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Articles 1 - 30 of 50
Full-Text Articles in Mechanical Engineering
Stress Relaxation Cracking In 347h Austenitic Steel Weldments Under Various Heat Treatments: Experiments And Modeling, Yi Yang
Doctoral Dissertations
347H austenitic stainless steel exhibits exceptional creep and corrosion resistance, rendering it an exemplary candidate for pipeline materials, particularly in mid- to high-temperature working conditions. However, due to constraints in component dimensions, welding has been chosen as the preferred method for joining pipeline systems extensively employed in nuclear power plants, fossil fuel plants, and petrochemical companies. The welding process entails the accumulation of residual stress during the cooling stage, along with the introduction of microstructure evolution. Moreover, the residual stress field and microstructure continuously evolve under service conditions, thereby intensifying the susceptibility of crack initiation and propagation. The initial residual …
Additive Manufacturing Of High-Performance Nanolamellar Eutectic High-Entropy Alloys, Jie Ren
Additive Manufacturing Of High-Performance Nanolamellar Eutectic High-Entropy Alloys, Jie Ren
Doctoral Dissertations
Additive manufacturing, also called three-dimensional (3D) printing, is an emerging technology for printing net-shaped components layer by layer for applications in automotive, aerospace, biomedical and other industries. In addition to the vast design freedom offered by this approach, metal 3D printing via laser powder-bed fusion (L-PBF) involves large temperature gradients and rapid cooling and provides exciting opportunities for producing microstructures and mechanical properties beyond those achievable by conventional processing routes. Although these extreme printing conditions enable microstructural refinement to the nanoscale for achieving high strength. However, high-strength nanostructured alloys by laser additive manufacturing often suffer from limited ductility. Eutectic high-entropy …
Controlling Mechanical Properties Of Well-Defined Polymer Networks, Ipek Sacligil
Controlling Mechanical Properties Of Well-Defined Polymer Networks, Ipek Sacligil
Doctoral Dissertations
Polymer networks are one of the most versatile and highly studied material class that revolutionized many aspects of life. Connecting the final network properties to the molecular parameters of its building blocks remains a major research thrust. Recent advances in network synthesis techniques allowed for accurate predictions of elastic modulus in model networks. Tew Group has developed highly efficient, thiol-norbornene networks with controllable mechanical properties. Chapter 2 focuses on modifying the gel fracture energy predicted by Lake-Thomas theory by accounting for loop defects. This study allowed for a priori estimates of gel fracture energy by combining theory, experiments, and simulations. …
Solidification Experiments And Magnetohydrodynamic Models In Electromagnetic Levitation, Gwendolyn Bracker
Solidification Experiments And Magnetohydrodynamic Models In Electromagnetic Levitation, Gwendolyn Bracker
Doctoral Dissertations
Electromagnetic levitation (EML) is a technique for containerless processing. The unique environment of containerless processing allows for the study of highly reactive melts at elevated temperatures. In containerless processing, the interface between a melt and its container is removed, reducing chemical contamination. In addition, levitation techniques reduce the available heterogeneous nucleation sites, providing greater access to the undercooled region for solidification studies. Levitation techniques provide the environment to study the fundamental behavior and thermophysical properties of liquid metals. During electromagnetic levitation experiments, magnetohydrodynamic flow is driven in the sample by the electromagnetic force field. This flow can have various effects …
Synthesis, Fabrication, And Assembly Of Mesoscale Polymer Filaments, Dylan M. Barber
Synthesis, Fabrication, And Assembly Of Mesoscale Polymer Filaments, Dylan M. Barber
Doctoral Dissertations
Mesoscale materials, with feature sizes in the range of one hundred nanometers to tens of micrometers, are ubiquitous in Nature. In organisms, mesoscale building blocks connect the properties of underlying molecular and nanoscructures to those of macroscale, organism-scale materials through hierarchical assemblies of recurring structural motifs. The collective action of large numbers of mesoscale features can afford stunning features like the structural color of the morpho butterfly wing, calcium ion-mediated movement in muscle, and wood structures like xylem that can support enormous external compressive loads and negative internal pressure to transport nutrients throughout an organism. In synthetic systems, the design, …
Processing Of Preceramic Polymers For Direct-Ink Writing, James W. Kemp
Processing Of Preceramic Polymers For Direct-Ink Writing, James W. Kemp
Doctoral Dissertations
Preceramic polymers are organosilicon polymers that, when pyrolyzed to above 1000°C, convert from a polymer to an amorphous ceramic. These polymers have been used for fiber spinning, polymer infiltration, and casting of materials but have recently gained interest for use as the feedstock material for additive manufacturing techniques. This work explores preceramic polymers being used for direct-ink writing (an additive manufacturing method) and many of the issues that occur with the polymers during curing and pyrolysis.
