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SelectedWorks

2011

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Articles 1 - 11 of 11

Full-Text Articles in Nanoscience and Nanotechnology

Study On The Use Of Mgal Hydrotalcites As Solid Heterogeneous Catalysts For Biodiesel Production, João F. Gomes Dec 2011

Study On The Use Of Mgal Hydrotalcites As Solid Heterogeneous Catalysts For Biodiesel Production, João F. Gomes

João F Gomes

This paper, reports experimental work on the use of new heterogeneous solid basic catalysts for biodiesel production: double oxides of Mg and Al, produced by calcination, at high temperature, of MgAl lamellar structures, the hydrotalcites (HT). The most suitable catalyst system studied are hydrotalcite Mg:Al 2:1 calcinated at 507 ºC and 700 ºC, leading to higher values of FAME also in the second reaction stage. One of the prepared catalysts resulted in 97.1 % Fatty acids methyl esters (FAME) in the 1st reaction step, 92.2 % FAME in the 2nd reaction step and 34 % FAME in the 3rd reaction …


A Review Of International Best Practice In E-Governmentsome Lessons For New Adopters, Deogratias Harorimana Sr Oct 2011

A Review Of International Best Practice In E-Governmentsome Lessons For New Adopters, Deogratias Harorimana Sr

Dr Deogratias Harorimana

Efficient bureaucratic processes as essential to attract and retain investment, as well as promote SME growth. The e_Gov is one of many ways emerging economies have used to streamline public service delivery and create a freindly and conducive atmosphere for business -both MNC and SMEs. This presentation provide an overview of some of the World's most recent case examples on the successful design-plan-implementation of eGov to build a strong basis to attract investment and deliver seamless essential services to Citizens.


A Critical Review Of The Effectiveness Of Fiscal And Monetary Policies In The Pacific Island Countries (Pics) Between 1990-2010, Deogratias Harorimana Mr Oct 2011

A Critical Review Of The Effectiveness Of Fiscal And Monetary Policies In The Pacific Island Countries (Pics) Between 1990-2010, Deogratias Harorimana Mr

Dr Deogratias Harorimana

The purpose of this paper is to critically assess the effectiveness of Fiscal and Monetary Policies in the South Pacific Island Countries. The paper tracks down the economic growth for the last 20 years between 1990-2010, and drawing from key fiscal and monetary policies in place during the time under consideration, as well as specific interventions in the region, we find that: 1) While the South Pacific Island Countries (SPICs) particularly the six major economies (Solomon Islands, Fiji, Vanuatu, PNG, Samoa, Tonga) pursued fiscal and monetary policies for promoting growth and diversification of their economies, their fiscal policies relied heavily …


Notice On A Case Study On The Utilization Of Wind Energy Potential On A Remote And Isolated Small Wastewater Treatment Plant, João F. Gomes Aug 2011

Notice On A Case Study On The Utilization Of Wind Energy Potential On A Remote And Isolated Small Wastewater Treatment Plant, João F. Gomes

João F Gomes

Small wastewater treatment plants (WWTP) are frequently located, by necessity, in remote and isolated sites, which increases the difficulty of its energy supply. Some of them are located near the seaside, in environmental sensible zones, and due to tourism activity of these sites, seasonal effects related with population size fluctuation can occur, which can originate certain inefficiencies concerning WWTP design and energy supply. The objective of this paper is to describe a step by step procedure for evaluation of the wind potential of sites that are dependent of in-situ energy generation, as well as, a case study on the utilization …


Carboxymethylation Of Kappa-Carrageenan For Intestinal-Targeted Delivery Of Bioactive Macromolecules, Kok Hoong Leong Feb 2011

Carboxymethylation Of Kappa-Carrageenan For Intestinal-Targeted Delivery Of Bioactive Macromolecules, Kok Hoong Leong

