Physical Sciences and Mathematics Commons^™

Environmental Fate Of Sulfur In Sulphur Creek, Valles Caldera, Nm: Implications For Metal Transport And Water Quality, Daniel Lavery

Earth and Planetary Sciences ETDs

The 1.2 Ma Valles Caldera in north-central New Mexico hosts a young igneous volcanic hydrothermal system after the model proposed in Goff and Janik (2000). The Sulphur Springs area within Valles Caldera is an acid-sulfate area typical of this model, discharging acidic waters (pH 1.5-3) formed by oxidation of magmatic H₂S at the surface. We report on samples obtained from springs and streams collected between October 2021 and May 2023 in the Sulphur Creek and Alamo watersheds. Sulphur Creek receives input from Sulphur Springs and exhibits low pH (2-4) and high concentrations of Al (≤110 mg/L), Fe (≤60 …

Landscape/Atmosphere Interactions And Carbon-Dioxide Dynamics In The Great Onyx Groundwater Basin, Mammoth Cave National Park, Kentucky, Meghan Raines

Masters Theses & Specialist Projects

An increase in atmospheric CO2 since the Industrial Revolution has altered rates of global climate change and has motivated a need to better quantify the flux of carbon between Earth’s reservoirs. Attempts to quantify the exchange of atmospheric carbon between sources and sinks have led to an increasing interest in the terrestrial landscape, including the continental carbon sink associated with carbonate-mineral dissolution. This research sought to better inform an understanding of karst landscapes and their relationship with global climate change through carbon cycling. The study utilized high-resolution data collection of pH, temperature, and specific conductance of waters in the Cascade …

Using Trace Element Concentrations In Volcanic Ash To Elucidate Magma Sources To Koma Kulshan’S (Mount Baker) Most Recent Explosive Eruption – The 6.7 Ka Ba (Black Ash) Tephra, Stone Machel

Geology Graduate and Undergraduate Student Scholarship

Koma Kulshan (Mount Baker) is an active stratovolcano in the northern Washington Cascades. Kulshan’s most recent magmatic eruption at 6.7 ka was explosive, producing the ~0.2 km³ BA tephra (black ash) from the edifice (Scott et al. 2019). Comprehensive geochemical data for the BA tephra were previously limited to major elements from one whole rock lapillus (silicic andesite) and several in situ glass analyses (dacite), despite being Kulshan’s most voluminous Holocene tephra. Here, I present the first extensive major and trace element study of the pyroxene- and plagioclase-bearing BA tephra glass to determine magma source and eruption processes. My …

Rift-Induced Disruption Of Cratonic Keels Drives Kimberlite Volcanism, Thomas M. Gernon, Stephen M. Jones, Sascha Brune, Thea K. Hincks, Martin Palmer, John C. Schumacher, Rebecca M. Primiceri, Matthew Field, William L. Griffin, Suzanne Y. O'Reilly, Derek Keir, Christopher J. Spencer, Andrew S. Merdith, Anne Glerum

Geology Faculty Publications and Presentations

Kimberlites are volatile-rich, occasionally diamond-bearing magmas that have erupted explosively at Earth’s surface in the geologic past^1,2,3. These enigmatic magmas, originating from depths exceeding 150 km in Earth’s mantle¹, occur in stable cratons and in pulses broadly synchronous with supercontinent cyclicity⁴. Whether their mobilization is driven by mantle plumes⁵ or by mechanical weakening of cratonic lithosphere^4,6 remains unclear. Here we show that most kimberlites spanning the past billion years erupted about 30 million years (Myr) after continental breakup, suggesting an association with rifting processes. Our dynamical …

Hydrology Data For Fern Cave, Alabama (2020-2022), Benjamin Tobin, Benjamin V. Miller, Matthew Niemiller, Andrea Erhardt

Research Data--KGS

Dataset includes water level from four sites within Fern Cave in Jackson County Alabama. Additionally, it includes chemistry of water, sediments and cave-adapted isopods.

