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Full-Text Articles in Mechanical Engineering

A Platinum Nanowire Network As A Highly Effective Current Collector For Intermediate Temperature Solid Oxide Fuel Cells, Hanping Ding, Xingjian Xue Dec 2015

A Platinum Nanowire Network As A Highly Effective Current Collector For Intermediate Temperature Solid Oxide Fuel Cells, Hanping Ding, Xingjian Xue

Xingjian "Chris" Xue

We report the fabrication and evaluation of a platinum nanowire network as a highly efficient current collector for solid oxide fuel cells (SOFCs). The ink of carbon-black supported platinum nanoparticles was sprayed onto the cathode. After firing, the carbon black was oxidized and disappeared as carbon dioxide gas while the platinum nanoparticles connect with one another, forming a tree-branch-like nanowire network. The diameters of the nanowires range from 100 nm to 400 nm. Compared to a conventional platinum paste current collector, the polarization resistance of the PrBaCo2O5+δ (PBCO) cathode with a nanowire current collector was reduced …


A Platinum Nanowire Network As A Highly Effective Current Collector For Intermediate Temperature Solid Oxide Fuel Cells, Hanping Ding, Xingjian Xue Dec 2015

A Platinum Nanowire Network As A Highly Effective Current Collector For Intermediate Temperature Solid Oxide Fuel Cells, Hanping Ding, Xingjian Xue

Xingjian "Chris" Xue

We report the fabrication and evaluation of a platinum nanowire network as a highly efficient current collector for solid oxide fuel cells (SOFCs). The ink of carbon-black supported platinum nanoparticles was sprayed onto the cathode. After firing, the carbon black was oxidized and disappeared as carbon dioxide gas while the platinum nanoparticles connect with one another, forming a tree-branch-like nanowire network. The diameters of the nanowires range from 100 nm to 400 nm. Compared to a conventional platinum paste current collector, the polarization resistance of the PrBaCo2O5+δ (PBCO) cathode with a nanowire current collector was reduced by 44% at 650 …


Modeling Of Chemical-Mechanical Couplings In Anode-Supported Solid Oxide Fuel Cells And Reliability Analysis, Xinfang Jin, Xingjian Xue Mar 2015

Modeling Of Chemical-Mechanical Couplings In Anode-Supported Solid Oxide Fuel Cells And Reliability Analysis, Xinfang Jin, Xingjian Xue

Xingjian "Chris" Xue

Oxygen ionic transport in conducting ceramics is an important mechanism enabling solid oxide fuel cell (SOFC) technology. The multi-physicochemical processes lead to the fact that the distribution of oxygen vacancy site fraction is not uniform in a positive-electrode electrolyte negative-electrode (PEN) assembly. Different oxygen vacancy concentrations induce different volumetric expansion of ceramics, resulting in complicated chemical–mechanical coupling phenomena and chemical stress in SOFCs. In this research, a mathematical model is developed to study oxygen ionic transport induced chemical stress in an SOFC. The model is validated using experimental polarization curves. Comprehensive simulations are performed to investigate chemical stress distribution in …


La0.7Sr0.3Fe0.7Ga0.3O3-Δ As Electrode Material For A Symmetrical Solid Oxide Fuel Cell, Zhibin Yang, Yu Chen, Chao Jin, Guoliang Xiao, Minfang Han, Fanglin Chen Mar 2015

La0.7Sr0.3Fe0.7Ga0.3O3-Δ As Electrode Material For A Symmetrical Solid Oxide Fuel Cell, Zhibin Yang, Yu Chen, Chao Jin, Guoliang Xiao, Minfang Han, Fanglin Chen

Fanglin Chen

In this research, La0.7Sr0.3Fe0.7Ga0.3O3−δ (LSFG) perovskite oxide was successfully prepared using a microwave-assisted combustion method, and employed as both anode and cathode in symmetrical solid oxide fuel cells. A maximum power density of 489 mW cm−2 was achieved at 800 °C with wet H2 as the fuel and ambient air as the oxidant in a single cell with the configuration LSFG|La0.8Sr0.2Ga0.83Mg0.17O3−δ|LSFG. Furthermore, the cells demonstrated good stability in H2 and acceptable sulfur tolerance.