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Articles 1 - 30 of 55
Full-Text Articles in Mechanical Engineering
Characterization Of Interlayer Laser Shock Peening During Fused Filament Fabrication Of Polylactic Acid (Pla), Fabien Denise
Characterization Of Interlayer Laser Shock Peening During Fused Filament Fabrication Of Polylactic Acid (Pla), Fabien Denise
Department of Mechanical and Materials Engineering: Dissertations, Theses, and Student Research
The field of additive manufacturing (AM) has gained a significant amount of popularity due to the increasing need for more sustainable manufacturing techniques and the adaptive development of complex product geometries. The problem is that AM parts routinely exhibit flaws or weaknesses that affect functionality or performance. Over the years, surface treatments have been developed to compensate certain flaws or weaknesses in manufactured products. Combining surface treatments with the modularity of additive manufacturing could lead to more adaptable and creative improvements of product functions in the future. The current work evaluates the feasibility of pursuing a new research axis in …
Sharprazor: Automatic Removal Of Hair And Ruler Marks From Dermoscopy Images, Reda Kasmi, Jason Hagerty, Reagan Harris Young, Norsang Lama, Januka Nepal, Jessica Miinch, William V. Stoecker, R. Joe Stanley
Sharprazor: Automatic Removal Of Hair And Ruler Marks From Dermoscopy Images, Reda Kasmi, Jason Hagerty, Reagan Harris Young, Norsang Lama, Januka Nepal, Jessica Miinch, William V. Stoecker, R. Joe Stanley
Mechanical and Aerospace Engineering Faculty Research & Creative Works
Background: The removal of hair and ruler marks is critical in handcrafted image analysis of dermoscopic skin lesions. No other dermoscopic artifacts cause more problems in segmentation and structure detection. Purpose: The aim of the work is to detect both white and black hair, artifacts and finally inpaint correctly the image. Method: We introduce a new algorithm: SharpRazor, to detect hair and ruler marks and remove them from the image. Our multiple-filter approach detects hairs of varying widths within varying backgrounds, while avoiding detection of vessels and bubbles. The proposed algorithm utilizes grayscale plane modification, hair enhancement, segmentation using tri-directional …
Enabling An Equitable Energy Transition Through Inclusive Research, Michael Ash, Erin Baker, Mark Tuominen, Dhandapani Venkataraman, Matthew Burke, S. Castellanos, M. Cha, Gabe Chan, D. Djokic, J.C. Ford, Anna P. Goldstein, David Hsu, Matt Lacker, C. Miller, D. Nock, A.P. Ravikumar, Allison Bates, Anna Stefanopoulou, E Grubert, D.M Kammen, M. Pastor, S.Z, Attari, S. Carley, D.L Clark, D. Dean-Ryan, U. Kosar, Kerry Bowie, Tina Johnson
Enabling An Equitable Energy Transition Through Inclusive Research, Michael Ash, Erin Baker, Mark Tuominen, Dhandapani Venkataraman, Matthew Burke, S. Castellanos, M. Cha, Gabe Chan, D. Djokic, J.C. Ford, Anna P. Goldstein, David Hsu, Matt Lacker, C. Miller, D. Nock, A.P. Ravikumar, Allison Bates, Anna Stefanopoulou, E Grubert, D.M Kammen, M. Pastor, S.Z, Attari, S. Carley, D.L Clark, D. Dean-Ryan, U. Kosar, Kerry Bowie, Tina Johnson
ETI Publications
Comprehensive and meaningful inclusion of marginalized communities within the research enterprise will be critical to ensuring an equitable, technology-informed, clean energy transition. We provide five key action items for government agencies and philanthropic institutions to operationalize the commitment to an equitable energy transition.
