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Western University

Graphene

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Full-Text Articles in Nanoscience and Nanotechnology

Quantification Of Flows Emerging From Small Pores In Plane Walls, Matia Peter Edwards Nov 2022

Quantification Of Flows Emerging From Small Pores In Plane Walls, Matia Peter Edwards

Electronic Thesis and Dissertation Repository

Current membrane separation processes are limited in high production and high purity settings due to a trade-off between selectivity and permeance. Methods of creating nanoscale geometries in 2D materials are emerging and present an opportunity for fast, size selective mass transport that can be tailored to a wide array of applications. This thesis develops a method for quantifying flow through small pores in plane walls based on the behaviour of a solute dispersed in a downstream reservoir. This method is validated for a range of micropore diameters, for which flow rates can be calculated with confidence, and is shown to …


Synthesis And Drop-On-Demand Deposition Of Graphene Derivative Inks For Flexible Thin Film Electronics, Dogan M. Sinar Aug 2018

Synthesis And Drop-On-Demand Deposition Of Graphene Derivative Inks For Flexible Thin Film Electronics, Dogan M. Sinar

Electronic Thesis and Dissertation Repository

This dissertation presents methods for deposition and post-processing of Graphene-Carboxymethyl Cellulose (G-CMC) and Graphene Oxide (GO) aqueous functional inks using a custom drop-on-demand (DOD) printer to fabricate mechanically flexible, non-transparent and transparent thin film electronic devices. Thin films on flexible substrates find use in lightweight, low profile, and conformable electronic devices. Such devices can include chemical sensors, flexible RFID tags, bioelectronics circuits, lightweight electronics for space systems, and transparent electrodes for optoelectronic systems. The goal of this research project is to provide simple methods for fabrication of these devices using environmentally friendly and easy to synthesize functional inks. Therefore, two …


Nanostructured Tin-Based Anodes For Lithium Ion Batteries With X-Ray Absorption Fine Structure Studies, Dongniu Wang Sep 2013

Nanostructured Tin-Based Anodes For Lithium Ion Batteries With X-Ray Absorption Fine Structure Studies, Dongniu Wang

Electronic Thesis and Dissertation Repository

The practical applications of lithium ion batteries are highly dependent on the choice of electrodes, where boosting the materials innovations to design and achieve high capacity, excellent cycling performance, rate capability, low-cost and safe electrode materials provide the best solution. Based on this, tin-based anodes have gained great attention due to its high theoretical capacity, low cost and nontoxic nature to environment. Nevertheless, it undergoes significant volume variation(259%)during the operation of the battery, leading to pulverization and significant capacity fade. Thus, the practical application of tin-based anodes is still quite challenging. This thesis tackles issues related to tin-based anodes. It …


Development Of Nanostructured Limpo4 (M=Fe, Mn) As Cathodes For High Performance Lithium-Ion Batteries, Jinli Yang Sep 2013

Development Of Nanostructured Limpo4 (M=Fe, Mn) As Cathodes For High Performance Lithium-Ion Batteries, Jinli Yang

Electronic Thesis and Dissertation Repository

Olivine LiFePO4 has garnered the most interest because of its environmental benignity, high safety and theoretical capacity. However, the major limitation for LiFePO4 is the intrinsically poor electronic conductivity and ionic conductivity. The sluggish kinetics for LiFePO4 could be overcome by reducing the size, coating with conductive carbon, or doping with isovalent ions. The decrease of the size to nanoscale could shorten the diffusion time of Li ions in LiFePO4 during intercalation/deintercalation process, but the nano-size active material usually accompanies with low tap density. Carbon coating and carbon addition could alleviate the poor electronic conductivity. However, …