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Mechanical Engineering Commons

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1997

Free energy

Articles 1 - 2 of 2

Full-Text Articles in Mechanical Engineering

Extracting The Relative Grain Boundary Free Energy And Mobility Functions From The Geometry Of Microstructures, Brent L. Adams, D. Kinderlehrer, W. W. Mullins, Anthony D. Rollett, Shlomo Ta'asan Nov 1997

Extracting The Relative Grain Boundary Free Energy And Mobility Functions From The Geometry Of Microstructures, Brent L. Adams, D. Kinderlehrer, W. W. Mullins, Anthony D. Rollett, Shlomo Ta'asan

Faculty Publications

This work was supported primarily by the MRSEC Program of the National Science Foundation under Award Number DMR-9632556. This paper describes a method for extracting, from measurements of a polycrystal, the relative excess free energy and the relative mobility of the grain boundaries as functions of the crystallographic type (five degrees of freedom) and relevant thermodynamic variables. The method requires the simultaneous measurement of both the geometry and the crystallography of a large number of grain boundary intersections; the crystallographic information may be obtained from orientation imaging microscopy (OIM). For simplicity, the intersections will be assumed to be triple junctions …


Extracting The Grain Boundary Character/Free Energy Relationship From The Microstructure: Pure <100> And <111> Tilt Boundaries, Brent L. Adams, S. Costiner, D. Kinderlehrer, W. W. Mullins, Shlomo Ta'asan Jan 1997

Extracting The Grain Boundary Character/Free Energy Relationship From The Microstructure: Pure <100> And <111> Tilt Boundaries, Brent L. Adams, S. Costiner, D. Kinderlehrer, W. W. Mullins, Shlomo Ta'asan

Faculty Publications

This work was supported primarily by the MRSEC Program of the National Science Foundation under Award Number DMR-9632556. Analysis is described to extract the excess free energy of grain boundaries from the mesotexture of well-equilibrated polycrystalline samples. The approach is based upon the force and torque balances at triple junctions described in the classical work of Herring. The main advantage of the approach is that the free energy function is obtained over the full fundamental zone of grain boundary types. For the purposes of exposition, the method is described for specified two-parameter hypersurfaces in the fundamental zone for cubic polycrystals …