Mechanical Engineering Commons^™

A New Approach For The Preparation Of Variable Valence Rare Earth Alloys From Nano Rare Earth Oxides At A Low Temperature In Molten Salt, Milin Zhang, Yongde Yan, Wei Han, Xing Li, Zhiyao Hou, Yang Tian, Ke Ye, Lihong Bao, Xiaodong Li, Zhijian Zhang

Faculty Publications

The solubility of RE₂O₃ (RE = Eu, Sm, and Yb) with variable valence in molten salts is extremely low. It is impossible to directly obtain variable valence metals or alloys from RE₂O₃ using electrolysis in molten salts. We describe a new approach for the preparation of variable valence rare earth alloys from nano rare earth oxide. The excellent dispersion of nano–Eu₂O₃ in LiCl–KCl melts was clearly observed using a luminescent feature of Eu³⁺ as a probe. The ratio of solubility of nano-Sm₂O₃/common Sm₂O_{3 …}