Thermotrophy Exploratory Study, James Weifu Lee
Thermotrophy Exploratory Study, James Weifu Lee
Chemistry & Biochemistry Faculty Publications
The question of whether environmental heat energy could be utilized as a source of energy for biological metabolism is the center of this exploratory research. In 1979, this author postulated a hypothesis for the existence of thermotrophs that could isothermally utilize environmental heat energy as a source of their energy on Earth. According to this hypothesis, the thermotrophs could be the first primitive forms of life in the early Earth environment. The chemotrophs and phototrophs that we currently are all well familiar with might have been evolved somehow from the primitive thermotrophs. Furthermore, all the organisms currently regarded as the …
Aircraft Engine Particulate Matter Emissions From Sustainable Aviation Fuels: Results From Ground-Based Measurements During The Nasa/Dlr Campaign Eclif2/Nd-Max, Tobias Schripp, Bruce E. Anderson, Uwe Bauder, Bastian Rauch, Joel C. Corbin, Greg J. Smallwood, Prem Lobo, Ewan C. Crosbie, Michael A. Shook, Richard C. Miake-Lye, Zhenhong Yu, Andrew Freedman, Philip D. Whitefield, Claire E. Robinson
Aircraft Engine Particulate Matter Emissions From Sustainable Aviation Fuels: Results From Ground-Based Measurements During The Nasa/Dlr Campaign Eclif2/Nd-Max, Tobias Schripp, Bruce E. Anderson, Uwe Bauder, Bastian Rauch, Joel C. Corbin, Greg J. Smallwood, Prem Lobo, Ewan C. Crosbie, Michael A. Shook, Richard C. Miake-Lye, Zhenhong Yu, Andrew Freedman, Philip D. Whitefield, Claire E. Robinson
Chemistry Faculty Research & Creative Works
The use of alternative jet fuels by commercial aviation has increased substantially in recent years. Beside the reduction of carbon dioxide emission, the use of sustainable aviation fuels (SAF) may have a positive impact on the reduction of particulate emissions. This study summarizes the results from a ground-based measurement activity conducted in January 2018 as part of the ECLIF2/ND-MAX campaign in Ramstein, Germany. Two fossil reference kerosenes and three different blends with the renewable fuel component HEFA-SPK (Hydroprocessed Esters and Fatty Acids Synthetic Paraffinic Kerosene) were burned in an A320 with V2527-A5 engines to investigate the effect of fuel naphthalene/aromatic …
Bbt Acoustic Alternative Top Bracing Cadd Data Set-Norev-2022jun28, Bill Hemphill
Bbt Acoustic Alternative Top Bracing Cadd Data Set-Norev-2022jun28, Bill Hemphill
STEM Guitar Project’s BBT Acoustic Kit
This electronic document file set consists of an overview presentation (PDF-formatted) file and companion video (MP4) and CADD files (DWG & DXF) for laser cutting the ETSU-developed alternate top bracing designs and marking templates for the STEM Guitar Project’s BBT (OM-sized) standard acoustic guitar kit. The three (3) alternative BBT top bracing designs in this release are
(a) a one-piece base for the standard kit's (Martin-style) bracing,
(b) 277 Ladder-style bracing, and
(c) an X-braced fan-style bracing similar to traditional European or so-called 'classical' acoustic guitars.
The CADD data set for each of the three (3) top bracing designs includes …
Bbt Side Mold Assy, Bill Hemphill
Bbt Side Mold Assy, Bill Hemphill
STEM Guitar Project’s BBT Acoustic Kit
This electronic document file set covers the design and fabrication information of the ETSU Guitar Building Project’s BBT (OM-sized) Side Mold Assy for use with the STEM Guitar Project’s standard acoustic guitar kit. The extended 'as built' data set contains an overview file and companion video, the 'parent' CADD drawing, CADD data for laser etching and cutting a drill &/or layout template, CADD drawings in AutoCAD .DWG and .DXF R12 formats of the centerline tool paths for creating the mold assembly pieces on an AXYZ CNC router, and support documentation for CAM applications including router bit specifications, feeds, speed, multi-pass …
Hybridization From Guest-Host Interactions Reduces The Thermal Conductivity Of Metal-Organic Frameworks, Mallory E. Decoster, Hasan Babaei, Sangeun S. Jung, Zeinab M. Hassan, John T. Gaskins, Ashutosh Giri, Emma M. Tiernan, John A. Tomko, Helmut Baumgart, Pamela M. Norris, Alan J.H. Mcgaughey, Christopher E. Wilmer, Engelbert Redel, Gaurav Giri, Patrick E. Hopkins
