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Open Access. Powered by Scholars. Published by Universities.®

2014

Inorganic Chemistry

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Full-Text Articles in Nuclear Engineering

Synthesis And Thermodynamic Analysis Of Volatile Beta-Diketone Complexes Of Select Lanthanides Via Gas-Phase Separations, Daniel Hanson Dec 2014

Synthesis And Thermodynamic Analysis Of Volatile Beta-Diketone Complexes Of Select Lanthanides Via Gas-Phase Separations, Daniel Hanson

Doctoral Dissertations

Rapid separation techniques for fission and activation products have long been desired to supplant the slow solution-based methodologies currently used. In this work, rare earth elements were derivatized with β [beta]-diketones to synthesize rare earth complexes with high volatility suitable for gas-phase separations. Rare earth elements samarium and dysprosium were combined with hfac (1,1,1,5,5,5-hexafluoro-2,4-pentadione) and fod (6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedione) and analyzed using a gas-phase separation technique. Rare earth elements praseodymium and europium were combined with dpm (2,2,6,6-tetra-methyl-3,5-heptanedione) and similarly analyzed. Employing the data from the separations, the entropy (Δ [delta] S) and enthalpy (Δ [delta] H) of adsorption were evaluated mathematically based …

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Termodynamika Procesowa I Techniczna Lab., Wojciech M. Budzianowski Jan 2014

Termodynamika Procesowa I Techniczna Lab., Wojciech M. Budzianowski

Wojciech Budzianowski

No abstract provided.

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Tematyka Prac Dyplomowych Dla Studentów Wydziału Mechaniczno-Energetycznego Pwr., Wojciech M. Budzianowski Jan 2014

Tematyka Prac Dyplomowych Dla Studentów Wydziału Mechaniczno-Energetycznego Pwr., Wojciech M. Budzianowski

Wojciech Budzianowski

No abstract provided.

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Tematyka Prac Dyplomowych Dla Studentów Wydziału Chemicznego Pwr., Wojciech M. Budzianowski Jan 2014

Tematyka Prac Dyplomowych Dla Studentów Wydziału Chemicznego Pwr., Wojciech M. Budzianowski

Wojciech Budzianowski

No abstract provided.

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Mechanika Płynów Lab., Wojciech M. Budzianowski Jan 2014

Mechanika Płynów Lab., Wojciech M. Budzianowski

Wojciech Budzianowski

No abstract provided.

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