The first chapter of this dissertation provides a review of preceramic polymers, while the second and third chapters focus on the development of inks …
Interfacial Bonding Between Thermoset And Thermoplastic Polyurethane Reinforced Textile Grade Carbon Fiber: Structure Property Relationships, Surbhi Subhash Kore
Interfacial Bonding Between Thermoset And Thermoplastic Polyurethane Reinforced Textile Grade Carbon Fiber: Structure Property Relationships, Surbhi Subhash Kore
Doctoral Dissertations
The research work focused on examining the interfacial adhesion of unsized, epoxy, and urethane-sized textile grade carbon fiber (TCF) reinforced in different classes of polyurethane (PU) thermoplastic (TPU) and thermoset (TSU) polyurethane (PU) through the structure-property relationship. The Carbon Fiber Technology Facility (CFTF) at Oak Ridge National Laboratory (ORNL) has produced TCF to reduce the cost of commercial-grade carbon fiber. The first part of the research examined the fundamental relationships between (a) soft segment thermoplastic polyurethane (S-TPU), (b) hard segment thermoplastic polyurethane (H-TPU), (c) thermoset polyurethane (TSU) and TCF reinforcement’s molecular behavior at the interface using the surface and thermal …
Structural Stability Of Thermosets During Material Extrusion Additive Manufacturing, Stian K. Romberg
Structural Stability Of Thermosets During Material Extrusion Additive Manufacturing, Stian K. Romberg
Doctoral Dissertations
Over the past decade, the scale of polymer additive manufacturing has been revolutionized with machines that print massive thermoplastic parts with greater geometric complexity than can be achieved by traditional manufacturing methods. However, the heat required to print thermoplastics consumes energy and induces thermal gradients that can reduce manufacturing flexibility and final mechanical properties. With the ability to be extruded at room temperature and excellent compatibility with fibers and fillers, thermoset resins show promise to decrease the energy consumption, expand the manufacturing flexibility, and broaden the material palette offered by large-scale polymer additive manufacturing. However, structural instability in the uncured …
Innovations In Aligned And Overmolded Long Fiber Thermoplastic Composites, Shailesh P. Alwekar
Innovations In Aligned And Overmolded Long Fiber Thermoplastic Composites, Shailesh P. Alwekar
Doctoral Dissertations
Long fiber thermoplastic (LFT) composite materials are increasingly used in high performance lightweight automotive, sporting, and industrial applications. LFT composites are processed with extrusion-compression molding (ECM) and/or injection molding (IM). Melt extrusion offers unique opportunities to align long fibers in a thermoplastic polymer melt. The properties of LFT materials are highly influenced by processing techniques which leads to different porosity content, fiber length distribution, and fiber orientation distribution. Hence, it is important to understand the various LFT processing techniques and their effect on mechanical, thermal, and microscopic properties.
