Mechanical Engineering Commons^™

Aerosol-Assisted Synthesis Of Monodisperse Single-Crystalline Α-Cristobalite Nanospheres, Xingmao Jiang, Lihong Bao, Yung-Sung Cheng, Darren R. Dunphy, Xiaodong Li, C. Jeffrey Brinker

Faculty Publications

Monodisperse single-crystalline α-cristobalite nanospheres have been synthesized by hydrocarbon-pyrolysis-induced carbon deposition on amorphous silica aerosol nanoparticles, devitrification of the coated silica at high temperature, and subsequent carbon removal by oxidation. The nanosphere size can be well controlled by tuning the size of the colloidal silica precursor. Uniform, high-purity nanocrystalline α-cristobalite is important for catalysis, nanocomposites, advanced polishing, and understanding silica nanotoxicology.

One-Step Infiltration Of Mixed Conducting Electrocatalysts For Reducing Cathode Polarization Of A Commercial Cathode-Supported Sofc, Nansheng Xu, Xue Li, Xuan Zhao, Hailei Zhao, Kevin Huang

Faculty Publications

Infiltrating fine-grained electrocatalyst particles of either ion conducting or mixed electron and ion conducting (MEIC) material into a ceramic porous electrode scaffold has proven a very effective way to improve electrode performance for low to intermediate temperature solid oxide fuel cells (SOFCs). We report here one-step infiltration of MEIC fine particles, La_0.6Sr_0.4CoO_3-δ (LSCo) and SrCo_0.8Fe_0.2O_3-δ (SCF), into a commercial cathode substrate. A comparative study shows that the cathode polarization can be considerably reduced by a factor of 17 to 28 and 28 to 49 from 1000 to 700 ³C by …

A Novel Solid Oxide Redox Flow Battery For Grid Energy Storage, Nansheng Xu, Xue Li, Xuan Zhao, John B. Goodenough, Kevin Huang

Faculty Publications

In this work we report proof-of-concept of a novel redox flow battery consisting of a solid oxide electrochemical cell (SOEC) integrated with a redox-cycle unit. The charge/discharge characteristics were explicitly observed by operating between fuel cell and electrolysis modes of the SOEC along with “in-battery” generation and storage of H₂ realized by an in situ closed-loop reversible steam-metal reaction in the redox-cycle unit. With Fe/FeO as the redox materials, the new storage battery can produce an energy capacity of 348 Wh/kg-Fe and round-trip efficiency of 91.5% over twenty stable charge/discharge cycles. This excellent performance combined with robustness, environmental friendliness …

Synthesis, Structural, Optical And Mechanical Characterization Of Srb2O4 Nanorods, Rui Li, Lihong Bao, Xiaodong Li

Faculty Publications

Single crystalline strontium borate (SrB₂O₄) nanorods were synthesized for the first time via a facile sol–gel route at low temperature. The SrB₂O₄ nanorods have a good crystalline nature with the growth direction along the [511] orientation and they are transparent from the ultraviolet to the visible regimes. Nanoscale three-point bending tests were performed directly on individual nanorods to probe their mechanical properties using an atomic force microscope. The elastic modulus of SrB₂O₄ nanorods was measured to be 158.2 ± 2.8 GPa, exhibiting a significant increase compared with other borate nanostructures …

Utilizing An Improved Rotorcraft Dynamic Model In State Estimation, Timothy Mclain, Randal W. Beard, Robert C. Leishman, John Macdonald, Jeffrey L. Ferrin, Stephen C. Quebe

Faculty Publications

Multirotor aircraft have become a popular platform for indoor flight. To navigate these vehicles indoors through an unknown environment requires the use of a SLAM algorithm, which can be processing intensive. However, their size, weight, and power capacity limit the processing capabilities available onboard. In this paper, we describe an approach to state estimation that helps to alleviate this problem. By using an improved dynamic model we show how to more accurately estimate the aircraft states than can be done with the traditional approach of integrating IMU measurements. The estimation is done with relatively infrequent corrections from accelerometers (40Hz) and …

Differential Flatness Based Control Of A Rotorcraft For Aggressive Maneuvers, Timothy Mclain, Randal W. Beard, Robert C. Leishman, Jeffrey L. Ferrin

Faculty Publications

We propose a new method to control a multi-rotor aerial vehicle. We show that the system dynamics are differentially flat. We utilize the differential flatness of the system to provide a feed forward input. The system model derived allows for arbitrary changes in yaw and is not limited to small roll and pitch angles. We demonstrate in hardware the ability to follow a highly maneuverable path while tracking a time-varying heading command.

