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In Situ Synthesis Of Ultrafine Ss-Mno2/Polypyrrole Nanorod Composites For High-Performance Supercapacitors, Jianfeng Zang, Xiaodong Li

Xiaodong Li

We report a remarkable observation that is at odds with the established notion that β-MnO2 was regarded as an undesirable candidate for supercapacitor applications. The specific capacitance of β-MnO2 can reach as high as 294 F g−1, which is comparable to the best crystallographic structure, like α-MnO2. The key is to substantially decrease the size of β-MnO2 powders to ultra small regime. We demonstrate a facile, simple, and effective approach to synthesizing ultrafine (<10 nm in diameter) β-MnO2/polypyrrole nanorod composite powders for high-performance supercapacitor electrodes. Our observation may encourage a revisit of the other good or even bad candidate …