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2011

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Full-Text Articles in Physical Sciences and Mathematics

A Review Of Baobab (Adansonia Digitata) Products: Effect Of Processing Techniques, Medicinal Properties And Uses, Donatien Kabore, Hagrétou Sawadogo-Lingani, Bréhima Diawara, Clarise Compaoré, Mamoudou H. Dicko Prof., Mogens Jacobsen Dec 2011

A Review Of Baobab (Adansonia Digitata) Products: Effect Of Processing Techniques, Medicinal Properties And Uses, Donatien Kabore, Hagrétou Sawadogo-Lingani, Bréhima Diawara, Clarise Compaoré, Mamoudou H. Dicko Prof., Mogens Jacobsen

Pr. Mamoudou H. DICKO, PhD

A general literature review including the effect of processing techniques, medicinal value and uses of baobab tree is reported in this manuscript. Baobab tree has multi-purpose uses, as it produces food and non-food products such as medicines, fuel, timber, fodder. Every part of the baobab tree is reported to be useful. The seeds, leaves, roots, flowers, fruit pulp and bark of baobab are edible. Baobab leaves are used in the preparation of soup. Seeds are used as a thickening agent in soups, but they can be fermented and used as a flavouring agent or roasted and eaten as snacks. The …


Electroluminescence Studies On Longwavelength Indium Arsenide Quantum Dot Microcavities Grown On Gallium Arsenide, John C. Ramsey Dec 2011

Electroluminescence Studies On Longwavelength Indium Arsenide Quantum Dot Microcavities Grown On Gallium Arsenide, John C. Ramsey

Theses and Dissertations

A comprehensive study of the electroluminescence of four GaAs/AlGaAs microcavity devices with InAs/GaInAs quantum dot active regions emitting near 1.3 µm was conducted. The four molecular beam epitaxial grown samples with AlAs oxide aperture confinement layers were fabricated, characterized, and optically modeled. Optical power transmission of the samples was modeled using Matlab and compared with measured transmission data. Resonant cavity light emitting diodes (RCLEDs) and three vertical cavity surface emitting laser (VCSEL) samples were fabricated and electro-optically characterized over a range of injection currents and temperatures. Devices achieved continuous wave room temperature lasing at 1.28 µm with an output power …


Formation Of Organized Nanostructures From Unstable Bilayers Of Thin Metallic Liquids, Mikhail Khenner, Sagar Yadavali, Ramki Kalyanaraman Dec 2011

Formation Of Organized Nanostructures From Unstable Bilayers Of Thin Metallic Liquids, Mikhail Khenner, Sagar Yadavali, Ramki Kalyanaraman

Mathematics Faculty Publications

Dewetting of pulsed-laser irradiated, thin (< 20 nm), optically reflective metallic bilayers on an optically transparent substrate with a reflective support layer is studied within the lubrication equations model. A steady-state bilayer film thickness (h) dependent temperature profile is derived based on the mean substrate temperature estimated from the elaborate thermal model of transient heating and melting/freezing. Large thermocapillary forces are observed along the plane of the liquid-liquid and liquid-gas interfaces due to this h-dependent temperature, which, in turn, is strongly influenced by the h-dependent laser light reflection and absorption. Consequently the dewetting is a result of the competition between thermocapillary and intermolecular forces. A linear analysis of the dewetting length scales established that the non-isothermal calculations better predict the experimental results as compared to the isothermal case within the bounding Hamaker coefficients. Subsequently, a computational non-linear dynamics study of the dewetting pathway was performed for Ag/Co and Co/Ag bilayer systems to predict the morphology evolution. We found that the systems evolve towards formation of different morphologies, including core-shell, embedded, or stacked nanostructure morphologies.


Starting Radial Subdiffusion From A Central Point Through A Diverging Medium (A Sphere): Heat-Balance Integral Method, Jordan Hristov Dec 2011

Starting Radial Subdiffusion From A Central Point Through A Diverging Medium (A Sphere): Heat-Balance Integral Method, Jordan Hristov

Jordan Hristov

The work presents an integral solution of the time-fractional subdiffusion equation as alternative approach to those employing hypergeometric functions. The integral solution suggests a preliminary defined profile with unknown coefficients and the concept of penetration (boundary layer) well known from the heat diffusion and hydrodynamics. The profile satisfies the boundary conditions imposed at the boundary of the boundary layer that allows its coefficients to be expressed through the boundary layer depth as unique parameter describing the profile. The technique is demonstrated by a solution of a time fractional radial equation concerning anomalous diffusion from a central point source in a …