The fundamental process-property relationships in LFT composites are investigated in this dissertation. …
Advanced Materials Design Using Application-Based Processing Techniques, Daniel S. Camarda
Advanced Materials Design Using Application-Based Processing Techniques, Daniel S. Camarda
Doctoral Dissertations
This dissertation pertains to generating advanced materials using application-based processing techniques. First, billets consisting of PTFE sintering powders are evaluated using Thermomechancal Analysis. It was found that both shape change and volume change are associated with enthalpic and entropic recoil, respectively. These phenomena, due to melting and stored energy during the powder compaction process, were found to be molecular weight dependent. Additionally, kinetics of the recovery and sintering process were found to be slower in blended specimens than pure samples. Next, the creation of graft copolymers by selectively grafting a second polymer to the amorphous fraction of a semi-crystalline polymer …
Transients In Plastic Instabilities During Thermo-Mechanical Reversals In An Additively Manufactured Ti6al4v, Sabina C. Kumar
Transients In Plastic Instabilities During Thermo-Mechanical Reversals In An Additively Manufactured Ti6al4v, Sabina C. Kumar
Doctoral Dissertations
A complex interaction of process variables in an evolving geometry during Additive Manufacturing (AM), can bring about spatial and temporal transients of temperature and stress within each layer in a part. Although AM shares commonalities with conventional processing techniques such as casting, welding, and thermo-mechanical process, published literature has shown that the steady-state conditions are not strictly valid during AM process. Macro-scale fluctuations of thermal gradients (dT/dx: 103 to 107 K/m) combined with local changes in thermal expansion coefficients, crystallographic strains and localized stress-strain constitutive properties in conjunction with thermal cycles, can bring about a plastic strain gradient …
Thermoelectric Transport In Disordered Organic And Inorganic Semiconductors, Meenakshi Upadhyaya
Thermoelectric Transport In Disordered Organic And Inorganic Semiconductors, Meenakshi Upadhyaya
Doctoral Dissertations
The need for alternative energy sources has led to extensive research on optimizing the conversion efficiency of thermoelectric (TE) materials. TE efficiency is governed by figure-of-merit (ZT) and it has been an enormously challenging task to increase ZT > 1 despite decades of research due to the interdependence of material properties. Most doped inorganic semiconductors have a high electrical conductivity and moderate Seebeck coefficient, but ZT is still limited by their high lattice thermal conductivity. One approach to address this problem is to decrease thermal conductivity by means of alloying and nanostructuring, another is to consider materials with an inherently low …
Material Property Heterogeneity In Dimensional Lumber And Its Relationship To Mass Timber Performance, Fiona O'Donnell
Material Property Heterogeneity In Dimensional Lumber And Its Relationship To Mass Timber Performance, Fiona O'Donnell
Doctoral Dissertations
According to the Environmental Protection Agency, buildings account for 38% of the United States' carbon dioxide emissions, providing architects and structural engineers a unique opportunity to mitigate a significant factor driving climate change by implementing innovative and sustainable technology in infrastructure design. Wood and mass timber products are becoming an increasingly popular alternative building material due to their economic and environmental benefits. The natural growth of wood leads to highly heterogeneous material properties. Defects such as checks, knots, and localized slope of grain contribute to some of this variation; however, wood properties vary significantly even in clear wood. Using mass …
Electro-Thermal Transport In Two-Dimensional Materials And Their Heterostructures, Arnab K. Majee
Electro-Thermal Transport In Two-Dimensional Materials And Their Heterostructures, Arnab K. Majee
Doctoral Dissertations
”Smaller is better” is the mantra that has driven semiconductor industry for the past 50 years. The on-going quest for faster electronic switching, higher transistor density, and better device performance, has been driven by a self-fulfilling prophecy popularly known as Moore’s law, according to which the number of transistors per unit area of a chip doubles itself approximately every two years. A modern smartphone has about 8 billion transistors, which is as large as current earth’s population. Although each transistor dissipates negligible power, but the collective power dissipation from all the transistors in an electronic gadget and inefficient heat removing …
Harnessing The Mechanics Of Thin-Walled Metallic Structures: From Plate-Lattice Materials To Cold-Formed Steel Shear Walls, Fani Derveni
Harnessing The Mechanics Of Thin-Walled Metallic Structures: From Plate-Lattice Materials To Cold-Formed Steel Shear Walls, Fani Derveni
Doctoral Dissertations
Thin-walled structures have received a lot of interest during the last years due to their light weight, cost efficiency, and ease in fabrication and transportation, along with their high strength and stiffness. This dissertation focuses on the mechanical performance of thin-walled metallic structures from cold-formed steel shear walls and connections (PART I) to plate-lattice architected materials (PART II) via computational, experimental, and probabilistic methods. Cold-formed steel (CFS) shear walls subjected to seismic loads is the focus of PART I of this dissertation. An innovative three-dimensional shell finite element model of oriented strand board (OSB) sheathed CFS shear walls is introduced …
3d Printing Of Hybrid Architectures Via Core-Shell Material Extrusion Additive Manufacturing, Robert Cody Pack
3d Printing Of Hybrid Architectures Via Core-Shell Material Extrusion Additive Manufacturing, Robert Cody Pack
Doctoral Dissertations
Biological materials often employ hybrid architectures, such as the core-shell motif present in porcupine quills and plant stems, to achieve unique properties and performance. Drawing inspiration from these natural materials, a new method to fabricate lightweight and stiff core-shell architected filaments is reported. Specifically, a core-shell printhead conducive to printing highly loaded fiber-filled inks, as well as a new low-density syntactic foam ink, are utilized to 3D-print core-shell architectures consisting of a syntactic epoxy foam core surrounded by a stiff carbon fiber-reinforced epoxy composite shell. Effective printing of test specimens and structures with controlled geometry, composition, and architecture is demonstrated …
Process-Structure-Property Relationships In 3d-Printed Epoxy Composites Produced Via Material Extrusion Additive Manufacturing, Nadim S. Hmeidat
Process-Structure-Property Relationships In 3d-Printed Epoxy Composites Produced Via Material Extrusion Additive Manufacturing, Nadim S. Hmeidat
Doctoral Dissertations
Extrusion-based additive manufacturing (AM) technologies, such as direct ink writing (DIW), offer unique opportunities to create composite materials and novel multi-material architectures that are not feasible using other AM technologies. DIW is a novel 3D-printing approach in which viscoelastic inks, with favorable rheological properties, are extruded through fine nozzles and patterned in a filament form at room temperature.
