Open Access. Powered by Scholars. Published by Universities.®
Physical Sciences and Mathematics Commons™
Open Access. Powered by Scholars. Published by Universities.®
Articles 1 - 10 of 10
Full-Text Articles in Physical Sciences and Mathematics
Substitution And Disorder Effects In Ternary Intermetallics, Larico Juan Treadwell
Substitution And Disorder Effects In Ternary Intermetallics, Larico Juan Treadwell
LSU Doctoral Dissertations
The focal point of this dissertation is the investigation of substitution and disorder effects in ternary intermetallics. The crystal growth, crystal structure, and physical properties are reported on single crystals of Ln6W4-xAl43-yTx+y (Ln = Gd, Yb; T= Mn, Fe), LnCr2FexAl20-x (Ln = Yb, Gd), Sm1.33Pd3Ga8, and CeCo2-xMxAl8 (M = Mn, Fe, Ni; 0 ≤ x < 1). The reported compounds were grown via the flux growth method with the strategic synthetic parameters described. Correlations between the structural and physical properties in relation to substitution and disorder of Ln6W4-xAl43-yTx+y (Ln = Gd, Yb; T= Mn, Fe), LnCr2FexAl20-x (Ln = Yb, Gd), Sm1.33Pd3Ga8, and CeCo2-xMxAl8 (M = Mn, Fe, Ni; 0 ≤ x < 1) are discussed. The synthesis and characterization of Mn- and Fe- substituted Ln6W4Al43 (Ln = Gd, Yb) are reported. The compounds adopt the Ho6Mo4Al43 structure type with lattice parameters of a ~ 11 Å and c ~ 17.8 Å with structural site preferences for Mn and Fe. The magnetization of Yb6W4Al43 is sensitive to Mn and Fe doping, which is evident by an increase in the field dependent magnetization. Gd6W4Al43, Gd6W4Al42.31(11)Mn0.69(11), and Gd6W4Al41.69(12)Fe1.30(12) order antiferromagnetically in the ab- and c-direction at 15, 14, and 13 K, respectively, with positive Weiss constants, suggesting the presence of ferromagnetic exchange interactions. Anisotropic magnetization data of Gd6W4Al43-yTy (T= Mn, Fe) analogs are discussed. Crystal growth, structure determination, and magnetic properties of LnCr2Al20-xFex (Ln = La, Gd, Yb) adopting the CeCr2Al20 structure type with space group Fd3¯ m, a ~ 14.5 Å, type are reported. Single crystal X-ray diffraction and Mössbauer spectroscopy are employed to fully characterize the crystal structure of LnCr2Al20-xFex (Ln = La, Gd, Yb). LnCr2Al20-xFex (Ln = La, Gd, Yb) are the first pseudo-ternaries adopting the CeCr2Al20 structure type with a transition metal occupying the main group site. The Yb analogues are Pauli paramagnets with the Yb ion adopting an electronic configuration close to Yb2+, while the Gd analogues show paramagnetic behavior with no magnetic order down to 3 K. The synthesis and characterization of Sm1.33Pd3Ga8 is reported. Sm1.33Pd3Ga8 adopts a disordered variant of the Er4Pt9Al24-structure type with lattice parameters of a = 4.353(5) and c = 38.98(4) Å and V = 639.70(12) Å3. The structure of Sm1.33Pd3Ga8 is composed of three distinct building blocks: Pd2Ga4, PdGa2, and Sm0.67Ga. The Sm0.67Ga slab does not magnetically order, which directly affect the structure. Sm1.33Pd3Ga8 is a temperature independent paramagnet. Field dependent magnetization of Sm1.33Pd3Ga8 displays anisotropic behavior. Single crystals of CeCo2-xMxAl8 (M = Mn, Fe, Ni; 0 ≤ x < 1) were grown and crystallize in the CaCo2Al8 structure type with space group Pbam. Single crystal X-ray diffraction data suggest that the Ce 4f-state is valence fluctuating as Fe concentration increases, whereas the Ni-doped analogues do not exhibit valence fluctuating. The results suggest that hole doping leads to an admixture of Ce3+/Ce4+.
