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Articles 1 - 7 of 7
Full-Text Articles in Nanoscience and Nanotechnology
Structural Characterization Of Multimetallic Nanoparticles, Vineetha Mukundan
Structural Characterization Of Multimetallic Nanoparticles, Vineetha Mukundan
Open Access Dissertations
Bimetallic and trimetallic alloy nanoparticles have enhanced catalytic activities due to their unique structural properties. Using in situ time-resolved synchrotron based x-ray diffraction, we investigated the structural properties of nanoscale catalysts undergoing various heat treatments. Thermal treatment brings about changes in particle size, morphology, dispersion of metals on support, alloying, surface electronic properties, etc. First, the mechanisms of coalescence and grain growth in PtNiCo nanoparticles supported on planar silica on silicon were examined in detail in the temperature range 400-900°C. The sintering process in PtNiCo nanoparticles was found to be accompanied by lattice contraction and L10chemical ordering. …
Transport And Optical Properties Of Low-Dimensional Complex Systems, Andrii Iurov
Transport And Optical Properties Of Low-Dimensional Complex Systems, Andrii Iurov
Dissertations, Theses, and Capstone Projects
Over the last five years of my research work, I, my research was mainly concerned with certain crucial tunneling, transport and optical properties of novel low-dimensional graphitic and carbon-based materials as well as topological insulators. Both single-electron and many-body problems were addressed. We investigated the Dirac electrons transmission through a potential barrier in the presence of circularly polarized light. An anomalous photon-assisted enhanced transmission is predicted and explained in a comparison with the well-known Klein paradox. It is demonstrated that the perfect transmission for nearly-head-on collision in an infinite graphene is suppressed in gapped dressed states of electrons, which is …
Quantum Tuning Of Plasmons In Ultrathin Metal Films, Ao Teng
Quantum Tuning Of Plasmons In Ultrathin Metal Films, Ao Teng
Doctoral Dissertations
The surface plasmon is a coherent charge density oscillation localized at a metal surface. It can couple with light and the resulting plasmon-polariton hybrid mode is confined to volumes that are much smaller than the classical diffraction limit of light. Nano-plasmonics is a rapidly evolving field where light manipulation at the nanoscale may lead to novel applications. However, as the size of plasmonic devices approaches the quantum-size regime, the macroscopic picture of plasmon may no longer be valid. To elucidate the influence of the discretization of the single particle spectrum on the collective plasmon response, we performed a systematic study …
Nanoscale Manipulation Of Pristine And Functionalized Freestanding Graphene Using Scanning Tunneling Microscopy, Matthew Ackerman
Nanoscale Manipulation Of Pristine And Functionalized Freestanding Graphene Using Scanning Tunneling Microscopy, Matthew Ackerman
Graduate Theses and Dissertations
Over the past ten years the 2D material graphene has attracted an enourmous amount of attention from researchers from across diciplines and all over the world. Many of its outstanding electronic properties are present only when it is not interacting with a substrate but is instead freestanding. In this work I demonstrate that pristine and functionalized freestanding graphene can be imaged using a scanning tunneling microscope (STM) and that imaging a flexible 2D surface is fundamentally different from imaging a bulk material due to the attraction between the STM tip and the sample. This attraction can be used to manipulate …
The Soft Mode Driven Dynamics Of Ferroelectric Perovskites At The Nanoscale: An Atomistic Study, Kevin Mccash
The Soft Mode Driven Dynamics Of Ferroelectric Perovskites At The Nanoscale: An Atomistic Study, Kevin Mccash
USF Tampa Graduate Theses and Dissertations
The discovery of ferroelectricity at the nanoscale has incited a lot of interest in perovskite ferroelectrics not only for their potential in device application but also for their potential to expand fundamental understanding of complex phenomena at very small size scales. Unfortunately, not much is known about the dynamics of ferroelectrics at this scale. Many of the widely held theories for ferroelectric materials are based on bulk dynamics which break down when applied to smaller scales. In an effort to increase understanding of nanoscale ferroelectric materials we use atomistic resolution computational simulations to investigate the dynamics of polar perovskites. Within …
Organic Ferroelectric Evaporator With Substrate Cooling And In Situ Transport Capabilities, Keith Foreman, C. Labedz, M. Shearer, Shireen Adenwalla
Organic Ferroelectric Evaporator With Substrate Cooling And In Situ Transport Capabilities, Keith Foreman, C. Labedz, M. Shearer, Shireen Adenwalla
Shireen Adenwalla Papers
We report on the design, operation, and performance of a thermal evaporation chamber capable of evaporating organic thin films. Organic thin films are employed in a diverse range of devices and can provide insight into fundamental physical phenomena. However, growing organic thin films is often challenging and requires very specific deposition parameters. The chamber presented here is capable of cooling sample substrates to temperatures below 130 K and allows for the detachment of the sample from the cooling stage and in situ transport. This permits the use of multiple deposition techniques in separate, but connected, deposition chambers without breaking vacuum …
Shaping Carbon Nanotube Forests For Field Emission, Ben Pound
Shaping Carbon Nanotube Forests For Field Emission, Ben Pound
Ben Pound
No abstract provided.