Physical Sciences and Mathematics Commons^™

Integrating Detailed Petrography, Geochemistry, And Mineralogy To Elucidate Extensive Early Diagenesis In The Eocene Carbonates Of Qatar, Brooks H. Ryan

Dissertations

Eocene carbonates comprising the Umm er Radhuma (UER), Rus, and Dammam Formations, cover 80% of the surface and extend >300 m into the subsurface of Qatar. These rocks record marine sedimentation in shallow sub-tidal to restricted settings. Despite undergoing only shallow burial (<1000 m), extensive diagenetic alteration has occurred. Given that little work on this topic has been published previously, the objectives of this work are to document diagenesis in the Eocene, and to integrate petrography, mineralogy, and geochemistry to delineate the timing and environments of diagenesis of these Eocene carbonates. Detailed petrographic data show that dolomitization occurred early in the UER, before the formation of diagenetic chert, palygorskite, pyrite, calcite, and gypsum cements. Bulk dolomite δ¹⁸O values, coupled with clumped isotope-derived (Δ47) temperatures and dolomitizing fluid δ¹⁸O values, suggest dolomitization took place in near-normal marine fluids, perhaps during shallow burial. These data challenge the current paradigm of large-scale, top-down hypersaline reflux dolomitization in the UER. Associated depth trends of increasing crystal size and with increasing stoichiometry and cation ordering …

Evaluating The Effects Of Sodium, Potassium, Magnesium, And Calcium Concentrations On Dolomite Stoichiometry, Cation Ordering, And Reaction Rate, Hanna F. Cohen

Masters Theses

Numerous environmental factors affect dolomitization. Shallow peritidal and restricted marine environments, for example, are often associated with more abundant and more stoichiometric dolomite than deeper marine environments. Higher fluid Mg/Ca ratios resulting from gypsum precipitation are often invoked to explain this observation, even when evidence of evaporites is absent. In this study, high-temperature dolomitization experiments show that the concentrations of major cation concentrations (Na, K, Mg, and Ca) impact dolomite stoichiometry and reaction rate. Nearly 200 batch dolomitization experiments were run whereby 100 mg of natural aragonite ooids were dolomitized at 215°C in ionic solutions. Fluid [NaCl] and [KCl] correlate …

A Multi-Indicator Approach To Understanding The Diagenesis Of Carbonates In Pennsylvanian Mudrocks Of The Midland Basin, Alex J. Reis

Theses and Dissertations--Earth and Environmental Sciences

The Late Pennsylvanian was a time of frequent, rapid glacioeustatic sea-level changes. These changes were recorded in the Wolfcamp D Formation of the Midland Basin as a series of cyclothems similar to those studied in the Midcontinent region (e.g., Algeo and Heckel, 2008). This study focuses on identifying the mechanisms and controls on carbonate deposition and diagenesis through the Upper Pennsylvanian Wolfcamp D Formation and evaluating the potential for these layers to be stratigraphically significant. A stepwise progression of diagenetic processes was identified through the use of δ¹³C_carb and δ¹⁸O_carb, bulk geochemical and …

Paragenesis Of Lacustrine Microbialites In The Upper Wilkins Peak Member, Green River Formation, Wyoming, Bethania Chagas Tosta Siviero

Loma Linda University Electronic Theses, Dissertations & Projects

Microbialites from the upper Wilkins Peak Member were investigated to determine their paragenesis and to help interpret lake chemistry. Two specific microbialite beds were analyzed that are associated with the “layered tuff”. Samples were collected from correlated sections along a NW to SE, 24 km line of section from lake margin towards lake center. XRD, SEM/EDS, and petrographic analysis show differences in diagenesis above and below the layered tuff.

Microbialites below the tuff bed contain some primary calcite with diagenetic dolomite and abundant secondary silicification. Later, dolomite replaces both calcite and quartz. Pores are commonly filled with 20 μm euhedral …

Outcrop Analog For Lower Paleozoic Hydrothermal Dolomite Reservoirs, Mohawk Valley, Ny, Brian E. Slater

Geology Theses and Dissertations

Geochemical analysis and field relations of linear dolomite bodies occurring in outcrop in the Mohawk Valley of New York suggest that they have undergone significant fault-related hydrothermal alteration. The dolomite occurs in the Lower Ordovician Tribes Hill Formation, which is regionally an early Ordovician shaley limestone with patchy dolomitization. The outcrop has an en echelon fault, fracture, and fold pattern. A 3D ground penetrating radar survey of the quarry floor has helped to map out faults, fractures, anticlines, synclines and the extent of dolomitization. Most of the dolomitization occurs in fault-bounded synclines or “sags” flanked by anticlines. The dolomite structures …

Characterization And Interpretation Of The Cephalopod Marker Bed, Oakes Quarry Park, Fairborn, Ohio, Jessica Nicole Mcdonough

Browse all Theses and Dissertations

A distinct sequence of orange-brown, fossiliferous grainstones with interbedded blue mudstones exists in the upper portion of the Silurian-aged (Llandoverian) Brassfield Formation exposure at Oakes Quarry Park, Fairborn, Ohio. The unit is locally referred to as the cephalopod marker bed as it can be easily identified and is continuous throughout the quarry. The unit varies considerably in thickness (0.3m-0.9m) and contains a variety of sedimentary structures and fossils indicative of a warm, shallow marine environment subject to wave action. Dominant fossils within the unit include echinoderms, cephalopods, bryozoans, abraded mollusks, gastropods, brachiopods, and trilobites. Less-common fossil organisms within the unit …

Dolomitization Of The Hatch Hill Arenites And The Burden Iron Ore, Peter Michael Hofmann

Geology Theses and Dissertations

The Taconic allochthon is a sequence of Cambrian or Precambrian to Ordovician rocks. It is composed of predominantly deep water argillaceous and subordinate arenaceous and calcareous rocks that were deposited on the continental rise and slope. During the Ordovician, sediments which were earlier deposited in the slope-rise environment were incorporated into the accretionary prism of an island arc that approached from the east, and subsequently overthrust the carbonate platform.
The Hatch Hill Formation is part of the Taconic sequence. It consists of dominantly black-gray slates, minor amounts of sandstones and carbonates. Previous workers have recognized the presence of dolomite and …