Mechanical Engineering Commons^™

Thermomechanical Properties Of Novel Lanthanum Zirconate Based Thermal Barrier Coatings - An Integrated Experimental And Modeling Study, Xingye Guo

Open Access Dissertations

Thermal barrier coatings (TBCs) are refractory materials deposited on gas turbine components, which provide thermal protection for metallic components at operating conditions. The current state-of-art TBC material is yttria-stabilized zirconia (YSZ), whose service temperature is limited to 1200 celsius, due to sintering and phase transition at higher temperatures. In comparison, lanthanum zirconate (La2Zr2O7, LZ) has become a promising candidate material for TBCs due to its lower thermal conductivity and higher phase stability compared to YSZ.

The primary objective of this thesis is to design a novel robust LZ-based TBC system suitable for applications beyond 1200 celsius. Due to LZ’s low …

Evaluating The Performance Of Passive Chilled Beams With Respect To Energy Efficiency And Thermal Comfort, Janghyun Kim

Open Access Dissertations

Existing modeling approaches for passive chilled beams determined from tests on individual chilled beams in a laboratory are not adequate for assessing overall energy usage and occupant comfort within building simulation programs. In addition, design guidelines for passive chilled beam systems are needed for identifying appropriate applications and optimal configurations. This thesis includes (i) extensive experimental studies for characterizing the performance of passive chilled beams, in both laboratory settings and in field studies, (ii) development of passive chilled beam performance prediction models, (iii) integration of these models into building simulation models/tools and (iv) use of building simulation for overall assessment …

Modifying Burning Rate And Agglomeration Size In Aluminized Composite Solid Propellants Using Mechanically Activated Metals, Hatem Mohamed Belal

Open Access Dissertations

Agglomeration reduction techniques are important field in solid propellant industry, Large agglomeration results in excessive two phase losses. Tailored composite particles has been applied to tailor aluminum particle ignition and combustion. In this research, mechanical activated aluminum magnesium powders are synthesized, tested in both laser ignition using CO2 and propellant. Prepared powders categorized into particle size that suitable for propellant application. Laser ignition tests showed that the prepared powder are more reactive than magnalium which has the same Al:Mg weight ratio. Agglomeration capturing showed that the prepared powder produce much less than neat aluminum or even similar physical mixture of …

Hydrodynamics Of Swimming Microorganisms In Complex Fluids, Gaojin Li

Open Access Dissertations

Swimming motion of microorganisms, such as spermatozoa, plankton, algae and bacteria, etc., ubiquitously occurs in nature. It affects many biological processes, including reproduction, infection and the marine life ecosystem. The hydrodynamic effects are important in microorganism swimming, their nutrient uptake, fertilization, collective motions and formation of colonies. In nature, microorganisms have evolved to use various fascinating ways for locomotion and transport. Different designs are also developed for the locomotion of artificial nano- and microswimmers. In this study, we use several different computational models to investigate the behavior of microswimmers.

Microorganisms typically swim in the low Reynolds number regime, where inertia …

Experimentally Validated 3d Md Model For Afm-Based Tip-Based Nanomanufacturing, Rapeepan Promyoo

Open Access Dissertations

In order to control AFM-based TBN to produce precise nano-geometry efficiently, there is a need to conduct a more focused study of the effects of different parameters, such as feed, speed, and depth of cut on the process performance and outcome. This is achieved by experimentally validating a MD simulation model of nanomachining, and using it to conduct parametric studies to guide AFM-based TBN. A 3D MD model with a larger domain size was developed and used to gain a unique insight into the nanoindentation and nanoscratching processes such as the effect of tip speed (e.g. effect of tip speed …

Fracture Analysis In Biomimetic Bouligand Architectures, Nobphadon Suksanqpanya

Open Access Dissertations

The Bouligand structure, which is found in many biological materials, is a hierarchical architecture that features uniaxial fiber layers assembled periodically into a helicoidal pattern. Many studies have highlighted the high damage-resistant performance of Bouligand structures and its biomimetic materials. One of the outstanding species with the Bouligand structures is the smashing Mantis Shrimp, Odontodactylus Scyllarus, (or stomatopod) due to its capability of generating high speed, high acceleration blows using its raptorial appendage to defeat highly armored preys. The load-bearing part of this appendage, the dactyl club, contains an interior region, which is mainly characterized by the Bouligand structure. This …

