Mechanical Engineering Commons^™

Dynamics Modeling Of Molten Salt Reactors, Visura Umesh Pathirana

Doctoral Dissertations

The abundance of energy is a necessity for the prosperity of humans. The rise in energy demand has created energy shortages and issues related to energy security. Nuclear energy can produce vast amounts of reliable energy without many of the negative externalities associated with other competing energy sources, such as coal and natural gas. As a result, public interest in nuclear power has increased in the past decade. Many new types of nuclear reactor are proposed. These nuclear reactor designs feature many passive technologies that can operate without external influence. Reactors that feature advanced passive safety features are catagorized as …

Additively Manufactured Nature Inspired Morphology For Redesign: Advancing Next Generation Energy Systems, Vanshika Singh

Doctoral Dissertations

To meet cleaner energy goals and increasing demand, energy systems such as gas turbines and power plants are required to be operated under harsh loading conditions like higher temperatures and pressures, fluctuating loads, and corrosive environments. Advanced manufacturing techniques such as additive manufacturing (AM) have put us on the trajectory for next-generation system designs, allowing complex geometries and high-temperature alloys with tailored material properties. We need new and systematic design philosophies to use AM's unique characteristics prudently. For a given functionality, nature tends to provide similar solutions in animate and inanimate structures. We propose to take inspiration from nature's repetitive …

Heat Pump Integrated Thermal Storage For Building Demand Response And Decarbonization, Sara Sultan

Doctoral Dissertations

This work presents a novel thermal energy storage (TES) integrated with existing residential heat pump (HP). The research focuses on controls and configuration for energy, demand, cost and carbon emissions savings for residential buildings’ energy consumption. This work will be significant in developing a framework especially for reduced energy demand and carbon emissions associated with space heating and cooling in residential buildings. Since buildings account for about 40% primary energy consumption in U.S. and half of that is associated with HP.

An existing air source HP in integrated with a phase change material (PCM) based TES via active configuration where …

Transient Thermal Performance Enhancement Of Phase Change Materials Through Novel Pin Arrangements Under Varied Gravity Conditions, Junaid Khan

Masters Theses

This thesis presents a comprehensive examination of encapsulation techniques and performance enhancement strategies for Phase Change Materials (PCMs) in the thermal management of spacecraft avionics. This research contributes to optimizing PCM applications in spacecraft through historical analysis, transient thermal performance enhancement, and computational studies.

The first chapter explains the significance of PCMs in passive thermal management since the beginning of space-age technology, it underlines the low thermal conductivity of PCMs and the necessity of incorporating materials with high thermal conductivity, such as metal foams, to improve heat transfer. It also discusses various advancements in PCM research for spacecraft thermal management …

Investigating The Electrochemical Performance Of Biphenyl-Sodium Polysulfide Organic Redox Flow Batteries, Mohammad Bahzad

Doctoral Dissertations

With the increased utilization of renewable energy sources, demand for long-duration energy storage systems has increased to moderate the intermittent power generation problem of these sources. Among the various energy storage technologies, those based on electrochemical conversion have received tremendous attention in recent decades. Organic redox flow batteries (ORFBs) are promising candidates for large-scale energy storage. The advantages of ORFBs are flexibility, wide voltage window, high energy density, and low cost. Although recent developments in ORFBs are promising, their future implementation requires further development, especially to understand their electrochemical performance and alleviate system inefficiencies. Most of ORFBs' performance loss comes …

Multiscale Investigation Of Freeze Cast Process And Ion Transport For Graphene Aerogel Electrodes, Yu-Kai Weng

Doctoral Dissertations

Effective use of renewable energy resources has been regarded as the most promising solution to climate emergency and energy crisis. However, the fluctuating and intermittent nature of renewable resources causes stability issues in the electric grid. High-capacity electrical energy storage is essential to stabilize the electric power supply using renewable resources. Among various types of energy storage systems, organic redox flow battery (ORFB) has attracted attentions due to their high stability, flexibility, low cost, and environmental compatibility, but the performance of the ORFB still needs a significant improvement due to their low energy or current density. Specifically, even though the …

