Open Access. Powered by Scholars. Published by Universities.®

Nuclear Engineering Commons

Open Access. Powered by Scholars. Published by Universities.®

2019

Crystallographic structure

Articles 1 - 1 of 1

Full-Text Articles in Nuclear Engineering

Crystallographic Changes In Lead Zirconate Titanate Due To Neutron Irradiation, Alexandra Henriques, Joseph T. Graham, Sheldon Landsberger, Jon F. Ihlefeld, Geoff L. Brennecka, Donald W. Brown, Jennifer S. Forrester, Jacob L. Jones Feb 2019

Crystallographic Changes In Lead Zirconate Titanate Due To Neutron Irradiation, Alexandra Henriques, Joseph T. Graham, Sheldon Landsberger, Jon F. Ihlefeld, Geoff L. Brennecka, Donald W. Brown, Jennifer S. Forrester, Jacob L. Jones

Joseph T. Graham

Piezoelectric and ferroelectric materials are useful as the active element in non-destructive monitoring devices for high-radiation areas. Here, crystallographic structural refinement (i.e., the Rietveld method) is used to quantify the type and extent of structural changes in PbZr0.5Ti0.5O3 after exposure to a 1 MeV equivalent neutron fluence of 1.7x1015 neutrons/cm2. The results showa measurable decrease in the occupancy of Pb and O due to irradiation, with O vacancies in the tetragonal phase being created preferentially on one of the two O sites. The results demonstrate a method by ...