Understanding The Connection Between Gypsum Blooms And Human Health At The Salton Sea, Isabel Ichiyama

Undergraduate Honors Theses

The Salton Sea is a closed hypersaline lake in Southern California that has been receiving little input over the past few decades, leading to desiccation that is rapidly increasing every year. This large-scale evaporation of the sea has led to increased dissolved solutes, high salinity, and gypsum blooms. Gypsum blooms, the precipitation of gypsum (CaSO42H2O) in the sea, have been a prominent facet of the sea and their distribution is well known. However, much of their chemistry and potential health hazards are still undetermined. Potential health effects from gypsum salt, an atmospheric dust particle present at the sea, have known …

The Impact Of Glacial Proximity On The Elemental Composition Of Leachate Derived From Sediment Weathering, Karoline Ford

Theses/Capstones/Creative Projects

This study assesses chemical weathering trends as they relate to glacial retreat. The chemical environment of surfaces exposed to the atmosphere differs significantly from beneath a glacier. As a glacier melts, changes to the biogeochemical processes generate environmental gradients. This study analyzed chemical weathering signals at different distances from a glacial front by comparing the elemental composition of leachate derived from sediments in southeastern Greenland. Samples from proglacial, nonglacial, and moraine locations were weathered in a laboratory setting, and ion chromatography was used to determine the elemental composition of the products. Divergent trends in leachate composition were observed as distance …

Study Of Trace Elements In Southern Nevada Spring Waters And Lakes, Hyejeong Lee

UNLV Theses, Dissertations, Professional Papers, and Capstones

Comprehending the natural water resource is imperative for the entire state of Nevada and of particular significance for Southern Nevada, where rapid population growth and climate change are placing significant strain on supplies. This research underscores the significance of water chemistry in identifying potential water source areas through trace elements. For the first time, the study proposed measuring the compositions of the entire suite of metal elements, ranging from Li to U, in over 40 springs in the Moapa Valley and its upper gradient valleys, utilizing the iCAP Qc ICP-MS (Inductively Coupled Plasma Mass Spectrometer) at UNLV. The research evaluated …

Modeled Uranium Series Disequilibria In A Heterogeneous Mantle Underlying Iceland, Dana Andersen

Honors Theses

Regional lithologic heterogeneities in Earth’s mantle may significantly contribute to variations in magma productivity and crustal generation. Such heterogeneities may be a key factor in the anomalously high rates of magmatism and thickened crust of Iceland, which are not fully explained by the presence of a mantle plume. However, the exact lithologic composition of the mantle underlying Iceland is largely unknown. Recent trace element modeling has suggested a two-component melt source beneath Iceland, consisting of a typical upper mantle peridotite mixing with one of several compositions of pyroxenitic material. This study further investigates these potential melt sources by calculating U-series …

Evaluating Bulk Carbon And Nitrogen Isotope Compositions Of Acidic Hydrothermal Sediments On Earth– Implications For Mars Astrobiology, Chance Sturrup

Masters Theses

Carbon isotopes have been widely used as unique biosignatures because biologic processes commonly result in distinctive negative delta ¹³C values (-35 to -10 ‰) within organic material on Earth. However, the bulk delta ¹³C analysis in Gale crater sediments on Mars revealed a wider range of values, from -25 to +56 ‰ (Franz et al., 2020), which suggests a more complex origin. To determine if bulk isotope analysis can be successfully used to detect a microbial signature in a martian analog environment, we analyzed concentrations and isotope compositions of C within hydrothermal sediments in Iceland (Námafjall, Krýsuvík, Hveragerdi) …

Silicon And Oxygen In Earth’S Core: Applications Of Machine Learning To Metal-Silicate Equilibria And Core Formation, Ruben Keane

