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Full-Text Articles in Mechanical Engineering
Distributions Of Noble Metal Pd And Pt In Mesoporous Silica, J. Arbiol, A. Cabot, J. R. Morante, Fanglin Chen, Meilin Liu
Distributions Of Noble Metal Pd And Pt In Mesoporous Silica, J. Arbiol, A. Cabot, J. R. Morante, Fanglin Chen, Meilin Liu
Faculty Publications
Mesoporous silica nanostructures have been synthesized and loaded with Pd and Pt catalytic noble metals. It is found that Pd forms small nanoclusters (3–5 nm) on the surface of the mesoporous structure whereas Pt impregnation results in the inclusion of Pt nanostructures within the silica hexagonal pores (from nanoclusters to nanowires). It is observed that these materials have high catalytic properties for CO–CH4 combustion, even in a thick film form. In particular, results indicate that the Pt and Pd dispersed in mesoporous silica are catalytically active as a selective filter for gas sensors.
Effect Of Residual Thermal Stresses On Fracture Behavior And Mechanical Properties Of Al Sub 2 O Sub 3/Ni Cermets, Guo Jin Li, Da Ming Chen, Xiao Xian Huang, Jing Kun Guo
Effect Of Residual Thermal Stresses On Fracture Behavior And Mechanical Properties Of Al Sub 2 O Sub 3/Ni Cermets, Guo Jin Li, Da Ming Chen, Xiao Xian Huang, Jing Kun Guo
Faculty Publications
Effect of residual thermal stresses on fracture behavior and mechanical properties of Al2O3/Ni cermets was qualitatively explained by using theory on residual thermal stresses. When Ni particles are located within Al2O3 grains or Ni content is relatively low, tensile stresses are exerted at Al2O3-Al2O3 grain boundary. While fracturing, intergranular fracture is easily produced. When Ni particles are dispersed at Al2O3 grain boundary or Ni content is relatively high, compressive stresses are exerted at Al2O3-Al2O3grain boundary. …