Hybridization From Guest-Host Interactions Reduces The Thermal Conductivity Of Metal-Organic Frameworks, Mallory E. Decoster, Hasan Babaei, Sangeun S. Jung, Zeinab M. Hassan, John T. Gaskins, Ashutosh Giri, Emma M. Tiernan, John A. Tomko, Helmut Baumgart, Pamela M. Norris, Alan J.H. Mcgaughey, Christopher E. Wilmer, Engelbert Redel, Gaurav Giri, Patrick E. Hopkins
Electrical & Computer Engineering Faculty Publications
We experimentally and theoretically investigate the thermal conductivity and mechanical properties of polycrystalline HKUST-1 metal–organic frameworks (MOFs) infiltrated with three guest molecules: tetracyanoquinodimethane (TCNQ), 2,3,5,6-tetrafluoro-7,7,8,8-tetracyanoquinodimethane (F4-TCNQ), and (cyclohexane-1,4-diylidene)dimalononitrile (H4-TCNQ). This allows for modification of the interaction strength between the guest and host, presenting an opportunity to study the fundamental atomic scale mechanisms of how guest molecules impact the thermal conductivity of large unit cell porous crystals. The thermal conductivities of the guest@MOF systems decrease significantly, by on average a factor of 4, for all infiltrated samples as compared to the uninfiltrated, pristine HKUST-1. This reduction in thermal conductivity goes in …
Numerical Reconstruction Of Spalled Particle Trajectories In An Arc-Jet Environment, Raghava S. C. Davuluri, Sean C. C. Bailey, Kaveh A. Tagavi, Alexandre Martin
Numerical Reconstruction Of Spalled Particle Trajectories In An Arc-Jet Environment, Raghava S. C. Davuluri, Sean C. C. Bailey, Kaveh A. Tagavi, Alexandre Martin
Mechanical Engineering Faculty Publications
To evaluate the effects of spallation on ablative material, it is necessary to evaluate the mass loss. To do so, a Lagrangian particle trajectory code is used to reconstruct trajectories that match the experimental data for all kinematic parameters. The results from spallation experiments conducted at the NASA HYMETS facility over a wedge sample were used. A data-driven adaptive methodology was used to adapts the ejection parameters until the numerical trajectory matches the experimental data. The preliminary reconstruction results show that the size of the particles seemed to be correlated with the location of the ejection event. The size of …
Effect Of Heat Treatment On Microstructure And Hardness Of A Worn Rail Repaired Using Laser Powder Deposition, Ershad Mortazavian, Zhiyong Wang, Hualiang Teng
Effect Of Heat Treatment On Microstructure And Hardness Of A Worn Rail Repaired Using Laser Powder Deposition, Ershad Mortazavian, Zhiyong Wang, Hualiang Teng
Mechanical Engineering Faculty Research
The frequent replacement of worn rails on tracks brings an immense economic burden on the railroad industry, and also causes significant interruptions to railroad operation. Restoration of worn rails via laser powder deposition (LPD) can considerably reduce the associated maintenance costs. This study was focused on the use of LPD to repair the worn profile of a standard U.S. rail. The microstructure of the 304L stainless steel deposits with a minimum hardness of 85 HRB was composed of austenite, δ-ferrite, and sigma. Micropores were dispersed throughout the deposit, and microcracks were found at the rail-deposition interface. The pearlitic rail substrate …
Application Of A Small Unmanned Aerial System To Measure Ammonia Emissions From A Pilot Amine-Co2 Capture System, Travis J. Schuyler, Bradley Irvin, Keemia Abad, Jesse G. Thompson, Kunlei Liu, Marcelo I. Guzman
Application Of A Small Unmanned Aerial System To Measure Ammonia Emissions From A Pilot Amine-Co2 Capture System, Travis J. Schuyler, Bradley Irvin, Keemia Abad, Jesse G. Thompson, Kunlei Liu, Marcelo I. Guzman
Chemistry Faculty Publications