WWU Honors College Senior Projects

Within Earth’s core, light elements (Si, O, C, S, N, H) are known to make up a small fraction of the total mass of the core with respect to heavy elements. The degree to which these elements exist in the cores of terrestrial planets have geophysical and geochemical implications, most notably the presence of core convection and a geodynamo, thermal conductivity within the core, and core temperature. Comparison of the composition of chondrites to Earth’s mantle composition and the Preliminary Reference Earth Model have given an estimation of about 10 % light elements in Earth’s core. The concentrations of each …

Connections Between Eruption Style And Magmatic Reservoir Evolution: Insights From Augustine Volcano, Alaska, Usa, Mahinaokalani G. Robbins

WWU Graduate School Collection

At a single volcano, eruptive behavior can change through time as the plumbing system evolves. Augustine Volcano, a frequently active intermediate stratovolcano in the Alaska-Aleutian arc (USA), is an ideal setting to investigate magma reservoir processes due to its frequent modern and Holocene eruption history. Its most recent 2006 CE eruption included mixed effusive and moderately explosive (VEI 3) events and has been studied in detail. Proximal fall deposits from this eruption were generally mixed fine ash to lapilli with variable thickness, but typically ~5 cm on the island (Wallace et al., 2010). The Pre-contact “Tephra M” was deposited by …

Petrological And Geochemical Evaluation Of Rare-Earth Element Potential In The Sparta Granite Complex, Max J. Eshbaugh

Honors College Theses

Rare earth elements (REEs) are important resources with applications in the electronics, renewable energy, and automotive industries. REEs may be concentrated in the residual weathered portion of igneous parent rocks, typically granites. These residual deposits are mined in southeast Asia, but analogous climatic and geologic conditions suggest the existence of economically viable REE residual deposits in the southeastern United States (U.S.). The Sparta Granite Complex in east-central Georgia is a granitoid complex emplaced at the end of the Alleghanian orogeny, forming a suture between the Savannah River and Milledgeville terranes. Petrologic and geochemical assessments of the Sparta Granite and overlying …

Dynamics And Timescales Of Magmatic Processes At Cerro Uturuncu, Bolivia, Sarah Jane Rasor

MSU Graduate Theses

Between 12-25°S latitude there is prolific volcanism fueled by the Altiplano-Puna Magmatic Body (APMB), a mid-crustal magma body above the 30° angle subduction of the Nazca plate and within 60-70 km thick South American crust. Cerro Uturuncu, a stratovolcano constructed above the center of the APMB, can provide insight to the evolution of the APMB over time. Previous research suggests that the APMB is more homogenous near its center as opposed to its edges. However, the processes that led to greater homogenization as well as the structure of the magma body below Cerro Uturuncu remain unknown. This research contributes greater …

Magmatic Evolution Of The Chasca Orkho Lava Series And Its Magmatic Enclaves, Volcán Ollagüe, Central Andes, Nathaniel W. Lenhard

MSU Graduate Theses

Magma mixing is a common factor in the creation of intermediate composition magmas and a potential instigator of a volcanic eruption. Magmatic enclaves, physical evidence of magma mixing within a volcanic system, are a phenomenon whose mechanisms remain unclear and debated. Common hypotheses explaining the occurrence of magmatic enclaves within a host lava range from the repeated injection of a new magma into a shallow reservoir to the disruption of equilibrium within a stratified magma chamber. Within the Andean Central Volcanic Zone (CVZ), the occurrence of magmatic enclaves yields similar geochemical compositions to their respective host rocks, bringing more difficulty …

Natural, Experimental, And Educational Explorations Of The Interiors Of Terrestrial Planetary Bodies, Nadine L. Grambling

Doctoral Dissertations

Planetary interiors are enigmatic, inaccessible, and vital to the processes that have formed the rocks we see on the surface of bodies in the inner Solar System today. Based on geophysical explorations of the Moon and Earth, along with information gleaned from rocks at the surface today, there is understanding of the basic structure and processes at depth. Using a combination of natural samples and experimental studies, we attempt to learn more about the physical conditions beneath the surface, and their effect on material properties and tectonics processes in the mantle.

