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Full-Text Articles in Mechanical Engineering

Formation Of Organized Nanostructures From Unstable Bilayers Of Thin Metallic Liquids, Mikhail Khenner, Sagar Yadavali, Ramki Kalyanaraman Dec 2011

Formation Of Organized Nanostructures From Unstable Bilayers Of Thin Metallic Liquids, Mikhail Khenner, Sagar Yadavali, Ramki Kalyanaraman

Mikhail Khenner

Dewetting of pulsed-laser irradiated, thin (< 20 nm), optically reflective metallic bilayers on an optically transparent substrate with a reflective support layer is studied within the lubrication equations model. A steady-state bilayer film thickness (h) dependent temperature profile is derived based on the mean substrate temperature estimated from the elaborate thermal model of transient heating and melting/freezing. Large thermocapillary forces are observed along the plane of the liquid-liquid and liquid-gas interfaces due to this h-dependent temperature, which, in turn, is strongly influenced by the h-dependent laser light reflection and absorption. Consequently the dewetting is a result of the competition between thermocapillary and intermolecular forces. A linear analysis of the dewetting length scales established that the non-isothermal calculations better predict the experimental results as compared to the isothermal case within the bounding Hamaker coefficients. Subsequently, a computational non-linear dynamics study of the dewetting pathway was performed for Ag/Co and Co/Ag bilayer systems to predict the morphology evolution. We found that the systems evolve towards formation of different morphologies, including core-shell, embedded, or stacked nanostructure morphologies.


Lectio Praecursoria, Kari Myöhänen Dec 2011

Lectio Praecursoria, Kari Myöhänen

Kari Myöhänen

Lectio praecursoria: Modelling of combustion and sorbent reactions in three-dimensional flow environment of a circulating fluidized bed furnace


Vuv Absorption Cross Section Of Benzene, Relevance For Titan’S Atmosphere, F-J. Capalbo, Y. Bénilan, N. Fray, M. Schwell, Et. Es-Sebbar, N. Champion, T. Koskinen, R. Yelle Jul 2011

Vuv Absorption Cross Section Of Benzene, Relevance For Titan’S Atmosphere, F-J. Capalbo, Y. Bénilan, N. Fray, M. Schwell, Et. Es-Sebbar, N. Champion, T. Koskinen, R. Yelle

Dr. Et-touhami Es-sebbar

Saturn's largest satellite, Titan, is the only one in the Solar System known to have a thick N2/CH4, planet like atmosphere. The dissociation of these principal components and the recombination of the products make this atmosphere to be rich in organic compounds of high interest for astrobiology. Solar and stellar occultations observed by the Ultraviolet Imaging Spectrograph (UVIS) on board the Cassini spacecraft can be used to characterize the composition of Titan’s upper atmosphere (400 – 1400 km). The results depend strongly on the knowledge of the molecular absorption cross sections of the atmospheric constituents (Ferradaz et al. 2009). This …


Bistability In A Simple Fluid Network Due To Viscosity Contrast, John B. Geddes, Brian D. Storey, David Gardner, Russell T. Carr Jun 2011

Bistability In A Simple Fluid Network Due To Viscosity Contrast, John B. Geddes, Brian D. Storey, David Gardner, Russell T. Carr

John B. Geddes

We study the existence of multiple equilibrium states in a simple fluid network using Newtonian fluids and laminar flow. We demonstrate theoretically the presence of hysteresis and bistability, and we confirm these predictions in an experiment using two miscible fluids of different viscosity—sucrose solution and water. Possible applications include blood flow, microfluidics, and other network flows governed by similar principles.


Characterization Of Continuous Vacuum Ultraviolet Lamps-Implication On The Study Of Methane Photolysis At Lyman Alpha (121.6 Nm), M-C. Gazeau, Y. Benilan, Et. Es-Sebbar, A. Jolly, E. Arzoumanian, N. Fray, H. Cottin Apr 2011

Characterization Of Continuous Vacuum Ultraviolet Lamps-Implication On The Study Of Methane Photolysis At Lyman Alpha (121.6 Nm), M-C. Gazeau, Y. Benilan, Et. Es-Sebbar, A. Jolly, E. Arzoumanian, N. Fray, H. Cottin

Dr. Et-touhami Es-sebbar

Low-temperature hydrogen plasmas are widely used as continuous vacuum ultraviolet irradiation sources in photochemical studies and, in particular, in laboratory simulations of planetary atmospheres. One of the most challenging objectives of such experiments is to retrieve accurate quantitative laboratory data allowing a reliable comparison with theoretical and/or observational ones. This task can only be achieved when the irradiation source delivers a well characterised radiation in terms of flux and wavelength dependency. As an example, we will present a study, developed in the frame of a program dedicated to simulations of Titan’s atmosphere, on methane photolysis at Lyman alpha (121.6 nm). …