In Situ Synthesis Of Ultrafine Ss-Mno2/Polypyrrole Nanorod Composites For High-Performance Supercapacitors, Jianfeng Zang, Xiaodong Li

Faculty Publications

We report a remarkable observation that is at odds with the established notion that β-MnO₂ was regarded as an undesirable candidate for supercapacitor applications. The specific capacitance of β-MnO₂ can reach as high as 294 F g⁻¹, which is comparable to the best crystallographic structure, like α-MnO₂. The key is to substantially decrease the size of β-MnO₂ powders to ultra small regime. We demonstrate a facile, simple, and effective approach to synthesizing ultrafine (<10 nm in diameter) β-MnO₂/polypyrrole nanorod composite powders for high-performance supercapacitor electrodes. Our observation may encourage a revisit of the other good …

Characteristics Of The Hydrogen Electrode In High Temperature Steam Electrolysis Process, Chao Jin, Chenghao Yang, Fanglin Chen

Faculty Publications

YSZ-electrolyte supported solid oxide electrolyzer cells (SOECs) using LSM-YSZ oxygen electrode but with three types of hydrogen electrode, Ni–SDC, Ni–YSZ and LSCM–YSZ have been fabricated and characterized under different steam contents in the feeding gas at 850°C. Electrochemical impedance spectra results show that cell resistances increase with the increase in steam concentrations under both open circuit voltage and electrolysis conditions, suggesting that electrolysis reaction becomes more difficult in high steam content. Pt reference electrode was applied to evaluate the contributions of the hydrogen electrode and oxygen electrode in the electrolysis process. Electrochemical impedance spectra and over potential of both electrodes …

A Generic Bamboo-Based Carbothermal Method For Preparing Carbide (Sic, B4C, Tic, Tac, Nbc, TiXNb1-XC, And TaX Nb1-XC) Nanowires, Xinyong Tao, Yiping Li, Jun Du, Yang Xia, Yingchao Yang, Hui Huang, Yongping Gan, Wenkui Zhang, Xiaodong Li

Faculty Publications

Finding a general procedure to produce a whole class of materials in a similar way is a desired goal of materials chemistry. In this work, we report a new bamboo-based carbothermal method to prepare nanowires of covalent carbides (SiC and B₄C) and interstitial carbides (TiC, TaC, NbC, Ti_xNb_1−xC, and Ta_xNb_1−xC). The use of natural nanoporous bamboo as both the renewable carbon source and the template for the formation of catalyst particles greatly simplifies the synthesis process. Based on the structural, morphological and elemental analysis, volatileoxides or halides assisted …

Compressibility Effects Of Extended Formation Flight, Andrew Ning, Ilan Kroo

Faculty Publications

Aircraft flown in formations may realize significant reductions in induced drag by flying in regions of wake upwash. However, most transports fly at transonic speeds and compressibility effects in formation flight are not well understood. This study uses an Euler solver to analyze the inviscid aerodynamic forces and moments of transonic wing/body configurations flying in a 2-aircraft formation. We consider formations with large streamwise separation distances (10-50 wingspans) in an arrangement we term extended formation flight. Compressibility-related drag penalties in formation flight may be eliminated by slowing 2-3% below the nominal out-of-formation drag divergence Mach number, at fixed lift coefficient …

Dynamics Of A Partially Fluid-Filled Sphere, Jeff Hendricks, Taylor W. Killian, Robert A. Klaus, Nick Smith, Tadd T. Truscott

Faculty Publications

We introduce a study on the slosh dynamics of a partially filled elastic sphere. Currently the physical design of fluid-filled containers utilizes clever construction and machinery to mitigate sloshing motions. There are numerous cases that have been observed but we focus on the impact of a sphere under free fall with an initially undisturbed free surface. The study focuses on measurement and simulation of the force distribution between the fluid and the sphere through the use of high-speed imaging and finite element analysis. Using the cavity shape data, a potential flow numerical model is developed that predicts the unsteady forces. …

Aerodynamic Performance Of Extended Formation Flight, Andrew Ning, Tristan Flanzer, Ilan Kroo

Faculty Publications

Close formation flight is of limited practicality for commercial aviation. Our concept of extended formation flight takes advantage of the persistence of cruise wakes by extending the streamwise spacing between aircraft in a formation. This allows the aircraft to fly at safe separation distances from each other, while still benefiting from the upwash of the upstream wake(s). In this paper we are interested in estimating the performance of these extended formations, and estimating some of the effects that limit the longitudinal extent of the formation. We consider the effects of wake rollup, vortex decay, vortex instabilities, vortex motion, and atmospheric …

Sr2Fe1.5Mo0.5O6 As Cathodes For Intermediate-Temperature Solid Oxide Fuel Cells With La0.8Sr0.2Ga0.87Mg0.13O3 Electrolyte, Guoliang Xiao, Qiang Liu, Fei Zhao, Lei Zhang, Changrong Xia, Fanglin Chen