On Earth, mid-ocean ridge processes have long been debated, …

Geochemical Analysis Of Recent Volcanic Ash Blanketing Barbados And Constraints On Magma Composition (V32e-0112), Nazrul I. Khandaker, Krishna Mahabir, Surendranauth Mahabir, Lloyd Kiefer, Juan C. Campo, Andrew M. Singh

Publications and Research

Preliminary field and geochemical investigations were conducted on ash samples from Barbados to chemically characterize and decipher magma chemistry associated with a recent volcanic event. A thick plume of volcanic ash from the La Soufriere Volcano in St Vincent, which erupted on April 9, 2021, caused lower visibility due to ash clouds which engulfed the region for some time. Three authors from the research team visited Barbados during the summer subsequent and completed a reconnaissance investigation on recent ashfall. St Vincent is a small volcanic island in the Eastern Caribbean and lies in the southern part of the Lesser Antilles …

Geochemical Characterization Of The Louann Salt, Puma Field, Green Canyon, Gulf Of Mexico Basin – Using Xrf And Xrd, Brian Lesh

Electronic Theses and Dissertations

The Jurassic-aged Louann Salt is an evaporite sequence deposited in the Gulf of Mexico Basin (GOMB). It is an important component of the GOMB petroleum system and influences the facies pattern in overlying strata and the distribution of petroleum stratigraphic traps. The Louann Salt is composed primarily of halite with intercalated anhydrites and silty or sandy-halite intervals, with overall thicknesses in excess of four kilometers (~13,000 feet). Suture zones occur intermittently within the Louann Salt, formed by the collision of allochthonous evaporite layers. The mineralogy and geochemistry of the suture zones are currently understudied and can be hazardous during drilling …

Geochemical Characterization Of The Bone Spring Formation, Delaware Basin, Using Chemostratigraphy And Integrated Petrophysics, David Tonner

Electronic Theses and Dissertations

The Delaware Basin forms part of West Texas's and New Mexico’s famous petroleum-generating Permian Basin. The Bone Spring Formation is a prolific hydrocarbon producer within this basin, creating one of the world’s richest oil shales. This formation has lithological sequences that are characterized by repeating carbonate and siliciclastic intervals of a third-order cycle which can largely be correlated to highstand and lowstand systems tracts, respectively. Lithological complexity and facies change are manifested by debris flows, turbidites, and slumps. In addition to glacio-eustasy, both tectonism and broader Milankovitch cycles have influenced the depositional history. Previous investigations have utilized cores and wireline …

Comparative Geochemical Analysis Of Recent Volcanic Flows On Barva Volcano, Costa Rica, Julie Coulombe

Masters Theses

ABSTRACT

Barva Volcano is a dormant stratovolcano in the Cordillera Central region of Costa Rica, rising above the capital city of San Jose with a population of 347,000. Barva’s recent inactivity and extensive forestation have resulted in fewer investigations of its composition, petrogenesis, and eruptive history. The objective of this research is to analyze the geochemical data from several of the most recent lava flows, evaluate variability between eruptive units, and ascertain physical conditions within the Barva magma storage region. The data collected in this study helps constrain the geochemistry of units seen in the quarry and provides information regarding …

Connections Between Interglacial Variation And Lithological Variability Within Midland Basin Permian Shale Rocks In Martin County, Texas, Helen Rice Hammon