Environmental Design And Optimization Of Modular Hydropower Plants, Colin Sasthav

Doctoral Dissertations

This research aimed to understand the pathways to cost-effective and sustainable low-head hydropower. Designing viable hydropower projects requires optimization across many economic, environmental, and social outcomes. However, existing run-of-river hydropower design models often focus on economic performance and customizing technologies for high-head diversion schemes. Standard modular hydropower is a new design approach that uses standardized rather than custom-designed technologies to achieve economies of scale. Oak Ridge National Laboratory established a conceptual outline for module classes based on functions, such as generation modules and fish passage modules, but further research was needed to identify how modules should be selected and operated …

Experimental And Computational Study Of Determining Mass Transport Parameters In Vanadium Redox Flow Batteries, Tugrul Y. Ertugrul

Doctoral Dissertations

Vanadium redox flow batteries are a promising large-scale energy storage technology, but a number of challenges must be overcome for commercial implementation. At the cell level, mass transport contributes significantly to performance losses, limiting VRFB performance. Therefore, understanding mass transport mechanisms in the electrode is a critical step to mitigating such losses and optimizing VRFBs.

In this study, mass transport mechanisms (e.g. convection, diffusion) are investigated in a VRFB test bed using a strip cell architecture, having 1 cm² active area. It is found that diffusion-dominated cells have large current gradients; convection-dominated cells have relatively uniform current distribution from …

Utility Scale Building Energy Modeling And Climate Impacts, Brett C. Bass

Doctoral Dissertations

Energy consumption is steadily increasing year over year in the United States (US). Climate change and anthropogenically forced shifts in weather have a significant impact on energy use as well as the resilience of the built environment and the electric grid. With buildings accounting for about 40% of total energy use in the US, building energy modeling (BEM) at a large scale is critical. This work advances that effort in a number of ways. First, current BEM approaches, their ability to scale to large geographical areas, and global climate models are reviewed. Next, a methodology for large-scale BEM is illustrated, …

Characterization Of Near Isothermal Compression And Expansion For Energy Storage, Saiid Kassaee

Doctoral Dissertations

As the global share of electricity generation from intermittent renewable energy sources increases, developing efficient and scalable electricity storage technologies becomes critical to modernizing the grid, matching the supply and demand, and raising the capacity factor of renewable generation. The Ground-Level Integrated Diverse Energy Storage (GLIDES) is an efficient energy storage technology invented at Oak Ridge National Laboratory (ORNL). GLIDES stores energy by compressing gas using a liquid piston in pressure vessels benefiting from employing hydraulic turbomachinery which are more efficient than gas turbomachinery. Therefore, GLIDES has higher round-trip efficiency (RTE) than Compressed Air Energy Storage (CAES). Since GLIDES employs …

Experimental Investigation Of Spray Cooling/Heating Of A Near-Isothermal Hydro-Pneumatic Energy Storage System, Saiid Kassaee

Masters Theses

Proposing experimental investigation of spray cooling/heating of a near-isothermal, scalable, efficient, high density, hydro-pneumatic integrated energy storage system; capable of spray cooling/heating during gas compression/expansion and capable of excess heat integration. The invented Ground-Level Integrated Diverse Energy Storage (GLIDES) is an energy storage technology capable of storing energy in high-pressure vessel using hydro-pneumatic concept. Indicated roundtrip efficiencies of 98% can be reached using the proposed technology marking an isothermal compression/expansion energy storage.

Enhanced Kinetics And Modeling Of Pan-Based Carbon Felt Anodes In Vanadium Redox Flow Batteries, Michael Cyrus Daugherty

Doctoral Dissertations

All-vanadium redox flow batteries (VRFBs) are a promising technology for grid-level energy storage, however, there are still several limitations in the forms of durability, efficiency, and overall costs, which are barriers to its commercial viability. With both bulk electrolyte flowing through its porous matrix and species flux at the solid-electrolyte interface, electrodes are the component of VRFB systems which host electrochemical reactions and facilitate contact between the liquid phase electrolyte and the electronically conductive solid phase. While the more limiting electrode in VRFB systems is dependent on the material, for polyacrylonitrile (PAN)-based carbon felts, the anode constitutes a larger portion …

Thermal Chemical Energy Storage, William Miller, Samuel Swayne, Jonathan West, John Davis, James Mcbroom, Tennessee Bryant

Chancellor’s Honors Program Projects

No abstract provided.

