Mechanical Engineering Commons^™

Impurity Effects In All-Vanadium Redox Flow Batteries, Andrew William Burch

Masters Theses

In this dissertation, the effects of VOSO₄ [vanadyl sulfate] source and impurities on the beginning-of-life (BOL) performance of an all-vanadium redox flow battery (VRFB) are explored. Battery performance was monitored at 50% state of charge (SOC) using electrolyte with VOSO₄ purities of 99%, 99.9% and 99.99% by weight. At cell potentials of 1.23V, the least pure solution yielded the lowest current density of 280 mA/cm² [square centimeter] and the most pure solution yielded the highest, 560 mA/cm². The voltage efficiencies and charge-discharge capacities were shown to follow the same trends. Scanning electron microscopy (SEM) images …