Formation Of Hcn And Nh3 As Primary Compounds Of Titan’S Atmosphere Simulations Using N2-Ch4 Afterglow Plasma’’, M-C. Gazeau, Y. Bénilan, E. Arzoumanian, Et. Es-Sebbar, A. Jolly, C.D. Pintassilgo Apr 2011

Formation Of Hcn And Nh3 As Primary Compounds Of Titan’S Atmosphere Simulations Using N2-Ch4 Afterglow Plasma’’, M-C. Gazeau, Y. Bénilan, E. Arzoumanian, Et. Es-Sebbar, A. Jolly, C.D. Pintassilgo

Dr. Et-touhami Es-sebbar

No abstract provided.


Argon Rectification And The Cause Of Light Emission In Single-Bubble Sonoluminescence, Brian D. Storey, Andrew J. Szeri Mar 2011

Argon Rectification And The Cause Of Light Emission In Single-Bubble Sonoluminescence, Brian D. Storey, Andrew J. Szeri

Brian Storey

In single-bubble sonoluminescence, repeated brief flashes of light are produced in a gas bubble strongly driven by a periodic acoustic field. A startling hypothesis has been made by Lohse and co-workers [Phys. Rev. Lett. 78, 1359 (1997)] that the non-noble gases in an air bubble undergo chemical reaction into soluble products, leaving only argon. In the present work, this dissociation hypothesis is supported by simulations, although the associated temperatures of about 7000 K seem too low for bremsstrahlung, which has been proposed as the dominant light emission mechanism. This suggests that emission from water vapor and its reaction products, heretofore …


Shape Stability Of Sonoluminescence Bubbles: Comparison Of Theory To Experiments, Brian D. Storey Mar 2011

Shape Stability Of Sonoluminescence Bubbles: Comparison Of Theory To Experiments, Brian D. Storey

Brian Storey

Single bubble sonoluminescence (SBSL) is the brief flash of light emitted from a single, stable, acoustically forced bubble. In experiments, the maximum pressure amplitude with which a bubble may be forced is limited by considerations of spherical stability. The traditional linear stability analysis predicts a threshold for SBSL at a much lower pressure amplitude than experimental observations. This work shows that if one constructs an accurate model of the radial dynamics, the traditional linear stability analysis predicts a boundary that is in excellent agreement with experimental data.


Field-Amplified Sample Stacking And Focusing In Nanofluidic Channels, Jess M. Sustarich, Brian D. Storey, Sumita Pennathur Mar 2011

Field-Amplified Sample Stacking And Focusing In Nanofluidic Channels, Jess M. Sustarich, Brian D. Storey, Sumita Pennathur

Brian Storey

Nanofluidic technology is gaining popularity for bioanalytical applications due to advances in both nanofabrication and design. One major obstacle in the widespread adoption of such technology for bioanalytical systems is efficient detection of samples due to the inherently low analyte concentrations present in such systems. This problem is exacerbated by the push for electronic detection, which requires an even higher sensor-local sample concentration than optical detection. This paper explores one of the most common preconcentration techniques, field-amplified sample stacking, in nanofluidic systems in efforts to alleviate this obstacle. Holding the ratio of background electrolyte concentrations constant, the parameters of channel …


Rayleigh-Taylor Instability Of Violently Collapsing Bubbles, Hao Lin, Brian D. Storey, Andrew J. Szeri Mar 2011

Rayleigh-Taylor Instability Of Violently Collapsing Bubbles, Hao Lin, Brian D. Storey, Andrew J. Szeri

Brian Storey

In a classical paper Plesset has determined conditions under which a bubble changing in volume maintains a spherical shape. The stability analysis was further developed by Prosperetti to include the effects of liquid viscosity on the evolving shape modes. In the present work the theory is further modified to include the changing density of the bubble contents. The latter is found to be important in violent collapses where the densities of the gas and vapor within a bubble may approach densities of the liquid outside. This exerts a stabilizing influence on the Rayleigh–Taylor mechanism of shape instability of spherical bubbles. …


Electrohydrodynamic Instabilities In Microchannels With Time Periodic Forcing, David A. Boy, Brian D. Storey Mar 2011

Electrohydrodynamic Instabilities In Microchannels With Time Periodic Forcing, David A. Boy, Brian D. Storey

