Nanoscience and Nanotechnology Commons^™

Investigation Into Effects Of Instability And Reactivity Of Hydride-Passivated Silicon Nanoparticles On Interband Photoluminescence, Christine Marie Radlinger

Dissertations and Theses

While silicon has long been utilized for its electronic properties, its use as an optical material has largely been limited due to the poor efficiency of interband transitions. However, discovery of visible photoluminescence (PL) from nanocrystalline silicon in 1990 triggered many ensuing research efforts to optimize PL from nanocrystalline silicon for optical applications. Currently, use of photoluminescent silicon nanoparticles (Si NPs) is commercially limited by: 1) the instability of the energy and intensity of the PL, and 2) the low quantum yield of interband PL from Si NPs.

Herein, red-emitting, hydrogen-passivated silicon nanoparticles (H-Si NPs) were synthesized by thermally-induced disproportionation …

Find, Build, And Export Information For 3d Printing Of Your Favorite Molecules And Crystal Structures At Two Dedicated Websites, Paul R. Destefano, Peter Moeck

Student Research Symposium

As 3D printers require instructions, the Nano-Crystallography Group at Portland State University is creating two websites (http://nanocrystallography.org/3dconvert/ and http://nanocrystallography.research.pdx.edu/3d-print-files/convert/) where such instructions are created, interactively, for the atomic arrangements of virtually all known molecules and crystals.

We will prepare a "pipeline" into which crystallographic information enters from two curated open access crystallographic databases, is manipulated to create the desired 3D models, and then is exported in either STL format (the standard for monochrome 3D printing) or VRML/X3D (the ISO successor to STL). The two aforementioned databases are the North-American mirror of the Crystallography Open Database (http://nanocrystallography.org) …

Understanding Photovoltaic Properties Of Pbs Quantum Dot Solids Via Solution Contacting, Vitalii Dereviankin, Erik Johansson

Student Research Symposium

Photovoltaic (PV) devices based on PbS quantum dot (QD) solids demonstrate high photontoelectron conversion yields. However, record power conversion efficiency remain low, in part due to small photovoltages, which in turn are affected by both bulk and interfacial defects. Their relative impacts on limiting the photovoltaic performance of QD solids are not known. Interfacial defects can be formed when contacting a semiconductor and may dominate the semiconductor/metal or metaloxide junction properties. The objective of this study is to explore whether electrochemical contacting using liquid electrolytes provides means of contacting QD solids without introducing interfacial defects. We have initially focused on …