are concentrically arranged and their contacts are gradational. Muscovite and biotite occur in all facies; the outer two facies contain garnet, and tourmaline. Muscovite and biotite grains within micaceous enclaves compositionally overlap primary muscovite, suggesting that they are early-crystallized accumulations. Muscovite in multiphase clusters and secondary muscovite compositionally overlap, suggesting formation during post-crystallization …

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Structural, Magnetic, And Mössbauer Spectral Study Of Er₂Fe₁₇ And Its Hydrides, Fernande Grandjean, Olivier Isnard, Dimitri Hautot, Gary J. Long Jan 2001

Structural, Magnetic, And Mössbauer Spectral Study Of Er₂Fe₁₇ And Its Hydrides, Fernande Grandjean, Olivier Isnard, Dimitri Hautot, Gary J. Long

Chemistry Faculty Research & Creative Works

The structural and magnetic properties of the Er2Fe17Hx compounds, where x is 0, 1, 2, 3, and 3.8, have been investigated by means of powder x-ray diffraction, thermal and ac magnetic susceptibility measurements, and iron-57 Mössbauer spectroscopy. The Er2Fe17Hx compounds crystallize in the hexagonal P63/mmc space group with the Th2Ni17-like structure, a structure which has both an iron-rich stoichiometry and disorder of the erbium and iron-iron 4f-4f dumbbell sites. The increase in the lattice parameters, the magnetic ordering temperature, the saturation magnetization, and the …

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