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Full-Text Articles in Nanoscience and Nanotechnology

Advances On The Development Of Novel Heterogeneous Catalysts For Transesterification Of Triglycerides In Biodiesel, João F. Gomes Jan 2010

Advances On The Development Of Novel Heterogeneous Catalysts For Transesterification Of Triglycerides In Biodiesel, João F. Gomes

João F Gomes

This paper describes experimental work done towards the search for more profitable and sustainable alternatives regarding biodiesel production, using heterogeneous catalysts instead of the conventional homogenous alkaline catalysts, such as NaOH, KOH or sodium methoxide, for the methanolysis reaction. This experimental work is a first stage on the development and optimization of new solid catalysts, able to produce biodiesel from vegetable oils. The heterogeneous catalytic process has many differences from the currently used in industry homogeneous process. The main advantage is that, it requires lower investment costs, since no need for separation steps of methanol/catalyst, biodiesel/catalyst and glycerine/catalyst. This work …


A Simulation Study On The Abatement Of Co2 Emissions By De-Absorption, João F. Gomes Jan 2010

A Simulation Study On The Abatement Of Co2 Emissions By De-Absorption, João F. Gomes

João F Gomes

Due to the adverse effect of CO2 from fossil fuel combustion on the earth’s ecosystems, the most cost effective method for CO2 capture is an important area of research. The predominant process for CO2 capture currently employed by industry is chemical absorption in amine solutions. A dynamic model for the de-absorption process was developed with Monoethanolamine (MEA) solution. Henry’s law was used for modeling the vapour phase equilibrium of the CO2, and fugacity ratios calculated by the Peng Robinson equation of state (EOS) were used for H2O, MEA, N2 and O2. Chemical reactions between CO2 and MEA were included in …


2009 Report Of Crerg Research Activities, João F. Gomes Dec 2009

2009 Report Of Crerg Research Activities, João F. Gomes

João F Gomes

No abstract provided.


Toxicological Assessment Of Coated Versus Uncoated Rubber Granulates Obtained From Used Tires For Use In Sport Facilities, João F. Gomes Dec 2009

Toxicological Assessment Of Coated Versus Uncoated Rubber Granulates Obtained From Used Tires For Use In Sport Facilities, João F. Gomes

João F Gomes

Reuse of tire crumb in sport facilities is currently a very cost-effective waste management measure. Considering that incorporation of the waste materials in artificial turf would be facilitated if the rubber materials were already colored green, coatings were specifically developed for this purpose. This paper presents an experimental toxicological and environmental assessment aimed at comparing the obtained emissions to the environment in terms of polycyclic aromatic hydrocarbons (PAHs), heavy metals, and ecotoxicity for coated and noncoated rubber granulates. This study is a comprehensive evaluation of the major potential critical factors related with the release of all of these classes of …