Nuclear Engineering Commons^™

Nuclear Fuel Materials Under Extremes: Redox Behavior And Resulting Defect Structure, William Cureton

Doctoral Dissertations

Oxide nuclear fuel materials and analogues are often subject to complex structural and chemical changes when exposed to extreme environments. For example, oxidation and buildup of fission products cause changes to the local- and long-range structure as well as the chemistry and stoichiometry of UO₂ during operation in light water reactors. Highly ionizing energetic fission fragments have been shown to cause redox effects and associated defect structures in oxide nuclear fuel-type materials. The underlying mechanisms that lead to defect structures produced in a wider range of nuclear fuel material compositions and microstructures is not well understood.

This research project …

Real-Time Identification Of Oxygen Vacancy Centers In Linbo₃ And Srtio₃ During Irradiation With High Energy Particles, Miguel L. Crespillo, Joseph T. Graham, Fernando Agulló-López, Yanwen Zhang, William J. Weber

Nuclear Engineering and Radiation Science Faculty Research & Creative Works

Oxygen vacancies are known to play a central role in the optoelectronic properties of oxide perovskites. A detailed description of the exact mechanisms by which oxygen vacancies govern such properties, however, is still quite incomplete. The unambiguous identification of oxygen vacancies has been a subject of intense discussion. Interest in oxygen vacancies is not purely academic. Precise control of oxygen vacancies has potential technological benefits in optoelectronic devices. In this review paper, we focus our attention on the generation of oxygen vacancies by irradiation with high energy particles. Irradiation constitutes an efficient and reliable strategy to introduce, monitor, and characterize …

Recent Advances On Carrier And Exciton Self-Trapping In Strontium Titanate: Understanding The Luminescence Emissions, Miguel L. Crespillo, Joseph T. Graham, Fernando Agullo-Lopez, Yanwen Zhang, William J. Weber

Nuclear Engineering and Radiation Science Faculty Research & Creative Works

An up-to-date review on recent results for self-trapping of free electrons and holes, as well as excitons, in strontium titanate (STO), which gives rise to small polarons and self-trapped excitons (STEs) is presented. Special attention is paid to the role of carrier and exciton self-trapping on the luminescence emissions under a variety of excitation sources with special emphasis on experiments with laser pulses and energetic ion-beams. In spite of the extensive research effort, a definitive identification of such localized states, as well as a suitable understanding of their operative light emission mechanisms, has remained lacking or controversial. However, promising advances …

Neutron Irradiation Effects On Domain Wall Mobility And Reversibility In Lead Zirconate Titanate Thin Films, Joseph T. Graham, Geoff L. Brennecka, Paulo Ferreira, Leo Small, David Duquette, Christopher Apblett, Sheldon Landsberger, Jon F. Ihlefeld

Nuclear Engineering and Radiation Science Faculty Research & Creative Works

The effects of neutron-induced damage on the ferroelectric properties of thin film lead zirconate titanate (PZT) were investigated. Two sets of PbZr_0.52Ti_0.48O₃ films of varying initial quality were irradiated in a research nuclear reactor up to a maximum 1 MeV equivalent neutron fluence of (5.16± 0.03) x 10¹⁵ cm^-2. Changes in domain wall mobility and reversibility were characterized by polarization-electric field measurements, Rayleigh analysis, and analysis of first order reversal curves (FORC). With increasing fluence, extrinsic contributions to the small-signal permittivity diminished. Additionally, redistribution of irreversible hysterons towards higher coercive fields was …