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Nuclear Engineering Commons

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2016

Boise State University Theses and Dissertations

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Thermoelectric Half-Heuslers: Synthesis, Processing, And Performance, Joseph Robert Croteau Aug 2016

Thermoelectric Half-Heuslers: Synthesis, Processing, And Performance, Joseph Robert Croteau

Boise State University Theses and Dissertations

Thermoelectric half-Heusler compounds have potential to convert the heat wasted from industrial and transportation processes to useful electricity. Among the highest performing half-Heusler compounds are nano-structured bulk materials which have been arc-melted, pulverized into a nano-powder, and sintered by DC-hot press. High performing n- and p-type half-Heusler compounds with nominal composition of Hf0.25Zr0.75NiSn0.99Sb0.01 and Nb0.75Ti0.25FeSb, respectively, have been provided to us in both dense and powder form by our collaborators at the University of Houston. We consolidate these powders by SPS, refine these powders to improve both particle size …