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Chemistry

Electronic Thesis and Dissertation Repository

Alloy 800; Fe-Cr-Ni Alloy; Metal Oxides; Oxide Film Formation; Metal Dissolution; Interfacial Reactions; Electrochemical Reactions; Water Radiolysis; gamma-Radiation; Steady-state radiolysis;

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Gamma-Radiation Induced Corrosion Of Alloy 800, Mojtaba Momeni Nov 2017

Gamma-Radiation Induced Corrosion Of Alloy 800, Mojtaba Momeni

Electronic Thesis and Dissertation Repository

This thesis presents a newly developed mechanism and predictive model for the corrosion of Alloy 800. The Fe-Cr-Ni Alloy (Incoloy 800) is mainly used for steam generator (SG) tubing in CANDU and PWR reactors and is a candidate material for the proposed Canadian Supercritical Water Reactor (SCWR) in which it will be exposed to extreme conditions of high radiation flux and large temperature gradients. The influence of gamma radiation and water chemistry conditions on the corrosion behaviour of Alloy 800 are studied in this work. Ionizing radiation creates reducing (•eaq, •H, •O2-) and oxidizing …