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Theses/Dissertations

Nanoparticle

Analytical Chemistry

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Full-Text Articles in Nanoscience and Nanotechnology

Rod-Like Plasmonic Nanoparticles As Optical Building Blocks: How Differences In Particle Shape And Structural Geometry Influence Optical Signal, Anthony Shawn Stender Jan 2013

Rod-Like Plasmonic Nanoparticles As Optical Building Blocks: How Differences In Particle Shape And Structural Geometry Influence Optical Signal, Anthony Shawn Stender

Graduate Theses and Dissertations

Gold nanoparticles, particularly those with an anisotropic shape, have become a popular optical probe for experiments involving work on the nanoscale. However, to carry out such delicate and intricate experiments, it is first necessary to understand the detailed behavior of individual nanoparticles. In this series of experiments, optical and electron microscopy were utilized for the characterization of individual nanoparticles and small assemblies of nanoparticles.

In the first experiment, gold nanorods were investigated. Single, isolated nanorods exhibit two maxima of localized surface plasmon resonance (LSPR), which are associated with the two nanorod axes. Upon the physical rotation of a nanorod at ...