Formation Of Organized Nanostructures From Unstable Bilayers Of Thin Metallic Liquids, Mikhail Khenner, Sagar Yadavali, Ramki Kalyanaraman Dec 2011

Formation Of Organized Nanostructures From Unstable Bilayers Of Thin Metallic Liquids, Mikhail Khenner, Sagar Yadavali, Ramki Kalyanaraman

Mikhail Khenner

Dewetting of pulsed-laser irradiated, thin (< 20 nm), optically reflective metallic bilayers on an optically transparent substrate with a reflective support layer is studied within the lubrication equations model. A steady-state bilayer film thickness (h) dependent temperature profile is derived based on the mean substrate temperature estimated from the elaborate thermal model of transient heating and melting/freezing. Large thermocapillary forces are observed along the plane of the liquid-liquid and liquid-gas interfaces due to this h-dependent temperature, which, in turn, is strongly influenced by the h-dependent laser light reflection and absorption. Consequently the dewetting is a result of the competition between thermocapillary and intermolecular forces. A linear analysis of the dewetting length scales established that the non-isothermal calculations better predict the experimental results as compared to the isothermal case within the bounding Hamaker coefficients. Subsequently, a computational non-linear dynamics study of the dewetting pathway was performed for Ag/Co and Co/Ag bilayer systems to predict the morphology evolution. We found that the systems evolve towards formation of different morphologies, including core-shell, embedded, or stacked nanostructure morphologies.


Adapting To Climate Change While Planning For Disaster: Footholds, Rope Lines, And The Iowa Floods, Robert R.M. Verchick, Abby Hall Dec 2011

Adapting To Climate Change While Planning For Disaster: Footholds, Rope Lines, And The Iowa Floods, Robert R.M. Verchick, Abby Hall

BYU Law Review

No abstract provided.


New Frontiers In Ocean Exploration: The 2011 E/V Nautilus Field Season, K. Bell, R. Ballard, D. Coleman, C. Roman, M. Brennan, T. Turanli, M. Duman, S. Carey, P. Nomikou, M. Marani, M. Rosi, J. Austin, M. Canals, J. Karson, L. Mayer, Y. Makovsky Dec 2011

New Frontiers In Ocean Exploration: The 2011 E/V Nautilus Field Season, K. Bell, R. Ballard, D. Coleman, C. Roman, M. Brennan, T. Turanli, M. Duman, S. Carey, P. Nomikou, M. Marani, M. Rosi, J. Austin, M. Canals, J. Karson, L. Mayer, Y. Makovsky

Christopher N. Roman

In the summer of 2011, the Exploration Vessel NAUTILUS is undertaking a four-month expedition to the Black, Aegean and Mediterranean Seas, and North Atlantic Ocean. The primary goal of the NAUTILUS is to create a focus of international leadership for the development and integration of leading-edge technologies, educational programs, field operations, and public outreach programs for ocean exploration, in partnership with NOAA, National Geographic Society, Office of Naval Research, and other sponsors. To do so, the program uses a complement of deep submergence vehicle systems and “telepresence” technologies to engage scientists, educators and the public, both at sea and ashore, …


Nanozeolites Doped Photopolymer Layers With Reduced Shrinkage, Mohesh Moothanchery, Izabela Naydenova, Svetlana Mintova, Vincent Toal Dec 2011

Nanozeolites Doped Photopolymer Layers With Reduced Shrinkage, Mohesh Moothanchery, Izabela Naydenova, Svetlana Mintova, Vincent Toal

Articles

An acrylamide based photopolymer doped with pure silica MFI-type zeolite (silicalite-1) nanoparticles has been characterized for holographic recording purposes. The concentrations of the silicalite-1 nanoparticles in the photopolymer layers were 1, 2.5, 5 and 7.5 wt.%. The inclusion of silicalite-1 nanoparticle in the photopolymer has resulted in an increase of the diffraction efficiency by up to 40%, and decrease of the shrinkage from 1.32% to 0.57%. The best results were obtained in layers doped with 5 wt.% silicalite-1 nanoparticles.