Fundamental Studies Of Flame Propagation In Lean-Burn Natural Gas Engines, Zhiyan Wang

Open Access Dissertations

Lean-burn natural gas engines offer enhanced thermal efficiencies and reduced soot and NOx emissions. However, cycle-to-cycle variability in combustion that can result from unreliable ignition, variability in equivalence ratio and quenching is a challenge. Reliability of ignition can be improved by employing a dual-fuel ignition strategy in which a small quantity of diesel fuel is injected to initiate ignition. Computational studies of n-heptane/methane-air mixing layers are performed to provide insight into the fundamental physics of dual-fuel ignition. The results show that the characteristic time required for steady premixed flame propagation has three components: time for autoignition to occur, time for …

Size Scaling Of Strength And Toughness For 3d Printed Polymer Specimens, Darren Thomas Bell

Open Access Theses

To find material systems that offer low density and high strength, stiffness or toughness, hierarchically designed material systems have provided a promising research area. This thesis lays the groundwork for designing efficient micro-architectured material systems by characterizing size effects for 3d printed polymer parts. Two methods were used to analyze data from 3-point bend tests for specimens of varying size: the load-separation method was used for finding the point of crack growth initiation and Bazant’s method was used to find shape independent strength at failure. The strength values were used as inputs for finding size independent material constants within a …

Thermal Transport In Lithium Ion Batteries: An Experimental Investigation Of Interfaces And Granular Materials, Aalok Jaisheela Uday Gaitonde

Open Access Theses

Increasing usage and recent accidents due to lithium-ion (Li-ion) batteries exploding or catching on fire has inspired research on the characterization and thermal management of these batteries. In cylindrical 18650 cells, heat generated during the battery's charge/discharge cycle is poorly dissipated to the surrounding through its metallic case due to the poor thermal conductivity of the jelly roll, which is spirally wound with many interfaces between electrodes and the polymeric separator. This work presents a technique to measure the thermal conduction across the metallic case-plastic separator interface, which ultimately limits heat transfer out of the jelly roll.

The polymeric separator …

Reaction Tuning Of Selectively Deposited Nano-Thermite Inks For Thrust And Heat Deposition, Raghav Ramachandran

Open Access Theses

Currently there is very little systematic work that quantifies the performance of energetic materials in terms of thrust or heat deposition applied to electronic circuits. A better understanding of the interactions between nano-scale energetic materials and electronic systems, as a function of stoichiometry is needed for enhanced defeat. Both of these needs are addressed in this research. Formulations of Al-CuO and Al-Bi2O3 nano-thermites were prepared at different equivalence ratios and selectively deposited onto silicon substrates and thrust and heat deposition of these materials was quantified. Both nano-thermite systems produced maximum thrust near stoichiometric ratios, and more fuel-rich mixtures led to …

Free Edge Stress Analysis Of Laminated Structures With Arbitrary Cross Sections Using Mechanics Of Structure Genome, Lingxuan Zhou

Open Access Theses

Composite laminates have been increasingly used in advanced structural applications, due to their excellent strength-to-weight properties and considerable flexibility on designing with respect to the laminate layup. However, the heterogeneity and anisotropy of composite laminates have brought many challenges for analysis and numerous researches have been devoted in this field. A well known problem which has been studied intensively is the so-called free-edge problem. It states that due to the mismatch in elastic properties of adjacent layers, full-scale three-dimensional (3D) and highly concentrated stress fields will occur in the vicinity of the free edges. The interlaminar stresses grow very rapidly …

Analysis Of Composite Plates By Using Mechanics Of Structure Genome And Comparison With Ansys, Banghua Zhao

Open Access Theses

Motivated by a recently discovered concept, Structure Genome (SG) which is defined as the smallest mathematical building block of a structure, a new approach named Mechanics of Structure Genome (MSG) to model and analyze composite plates is introduced. MSG is implemented in a general-purpose code named SwiftComp™, which provides the constitutive models needed in structural analysis by homogenization and pointwise local fields by dehomogenization. To improve the user friendliness of SwiftComp™, a simple graphic user interface (GUI) based on ANSYS Mechanical APDL platform, called ANSYS-SwiftComp GUI is developed, which provides a convenient way to create some common SG models or …