Recent developments in DIW of polymer composites have led to expanding the range of materials used for printing, as well as introducing novel deposition strategies to control filler orientation and create improved functional/structural composite materials. Despite these substantial advancements, the successful and …
Characterization Of A Digital Holography Diagnostic For In Situ Erosion Measurement Of Plasma-Facing Components In Fusion Devices, Cary Dean Smith
Characterization Of A Digital Holography Diagnostic For In Situ Erosion Measurement Of Plasma-Facing Components In Fusion Devices, Cary Dean Smith
Doctoral Dissertations
Fusion energy devices, particularly tokamaks, face the challenge of interior surface damage occurring over time from the heat flux of the high-energy plasma they generate. The ability to monitor the rate of surface modification is therefore imperative, but to date no proven technique exists for real-time erosion measurement of planar regions of interest on plasma-facing components in fusion devices. In order to fill this diagnostic gap, a digital holography system has been established at ORNL [Oak Ridge National Laboratory] for the purpose of measuring the erosion effects of plasma-material interaction in situ.
The diagnostic has been designed with the …
Processing-Structure-Performance Relationships In Fused Filament Fabricated Fiber Reinforced Abs For Material Qualification, William Howard Ferrell
Processing-Structure-Performance Relationships In Fused Filament Fabricated Fiber Reinforced Abs For Material Qualification, William Howard Ferrell
Doctoral Dissertations
This dissertation uses the processing-structure-performance relationships to elucidate future needs in qualification of materials manufactured by fused filament fabrication and also introduces a previously unused testing method for the determination of fracture toughness in these materials. Fused filament fabrication (FFF) is an additive manufacturing technique that utilizes the layering of deposited molten plastic in two dimensional shapes to create three dimensional objects. This technique has gained traction over the past two decades as a disruptive manufacturing technology that promises many benefits. In order for FFF to truly be a staple in manufacturing spaces across the world for the production of …
Cracking And Earing Phenomenon In Deep-Drawn Stainless Steel Alloys: Role Of Transformation Kinetics, Microstructure, And Texture, Peijun Hou
Doctoral Dissertations
The enhancement of formability of advanced high-strength TRIP-assisted steel alloys is a challenging assignment for industrial application due to the cracking phenomenon. The critical factor governing the cracking behavior is residual-stress concentration resulting from the inhomogeneous plastic deformation and microstructural evolution during the forming processes. Martensitic phase transformation kinetics, constituent phases, and crystallographic texture in TRIP-assisted steel alloys are correlated to the microstructure evolution, resulting in phase-specific stress concentration. In the current study, we are aiming at understanding the fundamental mechanisms responsible for the cracking phenomenon and thus improving the formability of TRIP-assisted steel alloys. Four stainless steel (SS) alloys …
Polymeric Impulsive Actuation Mechanisms: Development, Characterization, And Modeling, Yongjin Kim
Polymeric Impulsive Actuation Mechanisms: Development, Characterization, And Modeling, Yongjin Kim
Doctoral Dissertations
Recent advances in the field of biomedical and life-sciences are increasingly demanding more life-like actuation with higher degrees of freedom in motion at small scales. Many researchers have developed various solutions to satisfy these emerging requirements. In many cases, new solutions are made possible with the development of novel polymeric actuators. Advances in polymeric actuation not only addressed problems concerning low degree of freedom in motion, large system size, and bio-incompatibility associated with conventional actuators, but also led to the discovery of novel applications, which were previously unattainable with conventional engineered systems. This dissertation focuses on developing novel actuation mechanisms …
Mechanical Performance Of Structural Systems With Missing Members: From Buildings To Architected Materials, Panagiotis Pantidis
Mechanical Performance Of Structural Systems With Missing Members: From Buildings To Architected Materials, Panagiotis Pantidis
Doctoral Dissertations