Faculty Publications

The performance of Sr₂Fe_1.5Mo_0.5O₆ (SFMO) as a cathode material has been investigated in this study. The oxygen ionic conductivityof SFMO reaches 0.13 S cm^-1 at 800°C in air. The chemical diffusion coefficient (D_chem) and surface exchange constant (k_ex) of SFMO at 750°C are 5.0 x 10^-6 cm² s^-1 and 2.8 x 10^-5 cm s^-1, respectively, suggesting that SFMO may have good electrochemicalactivity for oxygen reduction. SFMO shows a thermal expansion coefficient (TEC) of 14.5 x 10^-6 K^-1 the …

A 3-D Chain Algorithm With Pseudo-Rigid-Body Model Elements, Robert Parley Chase, Robert H. Todd, Larry L. Howell, Spencer P. Magleby

Faculty Publications

A chain algorithm element is created from pseudo-rigid-body segments and used in a chain calculation that accurately predicts the force deflection relationship of beams with large 3-D deflections. Each chain element is made up of three pseudo-rigid-body models superimposed on each other acting orthogonally in relation to each other. The chain algorithm can predict large displacements and the force-deflection relationship of lateral torsional buckled beams significantly faster than the finite element method. This approach is not intended to compete with finite element analysis, but rather is a supplement tool that may prove particularly useful in the early phases of design …

Dynamic Simulation Of A High Pressure Regulator, A. Shahani, H. Esmaili, Ashkan Aryaei, S. Mohammadi, M. Najar

Faculty Publications

In this paper, the dynamic simulation for a high pressure regulator is performed to obtain the regulator behavior. To analyze the regulator performance, the equation of motion for inner parts, the continuity equation for diverse chambers and the equation for mass flow rate were derived. Because of nonlinearity and coupling, these equations are solved using numerical methods and the results are presented. Additionally, the dynamic analysis results consist of the output pressure change versus time, the displacement of the moving parts versus time, the regulator mass flow rate versus time and the output pressure versus mass flow rate in different …

Optical Cell For Combinatorial In Situ Raman Spectroscopic Measurements Of Hydrogen Storage Materials At High Pressures And Temperatures, Jason R. Hattrick-Simpers, Wilbur S. Hurst, Sesha S. Srinivasan, James E. Maslar

Faculty Publications

An optical cell is described for high-throughput backscattering Raman spectroscopic measurements of hydrogen storagematerials at pressures up to 10 MPa and temperatures up to 823 K. High throughput is obtained by employing a 60 mm diameter × 9 mm thick sapphire window, with a corresponding 50 mm diameter unobstructed optical aperture. To reproducibly seal this relatively large window to the cell body at elevated temperatures and pressures, a gold o-ring is employed. The sample holder-to-window distance is adjustable, making this cell design compatible with optical measurement systems incorporating lenses of significantly different focal lengths, e.g., microscope objectives and single element …

High Conductivity Solid Oxide Electrolyte Composite-Laminates Utilizing Scandia/Ceria Co-Doped Zirconia Core With Yttria Stabilized Zirconia Outer Skins, Jay Neutzler, Xinyu Huang, Joshua Sightler, Yan Chen, Nina Orlovskaya

Faculty Publications

Increasing the conductivity of electrolytes in lower temperature Solid Oxide Fuel Cells (SOFC) is of great importance. However, there are several challenges that are to be addressed, which include phase stability of electrolyte’s crystal structure, chemical stability in both oxidizing and reducing environments, and maintaining mechanical integrity and high ionic conductivity over time.

Mechanical Characterization Of Polymer Electrolyte Membrane With Optical Methods, Xinyu Huang, Luis Alva, Jay Neutzler

Faculty Publications

Mechanical properties of polymer electrolyte membrane have important implications in the endurance of many electrochemical energy conversion devices [1]. Mechanical experiments are effective method to reveal discrete damage developed in the membrane by quantifying the change of mechanical strength and toughness. Regular strain measurement methods are overly intrusive to the thin and relatively fragile polymer electrolyte membrane; hence optical-based minimal invasive stress/strain measurement methods are studied.

Self Assembly In Additive Manufacturing: Opportunities And Obstacles, Nathan B. Crane, J. Tuckerman, G. N. Nielson

Faculty Publications

Purpose

Additive manufacturing offers substantial flexibility in shape, but much less flexibility in materials and functionality—particularly at small size scales. A system for automatically incorporating microscale components would enable the fabrication of objects with more functionality. This paper considers the potential of self assembly to serve as an automated programmable integration method. In particular, it addresses the ability of random self assembly processes to successfully assemble objects with high performance despite the possibility of assembly errors.

Methodology

A self-assembled thermoelectric system is taken as a sample system. The performance expectations for these systems are then predicted using modified one-dimensional models …