Carbon Nanotube Thermal Interfaces And Related Applications, Stephen L. Hodson

Open Access Dissertations

The development of thermal interface materials (TIMs) is necessitated by the temperature drop across interfacing materials arising from macro and microscopic irregularities of their surfaces that constricts heat through small contact regions as well as mismatches in their thermal properties. Similar to other types of TIMs, CNT TIMs alleviate the thermal resistance across the interface by thermally bridging two materials together with cylindrical, high-aspect ratio, and nominally vertical conducting elements. Within the community of TIM engineers, the vision driving the development of CNT TIMs was born from measurements that revealed impressively high thermal conductivities of individual CNTs. This vision was …

Concurrent Detection And Isolation Of Cellular And Molecular Biomarkers, Wanfeng Huang

Open Access Dissertations

Detection of cancer markers such as protein biomolecules and cancer cells in bodily fluids is of great importance in early diagnosis, prognosis as well as evaluation of therapy efficacy. Numerous devices have been developed for detecting either cellular or molecular targets, however there has not yet been a system that can simultaneously detect both cellular and molecular targets effectively. Molecule and cell-based assays are important because each type of target can tell a different story about the state of the disease and the two types of information can potentially be combined and/or compared for more accurate biological or clinical assessments. …

A Method For Selecting Hvac Retrofit Solutions For Existing Small- And Medium-Sized Commercial Buildings, Bonggil Jeon

Open Access Dissertations

The primary purpose of the present study is to develop a framework and methodology for evaluating appropriate Heating, Ventilating, and Air Conditioning (HVAC) retrofit solutions that can be effectively retrofitted into different types of small- and medium-sized commercial buildings (SMSCB). Additionally, development of an advanced data-driven decision-making tool is introduced as a benefit of proposed framework. In recent years, considerable attention has been focused on retrofits of existing commercial buildings (IBE, 2013b). In fact, the Commercial Building Energy Consumption Survey (CBECS) 2003 (EIA, 2006) indicates that over 70% of existing commercial buildings across the United States are more than twenty …

Optimal Design Of Sound Absorbing Systems With Microperforated Panels, Nicholas Nakjoo Kim

Open Access Dissertations

As the development of technology makes economic prosperity and life more convenient, people now desire a higher quality of life. This quality of life is based not only on the convenience in their life but also on clean and eco-friendly environments. To meet that requirement, much research is being performed in many areas of eco-friendly technology, such as renewable energy, biodegradable content, and batteries for electronic vehicles.

This tendency is also obvious in the acoustics area, where there are continuing attempts to replace fiber-glass sound absorbers with fiber-free materials. The combination of microperfoated panels (MPP) (one of the fiber-free sound …

Energy Localization And Heat Generation In Composite Energetic Systems Under High-Frequency Mechanical Excitation, Jesus O. Mares

Open Access Dissertations

In this work, the ability to use high frequency mechanical excitation to generate significant heating within plastic bonded explosives, as well as single energetic particles embedded within a viscoelastic binder, is studied. In this work, the fundamental mechanisms associated with the conversion of high-frequency mechanical excitation to heat as applied to these composite energetic systems are thoroughly investigated.

High-frequency contact excitation has been used to generate a significant amount of heat within samples of PBX 9501 and representative inert mock materials. Surface temperature rises on the order of 10 °C were observed at certain frequencies over a range from 50 …

A Sharp Interface Isogeometric Strategy For Moving Boundary Problems, Tao Song

Open Access Dissertations

The proposed methodology is first utilized to model stationary and propagating cracks. The crack face is enriched with the Heaviside function which captures the displacement discontinuity. Meanwhile, the crack tips are enriched with asymptotic displacement functions to reproduce the tip singularity. The enriching degrees of freedom associated with the crack tips are chosen as stress intensity factors (SIFs) such that these quantities can be directly extracted from the solution without a-posteriori integral calculation.

