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Full-Text Articles in Nanoscience and Nanotechnology
Local And Segmental Motions Of The Mobile Amorphous Fraction In Semi-Crystalline Polylactide Crystallized Under Quiescent And Flow-Induced Conditions, Xavier Monnier, Laurence Chevalier, Antonello Esposito, Lucia Fernandez-Ballester, Allisson Saiter, Eric Dargent
Local And Segmental Motions Of The Mobile Amorphous Fraction In Semi-Crystalline Polylactide Crystallized Under Quiescent And Flow-Induced Conditions, Xavier Monnier, Laurence Chevalier, Antonello Esposito, Lucia Fernandez-Ballester, Allisson Saiter, Eric Dargent
Department of Mechanical and Materials Engineering: Faculty Publications
The molecular dynamics of the constrained and unconstrained mobile amorphous fractions in semicrystalline polylactide (PLA) was investigated in the presence of both flow-induced crystalline structures and spherulites by fast scanning calorimetry (FSC) through cooperativity and physical aging concepts. First, the shear rate conditions leading to flow-induced crystallization were characterized by examining the relaxation of shear-induced precursors. At a temperature of 150 °C, the critical relaxation time is so long that cooling down the sheared melt to the crystallization temperature does not affect significantly the precursors. Therefore, highly oriented structures develop. The arrangement of the crystalline fraction, either in flow-induced crystalline …