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Full-Text Articles in Physical Sciences and Mathematics
Mixed-Metal Cluster Synthesis: [Re(Co)3(Μ-S2Nc7H4)]2 As A Precursor For Tri- And Tetranuclear 2-Mercaptobenzothiolato Capped Clusters, Shishir Ghosh, Kamrun N. Khanam, Md. Kamal Hossain, G. M. Golzar Hossain, Daniel T. Haworth, Sergey V. Lindeman, Graeme Hogarth, Shariff E. Kabir
Mixed-Metal Cluster Synthesis: [Re(Co)3(Μ-S2Nc7H4)]2 As A Precursor For Tri- And Tetranuclear 2-Mercaptobenzothiolato Capped Clusters, Shishir Ghosh, Kamrun N. Khanam, Md. Kamal Hossain, G. M. Golzar Hossain, Daniel T. Haworth, Sergey V. Lindeman, Graeme Hogarth, Shariff E. Kabir
Chemistry Faculty Research and Publications
The readily prepared [Re2(CO)6(μ-S2NC7H4)2] (1) reacts with Group 8 trimetallic carbonyl clusters to yield new mixed-metal tri- and tetranuclear clusters. With [Os3(CO)10(NCMe)2] at 80 °C the tetranuclear mixed-metal cluster [Os3Re(CO)13(μ3-C7H4NS2)] (2) is the only isolated product. With Ru3(CO)12 products are dependent upon the reaction temperature. At 80 °C, a mixture of tetranuclear mixed-metal [Ru3Re(CO)13(μ3-C7H4NS2)] (5) …