Detection Of Diffuse Sea Floor Venting Using Structured Light Imaging, Gabrielle Inglis, Clara Smart, Christopher Roman, Steven Carey Dec 2011

Detection Of Diffuse Sea Floor Venting Using Structured Light Imaging, Gabrielle Inglis, Clara Smart, Christopher Roman, Steven Carey

Graduate School of Oceanography Faculty Publications

Efficiently identifying and localizing diffuse sea floor venting at hydrothermal and cold seep sites is often difficult. Actively venting fluids are usually identified by a temperature induced optical shimmering seen during direct visual inspections or in video data collected by vehicles working close to the sea floor. Relying on such direct methods complicates establishing spatial relations between areas within a survey covering a broad area. Our recent work with a structured light laser system has shown that venting can also be detected in the image data in an automated fashion. A structured light laser system consists of a camera and …


Remote Analysis Of Grain Size Characteristic In Submarine Pyroclastic Deposits From Kolumbo Volcano, Greece, Clara Smart, D. P. Whitesell, Christopher N. Roman, Steven Carey Dec 2011

Remote Analysis Of Grain Size Characteristic In Submarine Pyroclastic Deposits From Kolumbo Volcano, Greece, Clara Smart, D. P. Whitesell, Christopher N. Roman, Steven Carey

Graduate School of Oceanography Faculty Publications

Grain size characteristics of pyroclastic deposits provide valuable information about source eruption energetics and depositional processes. Maximum size and sorting are often used to discriminate between fallout and sediment gravity flow processes during explosive eruptions. In the submarine environment the collection of such data in thick pyroclastic sequences is extremely challenging and potentially time consuming. A method has been developed to extract grain size information from stereo images collected by a remotely operated vehicle (ROV). In the summer of 2010 the ROV Hercules collected a suite of stereo images from a thick pumice sequence in the caldera walls of Kolumbo …


High Resolution Sea Floor Bathymetry Using High Frequency Multibeam Sonar And Structured Light Laser Imaging, C. Roman, G. Inglis, C. Smart, I. Vaughn, S. Carey Dec 2011

High Resolution Sea Floor Bathymetry Using High Frequency Multibeam Sonar And Structured Light Laser Imaging, C. Roman, G. Inglis, C. Smart, I. Vaughn, S. Carey

Christopher N. Roman

Detailed bathymetric maps of the sea floor with centimeter level resolution can be produced by underwater vehicles using multibeam sonars and structured light laser imaging. Over spatial scales up to tens of thousands of square meters it is possible to produce maps gridded to sub centimeter levels. This level of accuracy demands detailed treatments of the sensor relative data, the vehicle navigation data and the vehicle to sensor position and rotational offsets. The presented results will show comparisons between these two sensor modalities. Data have a been collected during recent field programs to the Kolumbo volcanic crater and the Southern …


Remote Analysis Of Grain Size Characteristic In Submarine Pyroclastic Deposits From Kolumbo Volcano, Greece, C. Smart, D. P. Whitesell, C. Roman, S. Carey Dec 2011

Remote Analysis Of Grain Size Characteristic In Submarine Pyroclastic Deposits From Kolumbo Volcano, Greece, C. Smart, D. P. Whitesell, C. Roman, S. Carey

Christopher N. Roman

Grain size characteristics of pyroclastic deposits provide valuable information about source eruption energetics and depositional processes. Maximum size and sorting are often used to discriminate between fallout and sediment gravity flow processes during explosive eruptions. In the submarine environment the collection of such data in thick pyroclastic sequences is extremely challenging and potentially time consuming. A method has been developed to extract grain size information from stereo images collected by a remotely operated vehicle (ROV). In the summer of 2010 the ROV Hercules collected a suite of stereo images from a thick pumice sequence in the caldera walls of Kolumbo …


Detection Of Diffuse Sea Floor Venting Using Structured Light Imaging, G. Inglis, C. Smart, C. Roman, S. Carey Dec 2011

Detection Of Diffuse Sea Floor Venting Using Structured Light Imaging, G. Inglis, C. Smart, C. Roman, S. Carey

Christopher N. Roman

Efficiently identifying and localizing diffuse sea floor venting at hydrothermal and cold seep sites is often difficult. Actively venting fluids are usually identified by a temperature induced optical shimmering seen during direct visual inspections or in video data collected by vehicles working close to the sea floor. Relying on such direct methods complicates establishing spatial relations between areas within a survey covering a broad area. Our recent work with a structured light laser system has shown that venting can also be detected in the image data in an automated fashion. A structured light laser system consists of a camera and …


A Study Of Correlations Between The Definition And Application Of The Gene Ontology, Yuji Mo Dec 2011

A Study Of Correlations Between The Definition And Application Of The Gene Ontology, Yuji Mo

Computer and Electronics Engineering: Dissertations, Theses, and Student Research