Structural systems are potentially subjected to damage initiating scenarios throughout the course of their service time. Depending on the nature and extent of the damaging event, they may experience significant reduction or even complete loss of their mechanical performance. This dissertation delves into the mechanics of structural systems under the notion of missing members from their domain, investigating types of structural systems: a) multi-story steel framed buildings, and b) materials with a truss-lattice microstructure. Part I of the dissertation investigates the performance of multi-story steel framed buildings under a column removal scenario, developing an analytical framework for their quasi-static robustness …
Freeform Extrusion Fabrication Of Advanced Ceramics And Ceramic-Based Composites, Wenbin Li
Freeform Extrusion Fabrication Of Advanced Ceramics And Ceramic-Based Composites, Wenbin Li
Doctoral Dissertations
"Ceramic On-Demand Extrusion (CODE) is a recently developed freeform extrusion fabrication process for producing dense ceramic components from single and multiple constituents. In this process, aqueous paste of ceramic particles with a very low binder content ( < 1 vol%) is extruded through a moving nozzle to print each layer sequentially. Once one layer is printed, it is surrounded by oil to prevent undesirable water evaporation from the perimeters of the part. The oil level is regulated just below the topmost layer of the part being fabricated. Infrared radiation is then applied to uniformly and partially dry the top layer so that the yield stress of the paste increases to avoid part deformation. By repeating the above steps, the part is printed in a layer-wise fashion, followed by post-processing. Paste extrusion precision of different extrusion mechanisms was compared and analyzed, with an auger extruder determined to be the most suitable paste extruder for the CODE system. A novel fabrication system was developed based on a motion gantry, auger extruders, and peripheral devices. Sample specimens were then produced from 3 mol% yttria stabilized zirconia using this fabrication system, and their properties, including density, flexural strength, Young's modulus, Weibull modulus, fracture toughness, and hardness were measured. The results indicated that superior mechanical properties were achieved by the CODE process among all the additive manufacturing processes. Further development was made on the CODE process to fabricate ceramic components that have external/internal features such as overhangs by using fugitive support material. Finally, ceramic composites with functionally graded materials (FGMs) were fabricated by the CODE process using a dynamic mixing device"--Abstract, page iv.
Remanufacturing Of Precision Metal Components Using Additive Manufacturing Technology, Xinchang Zhang
Remanufacturing Of Precision Metal Components Using Additive Manufacturing Technology, Xinchang Zhang
Doctoral Dissertations
"Critical metallic components such as jet engine turbine blades and casting die/mold may be damaged after servicing for a period at harsh working environments such as elevated temperature and pressure, impact with foreign objects, wear, corrosion, and fatigue. Additive manufacturing has a promising application for the refurbishment of such high-costly parts by depositing materials at the damaged zone to restore the nominal geometry. However, several issues such as pre-processing of worn parts to assure the repairability, reconstructing the repair volume to generate a repair tool path for material deposition, and inspection of repaired parts are challenging. The current research aims …
Build Strategy Investigation Of Ti-6al-4v Produced Via A Hybrid Additive Manufacturing Process, Lei Yan
Build Strategy Investigation Of Ti-6al-4v Produced Via A Hybrid Additive Manufacturing Process, Lei Yan
Doctoral Dissertations
“Till now, laser metal deposition (LMD) has been developed with the capability of near-net shape high-performance metal parts fabrication, especially complicated titanium alloys, nickel alloys, and aluminum alloys. However, LMD processed parts usually do not meet end-use requirements without post treatments. In-process part quality inspection and inner features machining are impossible within a single LMD process. Hybrid additive manufacturing (HAM), which integrates additive and subtractive manufacturing in one process, has been proposed to increase the feasibility of complex parts fabrication. This dissertation aims to improve the applications of Ti-6Al-4V parts fabricated via a HAM technique. The first research topic is …
Modeling Deformation Behavior And Strength Characteristics Of Sand-Silt Mixtures: A Micromechanical Approach, Mehrashk Meidani