Brian Storey

In microfluidic applications it has been observed that flows with spatial gradients in electrical conductivity are unstable under the application of sufficiently strong electric fields. These electrohydrodynamic instabilities can drive a nonlinear flow despite the low Reynolds number. Such flows hold promise as a simple mechanism for mixing fluids. In this work, the effect of a time periodic electric field on the instability is explored. The case where an electric field is applied across a diffuse interface of two fluids with varying electrical conductivity is considered. Frequency-dependent behavior is found only in the regime where the instability growth rates are …


Bistability In A Simple Fluid Network Due To Viscosity Contrast, John B. Geddes, Brian D. Storey, David Gardner, Russell T. Carr Mar 2011

Bistability In A Simple Fluid Network Due To Viscosity Contrast, John B. Geddes, Brian D. Storey, David Gardner, Russell T. Carr

Brian Storey

We study the existence of multiple equilibrium states in a simple fluid network using Newtonian fluids and laminar flow. We demonstrate theoretically the presence of hysteresis and bistability, and we confirm these predictions in an experiment using two miscible fluids of different viscosity—sucrose solution and water. Possible applications include blood flow, microfluidics, and other network flows governed by similar principles.


Bulk Electroconvective Instability At High Péclet Numbers, Brian D. Storey, Boris Zaltzman, Isaak Rubinstein Mar 2011

Bulk Electroconvective Instability At High Péclet Numbers, Brian D. Storey, Boris Zaltzman, Isaak Rubinstein

Brian Storey

Bulk electroconvection pertains to flow induced by the action of a mean electric field upon the residual space charge in the macroscopic regions of a locally quasielectroneutral strong electrolyte. For a long time, controversy has existed in the literature as to whether quiescent electric conduction from such an electrolyte into a uniform charge-selective solid, such as a metal electrode or ion exchange membrane, is stable with respect to bulk electroconvection. While it was recently claimed that bulk electroconvective instability could not occur, this claim pertained to an aqueous, low-molecular-weight electrolyte characterized by an order-unity electroconvection Péclet number. In this paper, …


Instability Of Electro-Osmotic Channel Flow With Streamwise Conductivity Gradients, J. Jobim Santos, Brian D. Storey Mar 2011

Instability Of Electro-Osmotic Channel Flow With Streamwise Conductivity Gradients, J. Jobim Santos, Brian D. Storey

Brian Storey

This work considers the stability of an electro-osmotic microchannel flow with streamwise electrical conductivity gradients, a configuration common in microfluidic applications such as field amplified sample stacking. Previous work on such flows has focused on how streamwise conductivity gradients set a nonuniform electro-osmotic velocity which results in dispersion of the conductivity field. However, it has been known for many years that electric fields can couple with conductivity gradients to generate unstable flows. This work demonstrates that at high electric fields such an electrohydrodynamic instability arises in this configuration and the basic mechanisms are explored through numerical simulations. The instability is …


Steric Effects On Ac Electro-Osmosis In Dilute Electrolytes, Brian D. Storey, Lee R. Edwards, Mustafa Sabri Kilic, Martin Z. Bazant Mar 2011

Steric Effects On Ac Electro-Osmosis In Dilute Electrolytes, Brian D. Storey, Lee R. Edwards, Mustafa Sabri Kilic, Martin Z. Bazant

Brian Storey

The current theory of alternating-current electro-osmosis (ACEO) is unable to explain the experimentally observed flow reversal of planar ACEO pumps at high frequency (above the peak, typically 10–100 kHz), low salt concentration (1–1000 μM), and moderate voltage (2–6 V), even taking into account Faradaic surface reactions, nonlinear double-layer capacitance, and bulk electrothermal flows. We attribute this failure to the breakdown of the classical Poisson-Boltzmann model of the diffuse double layer, which assumes a dilute solution of pointlike ions. In spite of low bulk salt concentration, the large voltage induced across the double layer leads to crowding of the ions and …


A Depth-Averaged Electrokinetic Flow Model For Shallow Microchannels, Hao Lin, Brian D. Storey, Juan G. Santiago Mar 2011

A Depth-Averaged Electrokinetic Flow Model For Shallow Microchannels, Hao Lin, Brian D. Storey, Juan G. Santiago

Brian Storey

Electrokinetic flows with heterogeneous conductivity configuration occur widely in microfluidic applications such as sample stacking and multidimensional assays. Electromechanical coupling in these flows may lead to complex flow phenomena, such as sample dispersion due to electro-osmotic velocity mismatch, and electrokinetic instability (EKI). In this work we develop a generalized electrokinetic model suitable for the study of microchannel flows with conductivity gradients and shallow-channel geometry. An asymptotic analysis is performed with the channel depth-to-width ratio as a smallness parameter, and the three-dimensional equations are reduced to a set of depth-averaged equations governing in-plane flow dynamics. The momentum equation uses a Darcy–Brinkman–Forchheimer-type …


Applications Of A 3-D Cfb Model On Oxycombustion, Gasification And Calcinator In Calcium Looping, Kari Myöhänen, Timo Hyppänen, Markku Nikku, Matti Koski, Jarno Parkkinen Jan 2011

Applications Of A 3-D Cfb Model On Oxycombustion, Gasification And Calcinator In Calcium Looping, Kari Myöhänen, Timo Hyppänen, Markku Nikku, Matti Koski, Jarno Parkkinen

Kari Myöhänen

No abstract provided.


