Mechanical Engineering Commons^™

The Effect Of Stirring On The Morphology Of Birnessite Nanoparticles, Marcos A. Cheney, Pradip K. Bhowmik, Shingo Moriuchi, Mario Villabos, Shizhi Qian, Sang W. Joo

Mechanical & Aerospace Engineering Faculty Publications

The effect of mechanical stirring on the morphology of hexagonal layer- structure birnessite nanoparticles produced from decomposition of KMnO₄ in dilute aqueous H₂SO₄ is investigated, with characterization by X- ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), high- resolution transmission electron microscopy (HRTEM), thermogravimetric analysis (TGA), and N₂ adsorption (BET). Mechanical stirring during an initial stage of synthesis is shown to produce black birnessite containing nanofibers, whereas granular particulates of brown birnessite are produced without stirring. This is the first reduction synthesis of black birnessite nanoparticles with dendritic morphology without any use …