Modeling Deformation Behavior And Strength Characteristics Of Sand-Silt Mixtures: A Micromechanical Approach, Mehrashk Meidani
Doctoral Dissertations
This dissertation is comprised of six chapters. In the first chapter the motivation of this research, which was modeling the deformation behavior and strength characteristics of soils under internal erosion, is briefly explained. In the second chapter a micromechanis-based stress-strain model developed for prediction of sand-silt mixtures behavior is presented. The components of the micromechanics-based model are described and undrained behavior of six different types of sand-silt mixtures is predicted for several samples with different fines contents. The need for a more comprehensive compression model for sand-silt mixtures is identified at the end of this chapter. This desired compression model …
Quantitative Phase-Field Modeling Of Crack Propagation In Multi-Phase Materials, Arezoo Emdadi
Quantitative Phase-Field Modeling Of Crack Propagation In Multi-Phase Materials, Arezoo Emdadi
Doctoral Dissertations
”Research presented in this dissertation is focused on developing and validating a computational framework for study of crack propagation in polycrystalline composite ceramics capable of designing micro-architectures of phases to improve fracture toughness and damage tolerance of ZrB2-based ultra-high temperature ceramics (UHTCs). A quantitative phase-field model based on the regularized formulation of Griffith’s theory is presented for crack propagation in homogenous and heterogeneous brittle materials. This model utilizes correction parameters in the total free energy functional and mechanical equilibrium equation within the crack diffusive area to ensure that the maximum stress in front of the crack tip is …
High Temperature Polymer Composites Using Out-Of-Autoclave Processing, Sudharshan Anandan
High Temperature Polymer Composites Using Out-Of-Autoclave Processing, Sudharshan Anandan
Doctoral Dissertations
"High performance polymer composites possess high strength-to-weight ratio, corrosion resistance, and have design flexibility. Carbon/epoxy composites are commonly used aerospace materials. Bismaleimide based composites are used as a replacement for epoxy systems at higher service temperatures. Aerospace composites are usually manufactured, under high pressure, in an autoclave which requires high capital investments and operating costs. In contrast, out-of-autoclave manufacturing, specifically vacuum-bag-only prepreg process, is capable of producing low cost and high performance composites. In the current study, out-of-autoclave processing of high temperature carbon/bismaleimide composites was evaluated. The cure and process parameters were optimized. The properties of out-of-autoclave cured laminates compared …
Soy-Based Polyurethane Foam For Insulation And Structural Applications, Gurjot S. Dhaliwal
Soy-Based Polyurethane Foam For Insulation And Structural Applications, Gurjot S. Dhaliwal
Doctoral Dissertations
"Polyurethane (PU) foams are widely used as insulation materials due to their high insulation properties and low cost compared to conventional materials such as styrene and mineral wool. PU foams are traditionally fabricated with petroleum-based precursors. However, high crude price and higher carbon footprint has lead interest of researchers to synthesis PU foams using plant-based raw materials, that are inexpensive and renewable. In this dissertation, PU foams were fabricated using soy-based polyol and its thermal and mechanical properties were investigated. In the first part, of PU foam samples with different formulations were fabricated using soy-based polyol HB230, and varying amounts …
Direct Printing Of Single-Crystal Silicon By Microscale Nanoparticle Printing And Confined Laser Melting And Crystallization, Wan Shou
Doctoral Dissertations
"The transport and interfacial phenomena in laser melting and crystallization of silicon in micro-/nano-scale confinement lacks sufficient understanding. Uncovering the underlying mechanisms, and hence harness the melting and crystallization processes can help the formation of controllable single-crystal structures or patterns. In this dissertation, a molecular dynamics (MD) simulation was conducted to calculate the interfacial free energy of the silicon system in contact with flat and structured walls. Then the calculated interfacial energies were employed to predict the nucleation mechanisms in a slab of liquid silicon confined by two walls and compared with MD simulation results. Further, in combination with a …