Sensitivity Analysis For Best-Estimate Thermal Models Of Vertical Dry Cask Storage Systems, Remy R. Devoe, Kevin R. Robb, Steven Skutnik

Faculty Publications and Other Works -- Nuclear Engineering

Loading requirements for dry cask storage of spent nuclear fuel are driven primarily by decay heat capacity limitations, which themselves are determined through recommended limits on peak cladding temperature within the cask. This study examines the relative sensitivity of peak material temperatures within the cask to parameters that influence both the stored fuel residual decay heat as well as heat removal mechanisms. These parameters include the detailed reactor operating history parameters (e.g., soluble boron concentrations and the presence of burnable poisons) as well as factors that influence heat removal, including non-dominant processes (such as conduction from the fuel basket to …

Correlating Long-Term Lithium Ion Battery Performance With Solid Electrolyte Interphase (Sei) Layer Properties, Seong Jin An

Doctoral Dissertations

This study was conducted to understand effects of some of key factors (i.e., anode surface properties, formation cycling conditions, and electrolyte conditions) on solid electrolyte interphase (SEI) formation in lithium ion batteries (LIBs) and the battery cycle life. The SEI layer passivates electrode surfaces and prevents electron transfer and electrolyte diffusion through it while allowing lithium ion diffusion, which is essential for stable reversible capacities. It also influences initial capacity loss, self-discharge, cycle life, rate capability and safety. Thus, SEI layer formation and electrochemical stability are primary topics in LIB development. This research involves experiments and discussions on key factors …

Value Of Flow Measurement Accuracy In Hydropower Plants With Short Converging Intakes, Mark Herbert Christian

Doctoral Dissertations

This report documents research undertaken to determine the value of flow measurement accuracy in hydropower plants with short converging intakes. The motivation was to provide a suite of tools and best practices to streamline flow measurement sensor modeling in any type of hydropower plant. The Lower Granite Lock and Dam hydroplant was leveraged in development of the analysis tool. Computational fluid dynamics (CFD) models of Lower Granite Unit 4 provided necessary information about the hydraulic structures distribution through the unit. Two different CFD models were created. The first was done using the as-built plans; the second was created through modifications …

Computational Thermal-Hydraulics Modeling Of Twisted Tape Enabled High Heat Flux Components, Emily Buckman Clark

Doctoral Dissertations

The goal of this work was to perform a computational investigation into the thermalhydraulic performance of water-cooled, twisted tape enabled high heat flux components at fusion relevant conditions. Fusion energy is a promising option for future clean energy generation, but the community must overcome significant scientific and engineering challenges before meeting the goal of electricity generation. One such challenge is the high heat flux thermal management of components in fusion and plasma physics experiments. Plasma facing components in the magnetic confinement devices, such as ITER or W7-X, will be subjected to extreme heat loads on the order of 10-20 MW/m …

Impedance-Resolved Performance And Durability In Redox Flow Batteries, Alan Michael Pezeshki

Doctoral Dissertations

The realization of redox flow batteries (RFBs) as a grid-scale energy solution depends on improving the performance and lifetime of the technology to decrease the high capital costs. The electrodes are a key component in the RFB; performance enhancement is often achieved through chemical or thermal treatments of commercially available porous carbon materials.