The quantification of atmospheric gases with small unmanned aerial systems (sUAS) is expanding the ability to safely perform environmental monitoring tasks and quickly evaluate the impact of technologies. In this work, a calibrated sUAS is used to quantify the emissions of ammonia (NH3) gas from the exit stack a 0.1 MWth pilot-scale carbon capture system (CCS) employing a 5 M monoethanolamine (MEA) solvent to scrub CO2 from coal combustion flue gas. A comparison of the results using the sUAS against the ion chromatography technique with the EPA CTM-027 method for the standard emission sampling of NH3 …
Near Simultaneous Laser Scanning Confocal And Atomic Force Microscopy (Conpokal) On Live Cells, Joree N. Sandin, Surya P. Aryal, Thomas E. Wilkop, Christopher I. Richards, Martha E. Grady
Near Simultaneous Laser Scanning Confocal And Atomic Force Microscopy (Conpokal) On Live Cells, Joree N. Sandin, Surya P. Aryal, Thomas E. Wilkop, Christopher I. Richards, Martha E. Grady
Physiology Faculty Publications
Techniques available for micro- and nano-scale mechanical characterization have exploded in the last few decades. From further development of the scanning and transmission electron microscope, to the invention of atomic force microscopy, and advances in fluorescent imaging, there have been substantial gains in technologies that enable the study of small materials. Conpokal is a portmanteau that combines confocal microscopy with atomic force microscopy (AFM), where a probe "pokes" the surface. Although each technique is extremely effective for the qualitative and/or quantitative image collection on their own, Conpokal provides the capability to test with blended fluorescence imaging and mechanical characterization. Designed …
University Of Kentucky Measurements Of Wind, Temperature, Pressure And Humidity In Support Of Lapse-Rate Using Multisite Fixed-Wing And Rotorcraft Unmanned Aerial Systems, Sean C. C. Bailey, Michael P. Sama, Caleb A. Canter, Luis Felipe Pampolini, Zachary S. Lippay, Travis J. Schuyler, Jonathan D. Hamilton, Sean B. Macphee, Isaac S. Rowe, Christopher D. Sanders, Virginia G. Smith, Christina N. Vezzi, Harrison M. Wight, Jesse B. Hoagg, Marcelo I. Guzman, Suzanne Weaver Smith
University Of Kentucky Measurements Of Wind, Temperature, Pressure And Humidity In Support Of Lapse-Rate Using Multisite Fixed-Wing And Rotorcraft Unmanned Aerial Systems, Sean C. C. Bailey, Michael P. Sama, Caleb A. Canter, Luis Felipe Pampolini, Zachary S. Lippay, Travis J. Schuyler, Jonathan D. Hamilton, Sean B. Macphee, Isaac S. Rowe, Christopher D. Sanders, Virginia G. Smith, Christina N. Vezzi, Harrison M. Wight, Jesse B. Hoagg, Marcelo I. Guzman, Suzanne Weaver Smith
Mechanical Engineering Faculty Publications
In July 2018, unmanned aerial systems (UASs) were deployed to measure the properties of the lower atmosphere within the San Luis Valley, an elevated valley in Colorado, USA, as part of the Lower Atmospheric Profiling Studies at Elevation – a Remotely-piloted Aircraft Team Experiment (LAPSE-RATE). Measurement objectives included detailing boundary layer transition, canyon cold-air drainage and convection initiation within the valley. Details of the contribution to LAPSE-RATE made by the University of Kentucky are provided here, which include measurements by seven different fixed-wing and rotorcraft UASs totaling over 178 flights with validated data. The data from these coordinated UAS flights …
Computational Studies Of Thermal Properties And Desalination Performance Of Low-Dimensional Materials, Yang Hong
Department of Chemistry: Dissertations, Theses, and Student Research
During the last 30 years, microelectronic devices have been continuously designed and developed with smaller size and yet more functionalities. Today, hundreds of millions of transistors and complementary metal-oxide-semiconductor cells can be designed and integrated on a single microchip through 3D packaging and chip stacking technology. A large amount of heat will be generated in a limited space during the operation of microchips. Moreover, there is a high possibility of hot spots due to non-uniform integrated circuit design patterns as some core parts of a microchip work harder than other memory parts. This issue becomes acute as stacked microchips get …