Crystal Growth And An Investigation Of Structural Stability: Synthesis, Structure, And Physical Properties Of Yb(Mn,M)Xal12-X (M = Fe, Ru; X < 2.5) And Lnmnxga3 (Ln = Ho-Tm; X < 0.15), Bradford Wesley Fulfer
Crystal Growth And An Investigation Of Structural Stability: Synthesis, Structure, And Physical Properties Of Yb(Mn,M)Xal12-X (M = Fe, Ru; X < 2.5) And Lnmnxga3 (Ln = Ho-Tm; X < 0.15), Bradford Wesley Fulfer
LSU Doctoral Dissertations
The contents of this dissertation describe the crystal growth, crystal structures, and physical properties of ternary intermetallic aluminides and gallides. These compounds are grown in an effort to determine how controlling reaction ratios using the flux growth method can impact chemical structure and physical properties. Three specific examples are given where slight changes in reaction ratios leads to crystalline products that adopt various structure types. LnMn2+xAl10-x (Ln = Gd, Yb) crystals adopt the CaCr2Al10 and ThMn12 structure types. We compare LnMn2+xAl10-x compounds adopting the CaCr2Al10 and ThMn12 structure types, and outline synthesis methods to obtain each polymorph. Magnetic susceptibility measurements …
Challenges In The Discovery And Characterization Of Magnetic Intermetallics, William A. Phelan
Challenges In The Discovery And Characterization Of Magnetic Intermetallics, William A. Phelan
LSU Doctoral Dissertations
The crystal growth and characterization of four families of compounds, LnFeSb3 (Ln = Pr, Nd, Sm, Gd, and Tb) and CeCo(Sb, Sn)3, Ln2Fe4Sb5 (Ln = La – Nd and Sm), LnCu2(Al,Si)5 (Ln = La and Ce), and Ln(Cu,Al,Ga)13 (Ln = La – Pr and Eu), are presented in this dissertation. Special emphasis is placed on describing their structure-magnetic properties correlations. Discoveries and studies of these systems were motivated by their structurally related predecessors, which are comprised of complex structural subunits and exhibit unusual physical properties. The magnetic behaviors exhibited by a selection of these intermetallics include the large magnetoresistances and …
On The Synthesis, Characterization, And Magnetization Of Ln-M-X (Ln = Lanthanide; M = Ti-Cr, Cu, Mo, Pd; X = Al, Ga) Intermetallics, Michael James Kangas
On The Synthesis, Characterization, And Magnetization Of Ln-M-X (Ln = Lanthanide; M = Ti-Cr, Cu, Mo, Pd; X = Al, Ga) Intermetallics, Michael James Kangas
LSU Doctoral Dissertations
The focus of the research presented herein was to grow single crystals of Ln-M-X (Ln = lanthanide; M = Ti-Cr, Cu, Mo, Pd; X = Al, Ga) intermetallic compounds and to characterize their crystal structures and physical properties. Overall, the flux growth technique facilitated a detailed analysis of previously known structure-types (LnM2Al20 (Ln = La, Ce, Pr, Yb; M = Ti, V, Cr), Ln6M4Al43 (Ln = Gd, Yb; M = Cr, Mo), and Yb2Pd3Ga9), as well as the synthesis and characterization of new compounds (LnCrxGa3 (Ln = Ho, Er; x ~ 0.13), YbCr2Al20-xFex (x ~ 0.2), Ln(Cu,Al,Ga)13-x, and Ln2PdGa12 (Ln …
Crystal Growth Of Complex Intermetallics In Search For Heavy Electron Systems, Brenton L. Drake
Crystal Growth Of Complex Intermetallics In Search For Heavy Electron Systems, Brenton L. Drake
LSU Doctoral Dissertations
The structural solution and physical property characterization of several Ln-T-Al/Ga and Ln-T-Al-Si contain phases, which include Ln(Cu,Al)12 (Ln = Y, Ce, Pr, Sm, and Yb), Ln(Ag,Al,Si)2 (Ln = Ce and Gd), LnCu2(Al,Si)5 (Ln = La and Ce), Ln(Cu,Al,Ga)13-x (Ln = La, Ce, Pr, and Eu), α and β LnNiGa4 (α Ln = Y and Gd – Yb; β Ln = (Tb – Er)), and Ln4FeGa12 (Ln = Tb – Er) will be presented in this work with an emphasis on crystal growth. The systems cover a large breadth of phase space and serve to illustrate the new and rich chemistry …
Synthesis And Characterization Of Rare Earth-Nickel-Gallium Ternary Intermetallics, Kandace R. Thomas
Synthesis And Characterization Of Rare Earth-Nickel-Gallium Ternary Intermetallics, Kandace R. Thomas
LSU Doctoral Dissertations
