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Full-Text Articles in Nuclear Engineering
Synthesis And Thermodynamic Analysis Of Volatile Beta-Diketone Complexes Of Select Lanthanides Via Gas-Phase Separations, Daniel Hanson
Synthesis And Thermodynamic Analysis Of Volatile Beta-Diketone Complexes Of Select Lanthanides Via Gas-Phase Separations, Daniel Hanson
Doctoral Dissertations
Rapid separation techniques for fission and activation products have long been desired to supplant the slow solution-based methodologies currently used. In this work, rare earth elements were derivatized with β [beta]-diketones to synthesize rare earth complexes with high volatility suitable for gas-phase separations. Rare earth elements samarium and dysprosium were combined with hfac (1,1,1,5,5,5-hexafluoro-2,4-pentadione) and fod (6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedione) and analyzed using a gas-phase separation technique. Rare earth elements praseodymium and europium were combined with dpm (2,2,6,6-tetra-methyl-3,5-heptanedione) and similarly analyzed. Employing the data from the separations, the entropy (Δ [delta] S) and enthalpy (Δ [delta] H) of adsorption were evaluated mathematically based …
Doube-Pulse Laser-Induced Breakdown Spectroscopy Of Multi-Element Sample Containing Low- And High-Z Analytes, Patrick J. Skrodzki, Jason R. Becker, Prasoon K. Diwakar Ph. D., Sivanandan S. Harilal Ph. D., Ahmed Hassanein Ph. D.
Doube-Pulse Laser-Induced Breakdown Spectroscopy Of Multi-Element Sample Containing Low- And High-Z Analytes, Patrick J. Skrodzki, Jason R. Becker, Prasoon K. Diwakar Ph. D., Sivanandan S. Harilal Ph. D., Ahmed Hassanein Ph. D.
The Summer Undergraduate Research Fellowship (SURF) Symposium
Laser-induced breakdown spectroscopy (LIBS) is a portable, remote, non-invasive analytical technique which effectively distinguishes neutral and ionic species for a range of low- to high-Z elements in a multi-element target. Subsequently, LIBS holds potential in special nuclear material (SNM) sensing and nuclear forensics requiring minimal sample preparation and detecting isotopic shifts which allows for differentiation in SNM (namely U) enrichment levels. Feasible applications include not only nonproliferation and homeland security but also nuclear fuel prospecting and industrial safeguard endorsement. Elements of higher mass with complex atomic structures, such as U, however, result in crowded emission spectra with LIBS, and characteristic …