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Iowa State University

Analytical Chemistry

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Reduction Of Polyatomic Ion Interferences In Inductively Coupled Plasma Mass Spectrometry With Cryogenic Desolvation , Luís Cláudio Alves Jan 1993

Reduction Of Polyatomic Ion Interferences In Inductively Coupled Plasma Mass Spectrometry With Cryogenic Desolvation , Luís Cláudio Alves

Retrospective Theses and Dissertations

A new desolvation scheme for the introduction of aqueous and organic samples into an argon inductively coupled plasma (ICP) is described. The aerosol generated by the nebulizer is heated (+140°C) and cooled (-80°C) repeatedly. The dried aerosol is then injected into an inductively coupled plasma mass spectrometer (ICP-MS);The metal oxide count rate ratios (MO[superscript]+/M[superscript]+) were drastically reduced to ≤ 0.05% for all the elements tested with the exception of the UO[superscript]+/U[superscript]+ ratio which was reduced to 0.1%. However, the addition of ~2% of acetylene or H[subscript]2 to the ...