Nuclear Engineering Commons^™

Environment-Induced Degradation And Crack-Growth Studies Of Candidate Target Materials: Aaa Task-4 Quarterly (September 1 – November 30, 2001) Report, Ajit K. Roy, Brendan O'Toole

Transmutation Sciences Materials (TRP)

The primary objective of this task is to evaluate the effect of hydrogen on environment-assisted cracking of candidate materials for applications in spallation-neutron-target (SNT) systems such as accelerator production of tritium (APT) and accelerator transmutation of waste (ATW). The materials selected for evaluation and characterization are martensitic stainless steels including HT- 9, EP 823 and 422. The susceptibility to stress corrosion cracking (SCC) and hydrogen embrittlement (HE) of these alloys will be evaluated in environments of interest using tensile specimens under constant load and slow-strain-rate (SSR) conditions. The extent and morphology of cracking of these alloys will further be evaluated …

Development Of A Mechanistic Understanding Of High-Temperature Deformation Of Alloy Ep-823: Task 10, First Quarter Report, Ajit K. Roy, Brendan O'Toole

Transmutation Sciences Materials (TRP)

The objective of this task is to evaluate the elevated temperature tensile properties of Alloy EP-823, a leading target material for accelerator-driven waste transmutation applications. The test material will be thermally treated prior to evaluation of its tensile properties at temperatures relevant to the transmutation applications. The deformation characteristics of tensile specimens, upon completion of testing, will be evaluated by surface analytical techniques including scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The overall results are expected to provide a mechanistic understanding of high-temperature deformation behavior of Alloy EP-823 as a function of heat treatment.

Highlights of Accomplishment

• …

Modeling, Fabrication, And Optimization Of Niobium Cavities – Phase I: Quarterly Progress Report August 20, 2001 - November 20, 2001, Robert A. Schill Jr., Mohamed Trabia

Transmutation Sciences Materials (TRP)

Multipacting is one of the major loss mechanisms in rf superconductivity cavities for accelerators. This loss mechanism limits the maximum amount of energy/power supported by the cavities. Optimal designs have been identified in others’ studies. In practice, these designs are not easily manufactured. Chemical etching processes used to polish the cavity walls result in a nonuniform surface etch. A nonuniform surface etch will leave some unclean areas with contaminants and micron size particles. These significantly affect mutipacting. Further, a nonuniform etch will leave areas with damaged grain structure, which is not good for superconducting properties. Typically, the depth of chemical …

Analysis Of Corrosion Of Steel By Lead Bismuth Eutectic, John Farley, Dale L. Perry

Transmutation Sciences Materials (TRP)

We examined stainless samples that were exposed to LBE in experiments conducted by the Russians, under contract to Los Alamos. We examined both corroded and uncorroded samples using the Scanning Electron Microscope (SEM), the Energy Dispersive X-Ray (EDAX) Spectroscopy, and the X-ray Photoelectron Spectrometer (XPS). We found that the surface of the corroded sample is covered by oxygen-containing compounds, presumably mostly iron oxide. In samples exposed for shorter times or lower temperatures, we found that some areas were covered by an oxide layer, and some areas was uncovered. We found that the level of Cr in the uncovered area is …

Modeling Corrosion In Oxygen Controlled Lbe Systems With Coupling Of Chemical Kinetics And Hydrodynamics: Quarterly Progress Report August 16,2001- November 15, 2001, Samir Moujaes, Yitung Chen

Transmutation Sciences Materials (TRP)

The Lead-Bismuth eutectic (LBE) has been determined from previous experimental studies by the Russians and the European scientific community to be a potential material that can be used as a spallation target and coolant for the AAA proposed application.

Properly controlling the oxygen content in LBE can drastically reduce the LBE corrosion to structural steels. However, existing knowledge of material corrosion performance was obtained from point-wise testing with very limited density. The transport of oxygen and corrosion products, their interaction and variation of corrosion/precipitation along the flow are not well understood.

The first subtask of this project involves using a …

Environment-Induced Degradation And Crack-Growth Studies Of Candidate Target Materials: Aaa Task-4 Quarterly (June 1 – August 31, 2001) Report, Ajit K. Roy, Brendan O'Toole

Transmutation Sciences Materials (TRP)

The subject task entitled “Hydrogen-Induced Embrittlement of Candidate Target Materials for Applications in Spallation-Neutron-Target Systems” had commenced during the quarter ending on August 31, 2001. A research account has been established, contracts for both faculty and students have been prepared, and efforts are well underway to embark on the related research activities, as proposed.