The structural and physical characterization of several early and latter rare earth Ln-Ni-Ga systems, which include Ln2NiGa12 (Ln = Pr, Nd, Sm), alpha-LnNiGa4 (Ln = Y, Gd – Yb) and beta-LnNiGa4 (Ln = Tb – Ho) will be presented in this work. These systems are thermodynamically located within a copious, robust phase space and provide a rich understanding of how slight modifications to synthetic preparations can yield the adoption of different structure types in a Ga-rich regime. Each of these phases is made up of well-studied substructures which lend an additional angle of apperception as to how their structure and …
Exploration Of New Ternary Gallides And Investigation Of Their Structure-Property Relationships, Jung Young Cho
Exploration Of New Ternary Gallides And Investigation Of Their Structure-Property Relationships, Jung Young Cho
LSU Doctoral Dissertations
This dissertation focuses on the investigation of new ternary intermetallic gallides, which may exhibit exotic physical properties such as heavy-fermion behavior, large magnetoresistance, and even superconductivity. In particular, the Ln-Cu-Ga (Ln = lanthanides) system has been systematically investigated by changing a reaction ratio and/or using a different temperature profile to optimize desired phases. Single crystals of Ln2MGa12 (Ln = La, Ce; M = Ni, Cu) have been synthesized using Ga flux and compared to their Pd analogues. Interestingly, Ce2MGa12 (M = Ni, Cu) show enhanced Sommerfeld coefficient of ¡Ö 191 mJmol-1K-2 and ¡Ö 69 mJmol-1K-2 for Ni and Cu compounds, …
Highly Correlated Lanthanide Intermetallic And Oxide Phases: Crystal Growth And Structure-Property Relationships, Jasmine N. Millican
Highly Correlated Lanthanide Intermetallic And Oxide Phases: Crystal Growth And Structure-Property Relationships, Jasmine N. Millican
LSU Doctoral Dissertations
Our primary research goals are to synthesize, characterize, and study the structure, dimensionality, and physical properties of new highly correlated electron materials. Intermetallic lanthanide and oxide phases are of great interest due to their fascinating array of structural features and physical property phenomena, such as heavy fermion behavior, superconductivity, and magnetism. The crystal growth, structure, and physical properties of several different classes of materials, such as the Ln-M-Ga (Ln = La, Ce, Pr, M = Ni, Pd), Yb5Pt9, and R2Ir2O7 (R = Pr, Eu) compounds, will be highlighted within. The Ln-M-Ga phases allow us to examine the influence of the …
Synthesis, Crystal Growth, Magnetic And Transport Properties Of Ln-M-X (Ln=Lanthanide, M=Transition Metal, X=In, Ga) Compounds, Willa Maria Williams
Synthesis, Crystal Growth, Magnetic And Transport Properties Of Ln-M-X (Ln=Lanthanide, M=Transition Metal, X=In, Ga) Compounds, Willa Maria Williams
LSU Doctoral Dissertations
ABSTRACT This dissertation focuses on the structural stability, magnetic and transport properties of ternary lanthanide compounds grown using indium and gallium flux. Single crystals of TbRhIn5 were synthesized using indium flux. TbRhIn5 is isostructural to the well known LnnMIn3n+2 (n = 1, 2, ∞; Ln = La, Ce; M = Rh, Ir) and adopts the HoCoGa5 structure type and crystallizes in the space group P4/mmm, Z = 1. Lattice parameters are a = 4.6000(6) Å and c = 7.4370(11) Å, V = 157.29(6) Å3. A sharp antiferromagnetic transition is observed at TN = 48 K for TbRhIn5. Single crystals of …
Crystal Growth And The Search For Highly Correlated Ternary Intermetallic Antimonides And Stannides, Evan Lyle Thomas
Crystal Growth And The Search For Highly Correlated Ternary Intermetallic Antimonides And Stannides, Evan Lyle Thomas
LSU Doctoral Dissertations
This dissertation describes the crystal growth, chemical structures, and efforts made towards the understanding of the physical properties of novel ternary rare-earth intermetallics, which may display signature behavior such as superconductivity, heavy fermion behavior, intermediate valence, and/or large magnetoresistance. To address the problem of correlating these characteristics with structural features, several ternary antimony- and tin-containing phases, Ln-T-X (Ln = lanthanide; T = Co, Ni, Pd; X = Sn, Sb), have been synthesized in single crystalline form by metallic flux-growth methods and characterized by X-ray diffraction. The antimonide compounds LnNi1-xSb2 (Ln = Y, Gd-Tb, Er, Yb), alpha, beta-LnNiSb3 (Ln = La, …