When using the Gene Ontology (GO), nucleotide and amino acid sequences are annotated by terms in a structured and controlled vocabulary organized into relational graphs. The usage of the vocabulary (GO terms) in the annotation of these sequences may diverge from the relations defined in the ontology. We measure the consistency of the use of GO terms by comparing GO's defined structure to the terms' application. To do this, we first use synthetic data with different characteristics to understand how these characteristics influence the correlation values determined by various similarity measures. Using these results as a baseline, we found that …


Minerva 2011, The Honors College Dec 2011

Minerva 2011, The Honors College

Minerva

This issue of Minerva includes an article on four newly-hired Honors preceptors, Rob Glover, Sarah Harlan-Haughey, Jordan LaBouff, and Justin Martin; a feature on Honors award, scholarship, and fellowship winners; and an article on the Honors College collaboration with the IDeA Network of Biomedical Research Infrastructure (INBRE) National Genomics Research Initiative.


Removal Of Disinfection By-Product Precursors Using Magnetic Ion Exchange (Miex(R)): The Effects Of Ph And Source Water Variability, Sarah Cousins Dec 2011

Removal Of Disinfection By-Product Precursors Using Magnetic Ion Exchange (Miex(R)): The Effects Of Ph And Source Water Variability, Sarah Cousins

Graduate Theses and Dissertations

Disinfection by-products (DBPs) form as an unintended result of drinking water disinfection, from chemical reactions between disinfectants (e.g., free chlorine) and naturally occurring dissolved organic matter (DOM). At present, 11 DBPs are regulated in treated drinking waters due to potential adverse health effects, including four trihalomethanes (THMs). Despite nearly 40 years of DBP research, compliance with DBP regulations remains a challenge for many drinking water treatment plants (DWTPs), including the four DWTPs located on the Beaver Lake Reservoir in Northwest Arkansas. Due to the high net negative surface charge on DOM, anion exchange is one potentially viable method for removing …


Powersearch: Augmenting Mobile Phone Search Through Personalization, Xiangyu Liu Dec 2011

Powersearch: Augmenting Mobile Phone Search Through Personalization, Xiangyu Liu

Computer Science and Computer Engineering Undergraduate Honors Theses

Cell phone has become a fundamental element of people's life. People use it to call each other, browse websites, send text messages, etc. Among all the functionalities, the most important and frequently used is the search functionality. Based on ComScore, in July 2008, Google was estimated to host 235 millions searches per day. However, unlike the search on desktop, the search on cell phone has one critical constrain: battery. Cell phone performing a normal Google search, the battery drains very fast. The reason is that when sending a query to and fetching the results from Google, cell phone keeps communicating …


Designing Carbon Taxation Schemes For Automobiles: A Simulation Exercise For Germany, Adamos Adamou, Sofronis Clerides, Theodoros Zachariadis Dec 2011

Designing Carbon Taxation Schemes For Automobiles: A Simulation Exercise For Germany, Adamos Adamou, Sofronis Clerides, Theodoros Zachariadis

Theodoros Zachariadis

Vehicle taxation based on CO2 emissions is increasingly being adopted worldwide in order to shift consumer purchases to low-carbon cars, yet little is known about the effectiveness and overall economic impact of these schemes. We focus on feebate schemes, which impose a fee on high-carbon vehicles and give a rebate to purchasers of low-carbon automobiles. We estimate a discrete choice model of demand for automobiles in Germany and simulate the impact of alternative feebate schemes on emissions, consumer welfare, public revenues and firm profits. The analysis shows that a well-designed scheme can lead to emission reductions without reducing overall welfare.


The Value Of Government Mandated Location-Based Services In Emergencies In Australia, Anas Aloudat, Katina Michael, Roba Abbas, Mutaz M. Al-Debei Dec 2011

The Value Of Government Mandated Location-Based Services In Emergencies In Australia, Anas Aloudat, Katina Michael, Roba Abbas, Mutaz M. Al-Debei

Dr. Mutaz M. Al-Debei

The adoption of mobile technologies for emergency management has the capacity to save lives. In Australia in February 2009, the Victorian Bushfires claimed 173 lives, the worst peace-time disaster in the nation’s history. The Australian government responded swiftly to the tragedy by going to tender for mobile applications that could be used during emergencies, such as mobile alerts and location services. These applications, which are becoming increasingly accurate with the evolution of positioning techniques, have the ability to deliver personalized information direct to the citizen during crises, complementing traditional broadcasting mediums like television and radio. Indeed governments have a responsibility …