As a second application, the Stefan problem is modeled with a hybrid function/derivative enriched interface. Since the interface geometry is explicitly defined, normals and curvatures can be …

Optical Sub-Diffraction Limited Focusing For Confined Heating And Lithography, Luis M. Traverso

Open Access Dissertations

Electronics and nanotechnology is constantly demanding a decrease in size of fabricated nanoscale features. This decrease in size has become much more difficult recently due to the limited resolution of optical systems that are fundamental to many nanofabrication methods. A lot of effort has been made to fabricate devices smaller than the diffraction limit of light. Creating devices that are capable of confining fields by means of interference patterns of propagating wave modes and surface plasmon, has proven successful to confine light into smaller spot sizes.

Zone plate diffraction lenses generate spots with dimensions very close to the diffraction limit. …

On The Use Of Mechanical And Acoustical Excitations For Selective Heat Generation In Polymer-Bonded Energetic Materials, Daniel C. Woods

Open Access Dissertations

To address security issues in both military and civilian settings, there is a pressing need for improved explosives detection technologies suitable for trace vapor detection. In light of the strong dependence of vapor pressure on temperature, trace vapor detection capabilities may be enhanced by selectively heating target materials by external excitation. Moreover, polymer-bonded energetic materials may be particularly susceptible to heating by mechanical or acoustical excitation, due to the high levels of damping and low thermal conductivities of most polymers. In this work, the thermomechanical response of polymer-based energetic composites and methods for acoustical excitation are investigated in order to …

Photoelectrochemical And Photophysical Studies Of Carbon Nanotube And Molybdenum Disulfide Based Light Harvesting Devices, Hanyu Zhang

Open Access Dissertations

There is a critical need in utilizing solar radiation as a renewable energy source. While photovoltaic solar cells are widely used, much attention has been devoted in the past decade to developing nanotechnology for potential cost reduction and improved device efficiency and reliability. Low-dimensional materials offer unique physical properties which may be exploited for solar energy harvesting and conversion. Understanding their fundamental properties and developing relevant manufacturing strategies will thus pave the road toward high-performance, cost-effective, light-harvesting devices.

This thesis has investigated single-wall carbon nanotubes (SWCNTs) and molybdenum disulfide (MoS2) nanolayers for their light-harvesting ability in donor-acceptor systems. These materials …

An Investigation Of Composite Failure Analyses And Damage Evolution In Finite Element Models, Ann M. Frappier

Open Access Theses

This paper presents a composite conical structure used commonly in flight-qualification testing. This structure’s overall load-displacement behavioral response is characterized. Mixed-mode multidelamination in a layered composite specimen is considered in Abaqus/Explicit through both the Virtual Crack Closure Technique and Cohesive Elements. The Virtual Crack Closure Technique and Cohesive Elements are compared against experimental test results presented in literature. Further, a thorough comparison in which the effects of failure criteria type, through-thickness mesh density, and finite element type on the progressive failure response of this composite assembly is discussed. Lastly, Abaqus/Standard and Helius PFA are compared in order to gain confidence …

Passive Thermal Management Using Phase Change Materials, Yash Yogesh Ganatra

Open Access Theses

The trend of enhanced functionality and reducing thickness of mobile devices has led to a rapid increase in power density and a potential thermal bottleneck since thermal limits of components remain unchanged. Active cooling mechanisms are not feasible due to size, weight and cost constraints. This work explores the feasibility of a passive cooling system based on Phase Change Materials (PCMs) for thermal management of mobile devices. PCMs stabilize temperatures due to the latent heat of phase change thus increasing the operating time of the device before threshold temperatures are exceeded. The primary contribution of this work is the identification …

Liquid Metal Particle Popping: Nanoscale To Macroscale, Trevor R. Lear

Open Access Theses

Liquid metal nanoparticles can be used to produce stretchable electronic devices. Understanding the mechanical properties of liquid metal nanoparticles is crucial to optimizing their use in various applications, especially printing of flexible, stretchable electronics. Smaller nanoparticles are desired for high-resolution printing and compatibility with existing scalable manufacturing methods; however, they contain less liquid metal and are more difficult to rupture than larger particles, making them less desirable for post-processing functionality. This study investigates the mechanics of liquid metal particle rupture as a function of particle size. We employ compression of particle films to characterize the composition of the particle core …