Non-Einstein Viscosity Phenomenon Of Acrylonitrile–Butadiene–Styrene Composites Containing Lignin–Polycaprolactone Particulates Highly Dispersed By High-Shear Stress, Sing-Hoon Kim, Kisuk Choi, Kyouk Ryeol Choi, Taesung Kim, Jonghwan Suhr, Kwang Jin Kim, Hyoung Jin Choi, Jae-Do Nam
Non-Einstein Viscosity Phenomenon Of Acrylonitrile–Butadiene–Styrene Composites Containing Lignin–Polycaprolactone Particulates Highly Dispersed By High-Shear Stress, Sing-Hoon Kim, Kisuk Choi, Kyouk Ryeol Choi, Taesung Kim, Jonghwan Suhr, Kwang Jin Kim, Hyoung Jin Choi, Jae-Do Nam
Mechanical Engineering Faculty Research
Lignin powder was modified via ring-opening polymerization of caprolactone to form a lignin–polycaprolactone (LPCL) particulate. The LPCL particulates were mixed with an acrylonitrile–butadiene–styrene (ABS) matrix at an extremely high rotational speed of up to 3000 rpm, which was achieved by a closed-loop screw mixer and in-line melt extruder. Using this high-shear extruding mixer, the LPCL particulate size was controlled in the range of 3395 nm (conventional twin-screw extrusion) down to 638 nm (high-shear mixer of 3000 rpm) by altering the mixing speed and time. The resulting LPCL/ABS composites clearly showed non-Einstein viscosity phenomena, exhibiting reduced viscosity (2130 Pa·s) compared to …
Peridynamic Modeling Of Ruptures In Biomembranes, Michael Taylor, Irep Gözen, Samir Patel, Aldo Jesorka, Katia Bertoldi
Peridynamic Modeling Of Ruptures In Biomembranes, Michael Taylor, Irep Gözen, Samir Patel, Aldo Jesorka, Katia Bertoldi
Mechanical Engineering
We simulate the formation of spontaneous ruptures in supported phospholipid double bilayer membranes, using peridynamic modeling. Experiments performed on spreading double bilayers typically show two distinct kinds of ruptures, floral and fractal, which form spontaneously in the distal (upper) bilayer at late stages of double bilayer formation on high energy substrates. It is, however, currently unresolved which factors govern the occurrence of either rupture type. Variations in the distance between the two bilayers, and the occurrence of interconnections (“pinning sites”) are suspected of contributing to the process. Our new simulations indicate that the pinned regions which form, presumably due to …
Preface-Jes Focus Issue On Electrolysis For Increased Renewable Energy Penetration, B. Pivovar, M. Carmo, K. Ayers, X. Zhang, J. O'Brien
Preface-Jes Focus Issue On Electrolysis For Increased Renewable Energy Penetration, B. Pivovar, M. Carmo, K. Ayers, X. Zhang, J. O'Brien
Mechanical & Aerospace Engineering Faculty Publications
(First paragraph) Today represents a particularly exciting time, as our planet’s energy system is undergoing major changes due to dramatically decreasing renewable energy prices and increasing societal concerns over greenhouse gas emissions, criteria pollutants (arsenic, mercury, NOx, particulate matter), and climate change. These factors are pushing society toward deep decarbonization of our energy system, perhaps the most challenging issue facing the planet today. Unfortunately, wind and solar energy, while both promising generation sources, come with intermittency challenges and have limitations in their abilities to impact industrial and transportation sector demands where fossil fuel energy carriers based on chemical bonds have …
Effect Of Spalled Particles Thermal Degradation On A Hypersonic Flow Field Environment, Raghava S. C. Davuluri, Huaibao Zhang, Alexandre Martin
Effect Of Spalled Particles Thermal Degradation On A Hypersonic Flow Field Environment, Raghava S. C. Davuluri, Huaibao Zhang, Alexandre Martin
Mechanical Engineering Faculty Publications
Two-way coupling is performed between a spallation code and a hypersonic aerothermodynamics CFD solver to evaluate the effect of spalled particles on the flow field. Time accurate solutions are computed in argon and air flow fields. A single particle simulations and multiple particles simulations are performed and studied. The results show that the carbon vapor released by spalled particles tend to change the composition of the flow field, particularly the upstream region of the shock.