LSU Master's Theses

The Upper Pennsylvanian (323.2–289.9 Ma) and Lower Permian (289.9-251 Ma), (Wolfcamp and Spraberry formations) interval of the Midland Basin, West Texas, contains a mixed succession of shale, carbonate, and siltstone/sandstone lithofacies that accumulated in a deep-water marine environment under variable hydrographic restrictions. The heterogenous stratigraphy found in the Wolfcamp and Spraberry formation was formed in response to variations in sea level and a transition from a glacial to an interglacial climate during the Early Permian. These fluctuations left behind alternating beds of mudstone and carbonate, interwoven with thin sandstone beds. Because the Wolfcamp and Spraberry formations are highly heterolithic, it …

Connections Between Interglacial Variation And Lithological Variability Within Midland Basin Permian Shale Rocks In Martin County, Texas, Helen Rice Hammon

LSU Master's Theses

The Upper Pennsylvanian (323.2–289.9 Ma) and Lower Permian (289.9-251 Ma), (Wolfcamp and Spraberry formations) interval of the Midland Basin, West Texas, contains a mixed succession of shale, carbonate, and siltstone/sandstone lithofacies that accumulated in a deep-water marine environment under variable hydrographic restrictions. The heterogenous stratigraphy found in the Wolfcamp and Spraberry formation was formed in response to variations in sea level and a transition from a glacial to an interglacial climate during the Early Permian. These fluctuations left behind alternating beds of mudstone and carbonate, interwoven with thin sandstone beds. Because the Wolfcamp and Spraberry formations are highly heterolithic, it …

Geology And Geochronology Of The East Dome Complex Within The Hog Heaven Volcanic Field, Flathead County, Montana, Ethan Coppage

Graduate Theses & Non-Theses

This study describes the style and timing of volcanic activity and mineralization in the East Dome Complex (EDC) of the 55-km2 Eocene-Oligocene Hog Heaven Volcanic Field (~36-30 Ma; HHVF) located in northwestern Montana. The HHVF consists of three NE-aligned, predominantly high-K rhyodacitic dome complexes (1.8-4.9 wt. % K2O; 63.2-72.9 wt. % SiO2) formed near the crest the Purcell Anticlinorium, a major Cordilleran fold-thrust belt structure deforming metasedimentary rocks of the Mesoproterozoic Belt Supergroup. Dome emplacement was controlled by a NE-striking fault associated with a pull-apart basin formed between two overlapping, NW-trending dextral oblique-slip faults. The objective of this study is …

Stratigraphic And Geochemical Evaluation Of Distal Flows Of The Columbia River Flood Basalts In The Greater Vale Area, Southeastern Oregon, Lena Marie Fox

Dissertations and Theses

Exposures of Columbia River Basalt Group (CRBG) in southeastern Oregon are dominated by the four main phase CRBG units: Steens Basalt, Imnaha Basalt, Grande Ronde Basalt (GRB), and Picture Gorge Basalt (PGB). These units are best seen in stratigraphic sequence along the Malheur Gorge corridor of southeastern Oregon, between the towns of Vale and Juntura, with flows of Steens Basalt from the south overlain by flows of Imnaha and GRB from the north. Recently, PGB flows were found to be part of the eastern Malheur Gorge stratigraphy as well.

In Malheur Gorge, local units of Birch and Hunter Creek Basalt …

Using Lake Sediment Chemistry In The Exploration For Nickel Laterite Deposits In Tropical Regions, Gabriela Yvonne Ramirez

Masters Theses

"Developing reliable geochemical indicators to guide the search for ore deposits is a long-standing goal. This particularly applies to tropical regions that are often heavily vegetated which hampers boots-on-the ground exploration efforts. Here we present the preliminary results of a study that investigates the usefulness of lake sediment chemistry in the exploration for nickel laterite ore deposits in tropical regions using Lake Izabal, Guatemala, as a case study. Lake Izabal’s catchment area contains Ni laterite deposits along its northern shore, whereas no Ni-laterite discoveries have been made in the south except for a Ni mine in the southern region that …

Chemical And Thermal Influence On Intermediate Magma Storage Conditions: Volcán Ollagüe, Chile-Bolivia, Central Andes, Drew Allen Laviada-Garmon