In-Situ Particle Sizing Of Agglomerates In Aluminized Solid Composite Propellants Using Digital Inline Holography (Dih), Michael S. Powell

Open Access Theses

Aluminized ammonium perchlorate composite propellants (APCP) form large molten agglomerated particles that can result in poor combustion performance and increased two-phase flow losses. Quantifying agglomerate size distributions is important for assessing these losses for different types of aluminum fuels that can help improve rocket performance. It is highly desirable to measure particle sizes in-situ using non-intrusive optical methods, rather than conventional particle collection, which can have large uncertainties. Regular high-speed microscopic imaging suffers from a limited depth of field. Digital inline holography (DIH) is an alternative approach that results in 3D information through numerical reconstruction. In this paper, DIH approach …

Multivariate Calibration Of A Load Sensor For Dynamic And Static Freight Railcar Applications, Dylan Michael Blackwell

Theses and Dissertations

Determination of the load carried by each bearing in a railcar system is crucial to the integrity of the railroad industry. With accurate load measurement, the process of filling a railcar with its specified cargo can be optimized to provide the maximum amount of cargo without exceeding the upper weight limits imposed by the Associations of American Railroads (AAR). An accurate load measurement will additionally make it possible to identify any load imbalance that occurs during periods of travel which result in having a detrimental effect on the health of the bearing. Previous work conducted with a strain-gauge load sensor …

Forcespinning®: An Alternative Method To Fabricate Metal Oxide/Carbon Composite Nanofiber Anodes For Li-Ion Batteries, Luis Zuniga

Theses and Dissertations

Metals and their respective oxides have been highly regarded as next generation anode materials for lithium-ion batteries (LIBs). In this research work the electrochemical performance of Sn, SnO2, and TiO2. With the advantages of nanotechnology and the Forcespinning® method of fabricating micro and nanofibers, binder-free anodes are produced from metal or metal oxide/carbon composite microfibers. Through these microfibers the electrochemical performance of the above mentioned materials are significantly improved due to the increased surface area per volume providing a large number of reaction sites for the anode materials. Further performance enhancement was achieved by also modifying the fiber microstructure to …

Optimizing Border Security With Stochastic And Deterministic Strategies, Gabriel A. Rueda

Theses and Dissertations

International trade and border security have always been linked together, and so has the need to find ways to improve security decisions. The United States and bordering countries benefit from the North American Free Trade Agreement (NAFTA), but amongst the positive effects of NAFTA there is a looming drug threat that effects the bi-national supply chains. In 2015 Customs and Border Protections (CBP) processed over 72,000 trucks, rail, and sea containers a day. CBP also seized 3.4 million pounds of narcotics, the majority of them at the ports of entry. With unknown threats using commercial vehicles to transport their illicit …

Wettability Of Nonwoven Polymeric Nanofiber Mats, Edgar Munoz

Theses and Dissertations

The wettability of heterogeneous materials has been attracting special interest by academia and industrial sector given the need to development self-cleaning Nonwoven nanofiber mats have demonstrated potential given its hydrophobicity granted by the ultimate structure of the system, small fiber diameter and small pores giving rise to effects such as the Cassie-Baxter. This thesis analyzed the wettability of a wide range of polymeric systems. Nanofiber mats were manufactured using the Forcespinning® technology. Samples were prepared at different polymeric concentrations and rotational speeds to alter fiber size; density of the mat was also altered to evaluate the effect of porosity on …

Knee Joint Internal Forces During Squat Jump Exercise, Ricardo Moreno

Theses and Dissertations

The purpose of this research is to investigate muscular ligament and joint contact forces produced during squat jump exercise. An inverse dynamics, two dimensional, leg model is used to describe the motion in the sagittal plane. The lower extremity model includes two bones, tibia and femur, tibio-femoral ligaments, and muscles such as quadriceps, hamstrings, and gastrocnemius. The ligaments are anatomically modeled as nonlinear strings, but the femoral condyle is modeled as a circle and the tibial plateau as a straight line. Experimental squat jump exercises are conducted to obtain the ground reaction forces, the angular accelerations, and centroid linear acceleration …