Lectio Praecursoria, Kari Myöhänen Dec 2011

Lectio Praecursoria, Kari Myöhänen

Kari Myöhänen

Lectio praecursoria: Modelling of combustion and sorbent reactions in three-dimensional flow environment of a circulating fluidized bed furnace


Transient Flow Of A Generalized Second Grade Fluid Due To A Constant Surface Shear Stress: An Approximate Integral-Balance Solution, Jordan Hristov Dec 2011

Transient Flow Of A Generalized Second Grade Fluid Due To A Constant Surface Shear Stress: An Approximate Integral-Balance Solution, Jordan Hristov

Jordan Hristov

Integral balance solution to start-up problem of a second grade viscoelastic fluid caused by a constant surface stress at the surface has been developed by an entire-domain parabolic profile with an unspecified exponent. The closed form solution explicitly defines two dimensionless similarity variables ξ = y ν t and 2 D0 p t= χ = ν β , responsible for the viscous and the elastic responses of the fluid to the step jump at the boundary. Numerical simulations demonstrating the effect of the various operating parameter and fluid properties on the developed flow filed, as well comparison with the existing …


Quantification Of Stochastic Uncertainty Propagation For Monte Carlo Depletion Methods In Reactor Analysis, Quentin Thomas Newell Dec 2011

Quantification Of Stochastic Uncertainty Propagation For Monte Carlo Depletion Methods In Reactor Analysis, Quentin Thomas Newell

UNLV Theses, Dissertations, Professional Papers, and Capstones

The Monte Carlo method provides powerful geometric modeling capabilities for large problem domains in 3-D; therefore, the Monte Carlo method is becoming popular for 3-D fuel depletion analyses to compute quantities of interest in spent nuclear fuel including isotopic compositions. The Monte Carlo approach has not been fully embraced due to unresolved issues concerning the effect of Monte Carlo uncertainties on the predicted results.

Use of the Monte Carlo method to solve the neutron transport equation introduces stochastic uncertainty in the computed fluxes. These fluxes are used to collapse cross sections, estimate power distributions, and deplete the fuel within depletion …


Modeling Passive Solar Distillation Production In Las Vegas, Nevada, Noe I. Santos Dec 2011

Modeling Passive Solar Distillation Production In Las Vegas, Nevada, Noe I. Santos

UNLV Theses, Dissertations, Professional Papers, and Capstones

A study has been performed to examine the effects of daily weather on the performance of commercial solar distillation basins (solar stills). The objectives of this study were to evaluate the long term performance of solar stills, to instrument two solar stills and record sub-hourly thermal properties, to evaluate existing heat transfer modeling methods for hourly production, and to create new models to predict daily production using experimental distillate production and local weather data by utilizing artificial neural networks, genetic algorithms, and multivariate regression. A system dynamics model was also created to determine the required basin area and storage volume …


Stability And Classification Performance Of Feature Selection Techniques, Huanjing Wang, Taghi Khoshgoftaar, Qianhui Liang Dec 2011

Stability And Classification Performance Of Feature Selection Techniques, Huanjing Wang, Taghi Khoshgoftaar, Qianhui Liang

Computer Science Faculty Publications

Feature selection techniques can be evaluated based on either model performance or the stability (robustness) of the technique. The ideal situation is to choose a feature selec- tion technique that is robust to change, while also ensuring that models built with the selected features perform well. One domain where feature selection is especially important is software defect prediction, where large numbers of met- rics collected from previous software projects are used to help engineers focus their efforts on the most faulty mod- ules. This study presents a comprehensive empirical ex- amination of seven filter-based feature ranking techniques (rankers) applied to …


Fast Super-Resolution With Affine Motion Using An Adaptive Wiener Filter And Its Application To Airborne Imaging, Russell C. Hardie, Kenneth J. Barnard, Raúl Ordóñez Dec 2011

Fast Super-Resolution With Affine Motion Using An Adaptive Wiener Filter And Its Application To Airborne Imaging, Russell C. Hardie, Kenneth J. Barnard, Raúl Ordóñez

Electrical and Computer Engineering Faculty Publications

Fast nonuniform interpolation based super-resolution (SR) has traditionally been limited to applications with translational interframe motion. This is in part because such methods are based on an underlying assumption that the warping and blurring components in the observation model commute. For translational motion this is the case, but it is not true in general. This presents a problem for applications such as airborne imaging where translation may be insufficient. Here we present a new Fourier domain analysis to show that, for many image systems, an affine warping model with limited zoom and shear approximately commutes with the point spread function …


