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Mechanical Engineering Commons

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2011

Aerospace Engineering

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Full-Text Articles in Mechanical Engineering

Phase Transition And Structure Of Silver Azide At High Pressure, Dongbin Hou, Fuxiang Zhang, Cheng Ji, Trevor Hannon, Hongyang Zhu, Jianzhe Wu, Valery I. Levitas, Yanzhang Ma Jul 2011

Phase Transition And Structure Of Silver Azide At High Pressure, Dongbin Hou, Fuxiang Zhang, Cheng Ji, Trevor Hannon, Hongyang Zhu, Jianzhe Wu, Valery I. Levitas, Yanzhang Ma

Aerospace Engineering Publications

ilver azide (AgN 3) was compressed up to 51.3 GPa. The results reveal a reversible second-order orthorhombic-to-tetragonal phase transformation starting from ambient pressure and completing at 2.7 GPa. The phase transition is accompanied by a proximity of cell parameters aand b, a 3° rotation of azide anions, and a change of coordination number from 4-4 (four short, four long) to eight fold. The crystal structure of the high pressure phase is determined to be inI4/mcm space group, with Ag at 4a, N1 at 4d, and N2 at 8h Wyckoff positions. Both of ...