Development Of A Two-Fluid Drag Law For Clustered Particles Using Direct Numerical Simulation And Validation Through Experiments, Ahmadreza Abbasi Baharanchi
Development Of A Two-Fluid Drag Law For Clustered Particles Using Direct Numerical Simulation And Validation Through Experiments, Ahmadreza Abbasi Baharanchi
FIU Electronic Theses and Dissertations
This dissertation focused on development and utilization of numerical and experimental approaches to improve the CFD modeling of fluidization flow of cohesive micron size particles. The specific objectives of this research were: (1) Developing a cluster prediction mechanism applicable to Two-Fluid Modeling (TFM) of gas-solid systems (2) Developing more accurate drag models for Two-Fluid Modeling (TFM) of gas-solid fluidization flow with the presence of cohesive interparticle forces (3) using the developed model to explore the improvement of accuracy of TFM in simulation of fluidization flow of cohesive powders (4) Understanding the causes and influential factor which led to improvements and …
Three-Dimensional Scaffolds Of Graphene, Carbon Nanotubes And Transition-Metal Oxides For Applications In Electronics, Sensors And Energy Storage, Gilbert N. Mbah
Three-Dimensional Scaffolds Of Graphene, Carbon Nanotubes And Transition-Metal Oxides For Applications In Electronics, Sensors And Energy Storage, Gilbert N. Mbah
Department of Chemistry: Dissertations, Theses, and Student Research
Electronics, sensors and energy storage devices are the new waves behind economic development, security and communication1. Engineering small sizes of electronic, sensors and energy storage devices is the hurdle limiting efficient, portable and vast applications of Nano-devices for economic, security and communication advancement2. Silicon the major material used in transistors has approached its limit to fabricated Nano-devices3. The discovery of free standing, one atomic layer thick and two-dimensional graphene sheets with high conductivity, inert, high specific surface area, stable and high tensile strength material in 2004 has shown capabilities to replaced silicon in electronics, …
Synthesis And Formation Mechanism Of Cuins2 Nanocrystals With A Tunable Phase, Chao Yu, Linlin Zhang, Long Tian, Dan Liu, Fanglin Chen, Cheng Wang
Synthesis And Formation Mechanism Of Cuins2 Nanocrystals With A Tunable Phase, Chao Yu, Linlin Zhang, Long Tian, Dan Liu, Fanglin Chen, Cheng Wang
Faculty Publications
Chalcopyrite CuInS2 (CIS) hierarchical structures composed of nanoflakes with a thickness of about 5 nm were synthesized by a facial solvothermal method. The thermodynamically metastable wurtzite phase CIS would be obtained by using InCl3 instead of In(NO3)3 as In precursor. The effects of the In precursor and the volume of concentrated HCl aqueous solution on the phases and morphologies of CIS nanocrystals have been systematically investigated. Experimental results indicated that the obtained phases of CIS nanocrystals were predominantly determined by precursor-induced intermediate products. The photocatalytic properties of chalcopyrite and wurtzite CIS in visible-light-driven degradation of …
Analysis Of A Chemical Model System Leading To Chiral Symmetry Breaking: Implications For The Evolution Of Homochirality, Brandy N. Morneau, Jaclyn M. Kubala, Carl Barratt, Pauline Schwartz
Analysis Of A Chemical Model System Leading To Chiral Symmetry Breaking: Implications For The Evolution Of Homochirality, Brandy N. Morneau, Jaclyn M. Kubala, Carl Barratt, Pauline Schwartz
Chemistry and Chemical Engineering Faculty Publications
Explaining the evolution of a predominantly homochiral environment on the early Earth remains an outstanding challenge in chemistry. We explore here the mathematical features of a simple chemical model system that simulates chiral symmetry breaking and amplification towards homochirality. The model simulates the reaction of a prochiral molecule to yield enantiomers via interaction with an achiral surface. Kinetically, the reactions and rate constants are chosen so as to treat the two enantiomeric forms symmetrically. The system, however, incorporates a mechanism whereby a random event might trigger chiral symmetry breaking and the formation of a dominant enantiomer; the non-linear dynamics of …
The Solar Thermal Decoupled Electrolysis Of Water Process: An Investigation Of The Electrochemistry In A Base, Jessica Guertin
The Solar Thermal Decoupled Electrolysis Of Water Process: An Investigation Of The Electrochemistry In A Base, Jessica Guertin
Symposium on Undergraduate Research and Creative Expression (SOURCE)
The solar research team at Valparaiso University is developing solar thermal chemical processes that will transform solar energy into economically viable and reusable energy forms. One subgroup is working on the Solar Thermal Decoupled Electrolysis of Water Process. In this multi-step process, the electrolysis of water to generate hydrogen occurs at room temperature outside of the solar reactor, and it is facilitated by the oxidation of magnetite (Fe3O4) to hematite (Fe2O3). The hematite is then pumped to the solar reactor where it is reduced back to magnetite at high temperatures with the liberation of oxygen. This cycle is then repeated. …
Analysis Of The Penney-Ante Game Using Difference Equations: Development Of An Optimal And A Mixed-Strategies Protocol, Carl Barratt, Pauline Schwartz
Analysis Of The Penney-Ante Game Using Difference Equations: Development Of An Optimal And A Mixed-Strategies Protocol, Carl Barratt, Pauline Schwartz
Chemistry and Chemical Engineering Faculty Publications
Penney-Ante is a well known two-player (Player I and Player II) game based on an information paradox. We present a new approach, using difference-equations, to analyzing the outcome for each player. One strategy yields a winning outcome of 75% for Player II, the player playing second. The approach also permits investigation of non-optimal strategies, and demonstrates how mixing of such strategies can be used to tune the winning edge of either player. We generalize the analysis to accommodate the possibility of a biased coin.