Termodynamika Procesowa (Dla Me Aparatura Procesowa) Ćw., Wojciech M. Budzianowski Jan 2011

Termodynamika Procesowa (Dla Me Aparatura Procesowa) Ćw., Wojciech M. Budzianowski

Wojciech Budzianowski

No abstract provided.


The Analysis Of Heat Transfer In A Gas-Gas Heat Exchanger Operated Under A Heat-Recirculating Mode, Mariusz Salaniec, Wojciech M. Budzianowski Jan 2011

The Analysis Of Heat Transfer In A Gas-Gas Heat Exchanger Operated Under A Heat-Recirculating Mode, Mariusz Salaniec, Wojciech M. Budzianowski

Wojciech Budzianowski

The present paper presents the analysis of heat transfer in a gas-gas heat exchanger operated in a heat-recirculating mode.


An Overview Of Technologies For Upgrading Of Biogas To Biomethane, Wojciech M. Budzianowski Jan 2011

An Overview Of Technologies For Upgrading Of Biogas To Biomethane, Wojciech M. Budzianowski

Wojciech Budzianowski

The present contribution presents an overview of technologies available for upgrading of biogas to biomethane. Technologies under study include pressure swing adsorption (PSA), high-pressure water wash (HPWW), reactive absorption (RA), physical absorption (PA), membrane separation (MS) and cryogenic separation (CS).


Influence Of Energy Policy On The Rate Of Implementation Of Biogas Power Plants In Germany During The 2001-2010 Decade, Izabela Chasiak, Wojciech M. Budzianowski Jan 2011

Influence Of Energy Policy On The Rate Of Implementation Of Biogas Power Plants In Germany During The 2001-2010 Decade, Izabela Chasiak, Wojciech M. Budzianowski

Wojciech Budzianowski

The current article describes energy policy tools, which caused intensive development of biogas-based power generation in Germany during the 2001-2010 decade. The German system of financial support to biogas power plants is presented in details. It is shown that in Germany, i.e. in a country characterised by similar climate and potentials to renewable energy to Poland, biogas power plants cover 10,7% of electricity demands in 2010, while all renewable energy sources cover only 5,4% of electricity demands. It is emphasised that under favourable Polish energy policy, the development of biogas energy can be very rapid.


Stability Of A Strongly Anisotropic Thin Epitaxial Film In A Wetting Interaction With Elastic Substrate, Mikhail Khenner, Wondimu T. Tekalign, Margo S. Levine Jan 2011

Stability Of A Strongly Anisotropic Thin Epitaxial Film In A Wetting Interaction With Elastic Substrate, Mikhail Khenner, Wondimu T. Tekalign, Margo S. Levine

Mikhail Khenner

The linear dispersion relation for longwave surface perturbations, as derived by Levine et al. Phys. Rev. B 75, 205312 (2007) is extended to include a smooth surface energy anisotropy function with a variable anisotropy strength (from weak to strong, such that sharp corners and slightly curved facets occur on the corresponding Wulff shape). Through detailed parametric studies it is shown that a combination of a wetting interaction and strong anisotropy, and even a wetting interaction alone results in complicated linear stability characteristics of strained and unstrained films.


Modeling Diverse Physics Of Nanoparticle Self-Assembly In Pulsed Laser-Irradiated Metallic Films, Mikhail Khenner Jan 2011

Modeling Diverse Physics Of Nanoparticle Self-Assembly In Pulsed Laser-Irradiated Metallic Films, Mikhail Khenner

Mikhail Khenner

Presents physics behind dewetting of thin liquid films and mathematical/computational modeling tools (Educational/Research presentation for senior physics majors).


Reverse Logic - Safety Of Spent Nuclear Fuel Disposal, Antti Lempinen, Marianne Silvan-Lempinen Dec 2010

Reverse Logic - Safety Of Spent Nuclear Fuel Disposal, Antti Lempinen, Marianne Silvan-Lempinen

Antti Lempinen

No abstract provided.