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Full-Text Articles in Nanoscience and Nanotechnology
Nanostructured Tin-Based Anodes For Lithium Ion Batteries With X-Ray Absorption Fine Structure Studies, Dongniu Wang
Nanostructured Tin-Based Anodes For Lithium Ion Batteries With X-Ray Absorption Fine Structure Studies, Dongniu Wang
Electronic Thesis and Dissertation Repository
The practical applications of lithium ion batteries are highly dependent on the choice of electrodes, where boosting the materials innovations to design and achieve high capacity, excellent cycling performance, rate capability, low-cost and safe electrode materials provide the best solution. Based on this, tin-based anodes have gained great attention due to its high theoretical capacity, low cost and nontoxic nature to environment. Nevertheless, it undergoes significant volume variation(259%)during the operation of the battery, leading to pulverization and significant capacity fade. Thus, the practical application of tin-based anodes is still quite challenging. This thesis tackles issues related to tin-based anodes. It …
Nanophase Stability In A Granular Ferh-Cu System, Radhika Barua, Felix Jiménez-Villacorta, J. E. Shield, D. Heiman, L. H. Lewis
Nanophase Stability In A Granular Ferh-Cu System, Radhika Barua, Felix Jiménez-Villacorta, J. E. Shield, D. Heiman, L. H. Lewis
Donald Heiman
A granular system of FeRh-based nanoprecipitates (∼10–15 nm diameter) embedded in a rapidly solidified copper ribbon matrix was found to transit from a metastable tetragonal L10 (AuCu-1-type) structure to a stable B2 (CsCl-type) structure upon annealing-induced coarsening to ∼94 nm. The hysteretic magnetic transition observed at ∼100 K develops a gradual broadening that accompanies the L10 → B2 crystal structure transition. It is proposed that the Cu matrix influences the structural and magnetic properties of the FeRh-based nanoparticles through interfacial strain and chemical effects. These results emphasize the sensitivity of the magnetostructural response of FeRh to changes in the nanostructural …
Nanophase Stability In A Granular Ferh-Cu System, Radhika Barua, Felix Jiménez-Villacorta, J. E. Shield, D. Heiman, L. H. Lewis
Nanophase Stability In A Granular Ferh-Cu System, Radhika Barua, Felix Jiménez-Villacorta, J. E. Shield, D. Heiman, L. H. Lewis
Felix Jiménez-Villacorta
A granular system of FeRh-based nanoprecipitates (∼10–15 nm diameter) embedded in a rapidly solidified copper ribbon matrix was found to transit from a metastable tetragonal L10 (AuCu-1-type) structure to a stable B2 (CsCl-type) structure upon annealing-induced coarsening to ∼94 nm. The hysteretic magnetic transition observed at ∼100 K develops a gradual broadening that accompanies the L10 → B2 crystal structure transition. It is proposed that the Cu matrix influences the structural and magnetic properties of the FeRh-based nanoparticles through interfacial strain and chemical effects. These results emphasize the sensitivity of the magnetostructural response of FeRh to changes in the nanostructural …
Novel Bimetallic Plasmonic Nanomaterials, Ritesh Sachan
Novel Bimetallic Plasmonic Nanomaterials, Ritesh Sachan
Doctoral Dissertations
Plasmonic nanomaterials have attracted a lot of attention recently due to their application in various fields such as chemical and biological sensing, catalysis, energy harvesting and optical devices. However, there is a need to address several outstanding issues with these materials, including cost-effective synthesis, tunability in plasmonic characteristics, and long term stability. In this thesis, we have focused on bimetallic nanoparticles (NPs) of Ag and Co due to their immiscibility as well as their individual properties. First, a pulsed laser induced dewetting route was used to synthesize Ag-Co bimetallic plasmonic NPs. An synthesis parameter space was derived to show the …
Nanoscale Electrochemistry By In-Situ Transmission Electron Microscopy, Qi Gao
Nanoscale Electrochemistry By In-Situ Transmission Electron Microscopy, Qi Gao
Dissertations, Master's Theses and Master's Reports - Open
Nanoscale research in energy storage has recently focused on investigating the properties of nanostructures in order to increase energy density, power rate, and capacity. To better understand the intrinsic properties of nanomaterials, a new and advanced in situ system was designed that allows atomic scale observation of materials under external fields. A special holder equipped with a scanning tunneling microscopy (STM) probe inside a transmission electron microscopy (TEM) system was used to perform the in situ studies on mechanical, electrical, and electrochemical properties of nanomaterials. The nanostructures of titanium dioxide (TiO2) nanotubes are characterized by electron imaging, diffraction, and chemical …