This dissertation uses impedance spectroscopy-based methods to gain insight into performance and durability in RFBs, enabling intelligent cell design. Initial work focused on understanding the impact of improved electrode and membrane properties on system performance. An accelerated stress test was then developed that can be used to …

Fundamental Studies Of Electrochemical Reactions And Microfluidics In Proton Exchange Membrane Electrolyzer Cells, Jingke Mo

Doctoral Dissertations

In electrochemical energy devices, including fuel cells, electrolyzers and batteries, the electrochemical reactions occur only on triple phase boundaries (TPBs). The boundaries provide the conductors for electros and protons, the catalysts for electrochemical reactions and the effective pathways for transport of reactants and products. The interfaces have a critical impact on the overall performance and cost of the devices in which they are incorporated, and therefore could be a key feature to optimize in order to turn a prototype into a commercially viable product. For electrolysis of water, proton exchange membrane electrolyzer cells (PEMECs) have several advantages compared to other …

Investigation Of Localized Performance And Gas Evolution In All-Vanadium Redox Flow Batteries Via In-Situ Distributed Diagnostic Techniques, Jason Thomas Clement

Doctoral Dissertations

All-vanadium redox flow batteries (VRFBs) are an emerging grid-scale energy storage technology; however, enhancements in terms of performance, efficiency, durability, and cost are required before it can become commercially viable. These improvements are achievable through the development of advanced materials, superior architecture, and ultimately a deeper fundamental understanding of the influence of various phenomena and operational parameters on cell performance. There currently are a lack of in-situ experimental diagnostic techniques which can help in achieving this fundamental understanding.

Two separate distributed diagnostic techniques were developed in this work: in-plane current distribution, and neutron radiography. Localized current distribution measurements can identify …

Inter-Droplet Membranes For Mechanical Sensing Applications, Nima Tamaddoni Jahromi

Doctoral Dissertations

This dissertation combines self-assembly phenomena of amphiphilic molecules with soft materials to create and characterize mechanoelectrical transducers and sensors whose sensing elements are thin-film bioinspired membranes comprised of phospholipids or amphiphilic polymers. We show that the structures of these amphiphilic molecules tune the mechanical and electrical properties of these membranes. We show that these properties affect the mechanoelectrical sensing characteristic and range of operation of these membrane transducers. In the experiments, we construct and characterize a membrane-based hair cell embodiment that enables the membrane to be responsive to mechanical perturbations of the hair. The resulting oscillations of membranes formed between …

Computational Simulation Of Mass Transport And Energy Transfer In The Microbial Fuel Cell System, Shiqi Ou

Doctoral Dissertations

This doctoral dissertation introduces the research in the computational modeling and simulation for the microbial fuel cell (MFC) system which is a bio-electrochemical system that drives a current by using bacteria and mimicking bacterial interactions found in nature. The numerical methods, research approaches and simulation comparison with the experiments in the microbial fuel cells are described; the analysis and evaluation for the model methods and results that I have achieved are presented in this dissertation.

The development of the renewable energy has been a hot topic, and scientists have been focusing on the microbial fuel cell, which is an environmentally-friendly …

Impurity Effects In All-Vanadium Redox Flow Batteries, Andrew William Burch

Masters Theses

In this dissertation, the effects of VOSO₄ [vanadyl sulfate] source and impurities on the beginning-of-life (BOL) performance of an all-vanadium redox flow battery (VRFB) are explored. Battery performance was monitored at 50% state of charge (SOC) using electrolyte with VOSO₄ purities of 99%, 99.9% and 99.99% by weight. At cell potentials of 1.23V, the least pure solution yielded the lowest current density of 280 mA/cm² [square centimeter] and the most pure solution yielded the highest, 560 mA/cm². The voltage efficiencies and charge-discharge capacities were shown to follow the same trends. Scanning electron microscopy (SEM) images …

Optimization Of Titanium Liquid/Gas Diffusion Layers In Proton Exchange Membrane Electrolyzer Cells, Stuart Mccoy Steen

Masters Theses

Polymer electrolyte membrane electrolyzer cells (PEMECs), which are reverse PEM fuel cells (PEMFCs), are effective energy storage medium by producing hydrogen/oxygen from water using electricity from renewable energy sources. This is due in part because of its efficiency, high energy density, compact design, and large capacity. In a PEMEC, a liquid/gas diffusion layer (LGDL) is located between the catalyst layer and the current distributing flow field. The LGDL is expected to transport electrons, heat, and reactants/products to and from the catalyst layer with minimum voltage, current, thermal, interfacial, and fluidic losses. Carbon materials (carbon paper or carbon cloth), typically used …