Kok Hoong Leong

The work presented herein discusses the carboxymethylation of kappa-carrageenan, a natural linear polysaccharide, to afford a pH-dependent swelling property allowing for intestinal-targeted delivery of bioactive macromolecules. The carboxymethylation conditions with respect to the volume and concentration of sodium hydroxide (VNaOH, CNaOH), weight of monochloroacetic acid (WMCA), and reaction temperature (T) were optimized using a response surface method incorporating a multivariate spline interpolation technique (RSMS). Fluorescein isothiocyanate-labeled dextran (FD-4; 4.4 kDa) was used as a hydrophilic macromolecule model. Beads made from encapsulating FD-4 in the carboxymethylated kappa-carrageenan displayed pH-dependent swelling and encapsulation efficiency of 74%. The release of FD-4 was low …


Study On The Glycerolysis Reaction Of High Free Fatty Acid Oils For Use As Biodiesel Feedstock, João F. Gomes Jan 2011

Study On The Glycerolysis Reaction Of High Free Fatty Acid Oils For Use As Biodiesel Feedstock, João F. Gomes

João F Gomes

Biodiesel is the main alternative to fossil diesel and it may be produced from different feedstocks such as semi-refined vegetable oils, waste frying oils or animal fats. However, these feedstocks usually contain significant amounts of free fatty acids (FFA) that make them inadequate for the direct base catalyzed transesterification reaction (where the FFA content should be lower than 4%). The present work describes a possible method for the pre-treatment of oils with high content of FFA (20 to 50%) by esterification with glycerol. In order to reduce the FFA content, the reaction between these FFA and an esterification agent is …


Design Of A New Test Chamber For Evaluation Of The Toxicity Of Rubber Infill, João F. Gomes Jan 2011

Design Of A New Test Chamber For Evaluation Of The Toxicity Of Rubber Infill, João F. Gomes

João F Gomes

A test chamber was projected and built (according to ISO 16000-9 Standard) to simulate atmospheric conditions experienced by rubber infill (when applied in synthetic turf pitches) and measure accurately the airborne emissions of pollutants such as dusts and volatile organic compounds (VOC), as well as pollutants present in leacheates. It should be pointed out that standard ISO 16000-9 is only concerned with the determination of the emission of VOC from building products and furnishing (not specific of synthetic turf materials), while other standards are concerned with the emission of leacheates only. This procedure is to be considered as a technical …


What Is A Chemical Engineer ?, João F. Gomes Jan 2011

What Is A Chemical Engineer ?, João F. Gomes

João F Gomes

No abstract provided.


On The Toxicological Effects Of Airborne Nanoparticles From Welding Processes, João F. Gomes Jan 2011

On The Toxicological Effects Of Airborne Nanoparticles From Welding Processes, João F. Gomes

João F Gomes

No abstract provided.


Nanosized Molecular Sieves Utilized As An Environmentally Friendly Alternative To Antioxidants For Lubricant Oils, Eng-Poh Ng Dr. Jan 2011

Nanosized Molecular Sieves Utilized As An Environmentally Friendly Alternative To Antioxidants For Lubricant Oils, Eng-Poh Ng Dr.

Eng-Poh Ng

Lubricants play a significant part in current environmental considerations since they are an integral and indispensable component of modern technology. The production, application and disposal of the lubricants have to follow increasingly strict requirements for protecting the environment and living organisms. In this respect, molecular sieve (LTL type zeolite) is investigated as a potential environmentally friendly alternative to traditional antioxidant additives for lubricant oils. Accelerated oxidation experiments using pure base oil and additivated base oil in the presence of the LTL molecular sieve are carried out in parallel, and the oxidation processes are monitored by FT-IR spectroscopy, spectrophotometry, chromatography, total …


Locating/Understanding The “Technology” In Nanotechnology - Insights From Case Studies In Applying Lean Principles To Nanotechnology, Shweta Chopra, Chad M. Laux Jan 2011

Locating/Understanding The “Technology” In Nanotechnology - Insights From Case Studies In Applying Lean Principles To Nanotechnology, Shweta Chopra, Chad M. Laux

Shweta Chopra

Nanotechnology is a generic term referring diverse research contexts, technologies and application domains. We present two case studies illustrating the diversity of research as well as the technological issues associated with scaling pilot/lab based operations to industrial/commercial levels. We demonstrate the utility of lean principles such as the Six-Sigma methodology in addressing technological issues pertaining to diverse Nanotechnology related contexts by discussing the applicability of lean principles to the two cases discussed.