Mechanical Engineering Commons^™

An Application Of Path-Percolation Theory And Lattice-Boltzmann Model On Mass Transfer In Inhomogeneous Porous Media, Ozgur Cekmer

Doctoral Dissertations

In this dissertation, random inhomogeneous porous channels were generated statistically, and single- and multi-phase flow models were developed to investigate diffusion behavior of gases in porous media. Three different methods were used to simulate inhomogeneous porous flow channels. First, the path-percolation theory was adapted in diffusion studies to generate random high-tortuosity (above 1.07) porous channels with a desired porosity within a specified confidence level. Cluster labeling process was applied to simulate paths for the gas molecules, and the resulting effective porosity was investigated statistically. Second, the double-path-percolation theory was introduced to simulate low-tortuosity (between 1.0005 and 1.0700) flow channels. Using …

Transport Resistance In Polymer Electrolyte Fuel Cells, Jon Patrick Owejan

Doctoral Dissertations

Fuel cells offer the potential for high efficiency energy conversion with only water and heat as significant products of the electrochemical reaction. For a cost-competitive product, fuel cell researchers are exploring the limits of the Pt catalyst loading in parallel with performance and durability trade-offs. A significant portion of the performance loss in low-cost PEMFCs is associated with the partial pressure of oxygen (for an air cathode) at the Pt surface. This dissertation explores the main components of oxygen transport resistance which are associated with diffusion through partially saturated porous media and the ionomer coating in the catalyst layer.

Under …