An Application Of Path-Percolation Theory And Lattice-Boltzmann Model On Mass Transfer In Inhomogeneous Porous Media, Ozgur Cekmer

Doctoral Dissertations

In this dissertation, random inhomogeneous porous channels were generated statistically, and single- and multi-phase flow models were developed to investigate diffusion behavior of gases in porous media. Three different methods were used to simulate inhomogeneous porous flow channels. First, the path-percolation theory was adapted in diffusion studies to generate random high-tortuosity (above 1.07) porous channels with a desired porosity within a specified confidence level. Cluster labeling process was applied to simulate paths for the gas molecules, and the resulting effective porosity was investigated statistically. Second, the double-path-percolation theory was introduced to simulate low-tortuosity (between 1.0005 and 1.0700) flow channels. Using …

The Role Of Channel-Land Architecture, Diffusion Media Transport Properties, And Aging Effects On Water Transport And Storage In Polymer Electrolyte Fuel Cells, Jacob Michael Lamanna

Doctoral Dissertations

Thermally driven transport of water vapor in polymer electrolyte fuel cells, also known as the heat-pipe effect or phase-change-induced flow, can transport several times the generated amount of water given enough temperature differentials. Understanding this transport process is necessary to properly engineer the water balance in the fuel cell to ensure high performance and long operational life. Channel-land architecture, diffusion media heat and mass transport properties, and operational age can all have an influence on thermally driven flow. High resolution neutron imaging was used to determine the steady-state water accumulation in various cell configurations to understand the influence of these …

Transport Resistance In Polymer Electrolyte Fuel Cells, Jon Patrick Owejan

Doctoral Dissertations

Fuel cells offer the potential for high efficiency energy conversion with only water and heat as significant products of the electrochemical reaction. For a cost-competitive product, fuel cell researchers are exploring the limits of the Pt catalyst loading in parallel with performance and durability trade-offs. A significant portion of the performance loss in low-cost PEMFCs is associated with the partial pressure of oxygen (for an air cathode) at the Pt surface. This dissertation explores the main components of oxygen transport resistance which are associated with diffusion through partially saturated porous media and the ionomer coating in the catalyst layer.

Under …

Characterization Techniques And Electrolyte Separator Performance Investigation For All Vanadium Redox Flow Battery, Zhijiang Tang

Doctoral Dissertations

The all-vanadium redox flow battery (VRFB) is an excellent prospect for large scale energy storage in an electricity grid level application. High battery performance has lately been achieved by using a novel cell configuration with advanced materials. However, more work is still required to better understand the reaction kinetics and transport behaviors in the battery to guide battery system optimization and new battery material development. The first part of my work is the characterization of the battery systems with flow-through or flow-by cell configurations. The configuration difference between two cell structures exhibit significantly different polarization behavior. The battery output can …

Modeling And Validation Of Heat Transfer Present In A Solar Thermal Collector, Eric Ezekiel Stannard

Masters Theses

A solar absorber panel for a solar water heating system located at the College of Architecture’s New Norris House in Norris, TN was modeled and validated against field data in this work. The purpose of this modeling was to create the foundations of a tool that can be used in collector design and building energy simulations. This tool would take into account the radiometric properties of the collector materials, which are essential for an accurate model. Solar water heaters convert the shortwave energy of the Sun into usable heat for residential and industrial applications and have the potential to greatly …

Plasmonics Resonance Enhanced Active Photothermal Effects In Aluminum Nanoenergetics For Propulsion Applications, Jacques Abboud

Doctoral Dissertations

In this dissertation, aluminum nanoparticles (Al NPs) are shown capable to on-demand enhance and control the local photothermal energy deposition, both spatially and temporally, via active photothermal effects initiated by the localized surface plasmon resonance (LSPR) phenomenon, and amplified by the Al exothermal oxidation reactions. Experiments in dry and wet environments along with computational modeling of the photothermal process are very desirable for gaining fundamental understanding, ignition optimization and parameter exploration.

Combined phenomena of motion and ignition of Al NPs are explored first in this study. Both resulting from exposing a pile of the nanoenergetics in hand to a single …