As the title of this project implies, the primary objective of this task is to evaluate the effect of hydrogen on environment-assisted cracking of candidate materials for applications in spallationneutron- target (SNT) systems such as accelerator production of tritium (APT) and accelerator transmutation of waste (ATW). …

Modeling, Fabrication, And Optimization Of Niobium Cavities – Phase I: Quarterly Progress Report May 15, 2001 - August 15, 2001, Robert A. Schill Jr., Mohamed Trabia

Transmutation Sciences Materials (TRP)

Multipacting is one of the major loss mechanisms in rf superconductivity cavities for accelerators. This loss mechanism limits the maximum amount of energy/power supported by the cavities. Optimal designs have been identified in others’ studies. In practice, these designs are not easily manufactured. Chemical etching processes used to polish the cavity walls result in a nonuniform surface etch compromising the optimal geometrical design. Past multipacting studies have not examined the impact of wall perturbations.

It is the purpose of this study to examine the chemical etching process in the design of niobium cavities so to maximize the surface quality of …

Analysis Of Corrosion Of Steel By Lead Bismuth Eutectic, John Farley, Dale L. Perry

Transmutation Sciences Materials (TRP)

The goal is to achieve a basic understanding of the corrosion of stainless steel by Lead Bismuth Eutectic (LBE), which has been proposed for use in the transmuter as both a coolant and as a sputtering target.

Development Of A Mechanistic Understanding Of High-Temperature Deformation Of Alloy Ep-823 For Transmutation Applications, Ajit K. Roy, Brendan O'Toole

Transmutation Sciences Materials (TRP)

The purpose of this project is to evaluate the elevated temperature tensile properties of Alloy EP- 823, a leading target material for accelerator-driven waste transmutation applications. This alloy has been proven to be an excellent structural material to contain the lead-bismuth-eutectic (LBE) nuclear coolant needed for fast spectrum operations. However, very little data exist in the open literature on the tensile properties of this alloy. The selection of Alloy EP-823 as the test material in the proposed task is based on the recommendation of our collaborator at the Los Alamos National Laboratory (LANL). The test material will be thermally treated …

Modeling Corrosion In Oxygen Controlled Lbe Systems With Coupling Of Chemical Kinetics And Hydrodynamics, Samir Moujaes, Yitung Chen

Transmutation Sciences Materials (TRP)

The proposed work will combine chemical kinetics and hydrodynamics in target and test-loop lead-bismuth eutectic (LBE) systems to model system corrosion effects. This approach will result in a predicative tool that can be validated with corrosion test data, used to systematically design tests and interpret the results, and provide guidance for optimization in LBE system designs. The task includes of two subtasks. The first subtask is to try to develop the necessary predictive tools to be able to predict the levels of oxygen and corrosion products close to the boundary layer through the use of Computational Fluid Dynamics (CFD) modeling. …

Hydrogen-Induced Embrittlement Of Candidate Target Materials For Applications In Spallation-Neutron-Target Systems, Brendan O'Toole, Ajit K. Roy

Transmutation Sciences Materials (TRP)

The purpose of this project is to evaluate the effect of hydrogen on cracking of candidate target materials for applications in spallation-neutron-target (SNT) systems such as accelerator production of tritium (APT) and accelerator transmutation of waste (ATW). The test materials will undergo appropriate thermal treatments prior to being hydrogen-charged by potentiostatic cathodic polarization technique in a simulated aqueous environment at different temperatures of interest. The specimens, upon completion of testing, will be metallographically examined. Further, the scanning electron microscopy (SEM) will be used to determine the extent and nature of cracking in the specimens tested. The thrust of the proposed …

Modeling, Fabrication, And Optimization Of Niobium Cavities: Phase I, Robert A. Schill Jr., Mohamed Trabia

Transmutation Sciences Materials (TRP)

Niobium cavities are important parts of the integrated NC/SC high-power linacs. Over the years, researchers in several countries have tested various cavity shapes. They concluded that elliptically shaped cells and buffered chemical polishing produce good performance. The objective of the proposed research is to maximize the performance of the niobium cavities through studying multipacting, studying the effect of chemical etching on the surface roughness, and redesigning the cavities.

The US Congress has recently authorized exploring an alternative way to deal with spent nuclear fuel: Accelerator Transmuting of Waste (ATW). In this approach, a particle accelerator produces protons that react with …

Experimental Investigation Of Steel Corrosion In Lead Bismuth Eutectic (Lbe): Characterization, Species Identification, And Chemical Reactions, John Farley, Dale L. Perry

Transmutation Sciences Materials (TRP)

The goal of the present research is to achieve a basic understanding of corrosion of steels by Lead Bismuth Eutectic (LBE). Liquid LBE is under consideration in the transmuter as both a coolant and a target material. There have been studies of LBE, especially by the Russians, but a fundamental understanding and verification of its role in the corrosion of steels is still very 2 incomplete. Post-experiment testing and analysis will be performed on steel samples that have been in intimate contact with LBE. Chemical alterations and resulting chemical species will be measured at the steel surface. Techniques to be …