MSU Graduate Theses

Continental arc volcanoes are the single best portrayal of the evolution of recycled earth material stemming from subduction, one of the most important and foundational phenomena in global tectonics. Understanding the genesis of intermediate-composition magmas produced at arc volcanoes is a difficult process making them a focal point for investigation. Geochemical investigation of zircon and plagioclase mineral phases erupted from continental arcs can provide insight into magma process, generation, storage conditions, timescales and differentiation of sub-volcanic plumbing systems prior to eruption events. The Central Volcanic Zone is a prime example of continental arc volcanism through subduction, and is host to …

Geochemical And Sensor-Based Monitoring Of Fault-Associated Carbonic Springs In Grand Canyon And Northern New Mexico: Identifying Hydrologic Pathways And Establishing Baselines, Chris Mcgibbon

Earth and Planetary Sciences ETDs

This dissertation examines the interaction of spring systems and faulting. When springs discharge within a fault zone the interaction is often complex, and multiple methods are required to understand the flow, mixing and evolution of groundwater. In karst aquifer systems fracture networks can range from sub-millimeter to meters and only adds to the complexities involved in examining spring hydrology. The Interest in springs and faulting is not only driven by science, but also has applied applications. Faulting and fluid flow are of interest to the oil and gas industry, and potential CO₂ sequestration. In the southwestern US, water quantity …

Identifying Biogeochemical Factors Responsible For The Cyclical Precipitation Of Sphalerite And Galena In Low Temperature Mississippi Valley Type Ore Deposits, Daniel John Makowsky

Theses and Dissertations

Mississippi Valley Type (MVT) lead and zinc deposits provide a significant source of sedimentary galena and sphalerite. However, geochemical characteristics and genesis including the source and production of hydrogen sulfide required for galena and sphalerite ore formation and the reasoning for quick, episodic mineralization is not fully understood. By simulating regional MVT brines, the input and effect of biological by-products during the development of these ores as well as the cause of cyclicity within MVT deposits have been observed. Experiments using compositions from MVT fluid inclusions were conducted over two-week periods. Variables during the experiments included temperature, CO2, hydrogen sulfide …

Geochemical Investigation Of Monogenetic Volcanoes From The Pribilof Islands, Bering Sea, Alaska, Clayton L. Reinier

MSU Graduate Theses

Small-volume basaltic magmas found at continental intraplate environments have not been as extensively studied compared to their polygenetic counterparts. Specifically, regions such as the Bering Sea basalt province, described as a diffuse igneous province, have commonly been overlooked. Assumptions that these systems are invoked by simple, single batches of magma has subsequently left a gap in understanding the processes responsible for primary magma generation away from plate boundaries with little tectonic influence. The following studies that constitute this thesis focus on an in-depth geochemical investigation at the crystal and sub-crystal scale to evaluate lithospheric mantle heterogeneities, processes that govern primary …

The Sedimentary Geochemistry And Paleoenvironments Project, Úna C. Farrell, Rifaat Samawi, Savitha Anjanappa, Roman Klykov, Oyeleye O. Adeboye, Heda Agic, Anne Sofie C. Ahm, Thomas H. Boag, Fred Bowyer, Jochen J. Brocks, Tessa N. Brunoir, Donald E. Canfield, Xiaoyan Chen, Meng Cheng, Matthew O. Clarkson, Devon B. Cole, David R. Cordie, Peter W. Crockford, Huan Cui, Tais W. Dahl, Lucas D. Mouro, Keith Dewing, Stephen Q. Dornbos, Nadja Drabon, Julie A. Dumoulin, Joseph F. Emmings, Cecilia R. Endriga, Tiffani A. Fraser, Robert R. Gaines, Richard M. Gaschnig, Timothy M. Gibson, Geoffrey J. Gilleaudeau

Geosciences: Faculty Publications

No abstract provided.