Concept Tests For A New Wire Flying Vehicle Designed To Achieve High Horizontal Resolution Profiling In Deep Water, Chris Roman, Dave Hebert Dec 2011

Concept Tests For A New Wire Flying Vehicle Designed To Achieve High Horizontal Resolution Profiling In Deep Water, Chris Roman, Dave Hebert

Graduate School of Oceanography Faculty Publications

Efficiently profiling the water column to achieve both high vertical and horizontal resolution from a moving vessel in deep water is difficult. Current solutions, such as CTD tow-yos, moving vessel profilers, and undulating tow bodies, are limited by ship speed or water depth. As a consequence, it is difficult to obtain oceanographic sections with sufficient resolution to identify many relevant scales over the deeper sections of the water column. This paper presents a new concept for a profiling vehicle that slides up and down a towed wire in a controlled manner using the lift created by wing foils. The wings …


Water Quality Models For Stormwater Runoff In Two Lincoln, Nebraska Urban Watersheds, Jake Fisher Dec 2011

Water Quality Models For Stormwater Runoff In Two Lincoln, Nebraska Urban Watersheds, Jake Fisher

Department of Civil and Environmental Engineering: Dissertations, Theses, and Student Research

Water quality monitoring was conducted in two urban watersheds (Colonial Hills and Taylor Park) located in southeast Lincoln, NE over a three year period spanning from October 2008 through September 2011. In-line probes continuously measured for turbidity, conductivity, dissolved oxygen, and water temperature while other water quality constituents were analyzed for discrete water samples collected using grab and automatic sampling techniques. The water quality data was used to calculate event mean concentrations (EMCs) for sixteen storm events sampled over the duration of the project period. Three types of stormwater quality multiple linear regression models were developed for the estimation of …


On The Pooling Of Positive Examples With Ontology For Visual Concept Learning, Shiai Zhu, Chong-Wah Ngo, Yu-Gang Jiang Dec 2011

On The Pooling Of Positive Examples With Ontology For Visual Concept Learning, Shiai Zhu, Chong-Wah Ngo, Yu-Gang Jiang

Research Collection School Of Computing and Information Systems

A common obstacle in effective learning of visual concept classifiers is the scarcity of positive training examples due to expensive labeling cost. This paper explores the sampling of weakly tagged web images for concept learning without human assistance. In particular, ontology knowledge is incorporated for semantic pooling of positive examples from ontologically neighboring concepts. This effectively widens the coverage of the positive samples with visually more diversified content, which is important for learning a good concept classifier. We experiment with two learning strategies: aggregate and incremental. The former strategy re-trains a new classifier by combining existing and newly collected examples, …


Water Quality Trends For Section 319 Priority Watersheds In Northwest Arkansas, 1997-2010, Bryan William Bailey Dec 2011

Water Quality Trends For Section 319 Priority Watersheds In Northwest Arkansas, 1997-2010, Bryan William Bailey

Graduate Theses and Dissertations

Northwest Arkansas contains two Section 319 Priority Watersheds that the Arkansas Natural Resources Commission (ANRC) has identified as being impacted by point and nonpoint sources of pollution (i.e., phosphorus, nitrogen, and sediment), and the Arkansas Water Resources Center (AWRC) has monitored the water quality at several sites within these watersheds. Water-quality data has been collected over the last decade within the Illinois River Watershed (HUC #11110103) and the Upper White River Basin (Beaver Reservoir HUC# 11010001), each watershed containing three sampling sites. The Illinois River Watershed sites are located on the Illinois River, Osage Creek, and Ballard Creek, and the …


Synthesis And Characterization Of Catalysts For The Selective Transformation Of Biomass-Derived Materials, Isaac Tyrone Ghampson Dec 2011

Synthesis And Characterization Of Catalysts For The Selective Transformation Of Biomass-Derived Materials, Isaac Tyrone Ghampson

Electronic Theses and Dissertations

The experimental work in this thesis focuses on generating catalysts for two intermediate processes related to the thermal conversion of lignocellulosic biomass: the synthesis and characterization of mesoporous silica supported cobalt catalysts for the Fischer-Tropsch reaction, and an exploration of the reactivity of bulk and supported molybdenum-based nitride catalysts for the hydrodeoxygenation (HDO) of guaiacol, a lignin model compound. The first section of the work details the synthesis of a series of silicasupported cobalt Fischer-Tropsch catalysts with pore diameters ranging from 2-23 nm. Detailed X-ray diffraction measurements were used to determine the composition and particle diameters of the metal fraction, …