Kinetic Models Of The Prebiotic Replication Of Dsrna Under Thermal Cycling Conditions, Pauline Schwartz, Dante M. Lepore, Carl Barratt
Kinetic Models Of The Prebiotic Replication Of Dsrna Under Thermal Cycling Conditions, Pauline Schwartz, Dante M. Lepore, Carl Barratt
Chemistry and Chemical Engineering Faculty Publications
We present computational models for the replication of double stranded RNA (dsRNA) or related macromolecules under thermal cycling conditions that would reflect prebiotic (i.e. non-enzymatic) environments. Two models of the replication of dsRNA are represented as multi-step chemical systems. The objective of this investigation was to better understand the kinetic features of such chemical systems. It is shown that thermal cycling in a chemical system is advantageous (relative to a fixed temperature) if there are two competing reactions, one favored at high temperature and one favored at low temperature. For the prebiotic replication of dsRNA, a high temperature favors formation …
Computational Models Of Chemical Systems Inspired By Braess’ Paradox, Dante Lepore, Carl Barratt, Pauline Schwartz
Computational Models Of Chemical Systems Inspired By Braess’ Paradox, Dante Lepore, Carl Barratt, Pauline Schwartz
Chemistry and Chemical Engineering Faculty Publications
Systems chemistry is a new discipline which investigates the interactions within a network of chemical reactions. We have studied several computational models of chemical systems inspired by mathematical paradoxes and have found that even simple systems may behave in a counterintuitive, non-linear manner depending upon various conditions. In the present study, we modeled a set of reactions inspired by one such paradox, Braess’ paradox, an interesting phenomenon whereby the introduction of additional capacity (e.g. pathways) in some simple network systems can lead to an unexpected reduction in the overall flow rate of “traffic” through the system. We devised several chemical …
Diffuse-Charge Dynamics Of Ionic Liquids In Electrochemical Systems, Hui Zhao
Diffuse-Charge Dynamics Of Ionic Liquids In Electrochemical Systems, Hui Zhao
Mechanical Engineering Faculty Research
We employ a continuum theory of solvent-free ionic liquids accounting for both short-range electrostatic correlations and steric effects (finite ion size) [Bazant et al., Phys. Rev. Lett. 106, 046102 (2011)] to study the response of a model microelectrochemical cell to a step voltage. The model problem consists of a 1-1 symmetric ionic liquid between two parallel blocking electrodes, neglecting any transverse transport phenomena. Matched asymptotic expansions in the limit of thin double layers are applied to analyze the resulting one-dimensional equations and study the overall charge-time relation in the weakly nonlinear regime. One important conclusion is that our …
Systems Chemistry And Parrondo’S Paradox: Computational Models Of Thermal Cycling, Daniel C. Osipovitch, Carl Barratt, Pauline M. Schwartz
Systems Chemistry And Parrondo’S Paradox: Computational Models Of Thermal Cycling, Daniel C. Osipovitch, Carl Barratt, Pauline M. Schwartz
Chemistry and Chemical Engineering Faculty Publications
A mathematical concept known as Parrondo’s paradox motivated the development of several novel computational models of chemical systems in which thermal cycling was explored. In these kinetics systems we compared the rates of formation of product under cycling temperature and steady-sate conditions. We found that a greater concentration of product was predicted under oscillating temperature conditions. Our computational models of thermal cycling suggest new applications in chemical and chemical engineering systems.
Localised Galvanic Corrosion Processes In Thermal Spray Coated/Cast Aluminium Alloy Systems, David Culliton, Tony Betts, David Kennedy
Localised Galvanic Corrosion Processes In Thermal Spray Coated/Cast Aluminium Alloy Systems, David Culliton, Tony Betts, David Kennedy
Conference Papers
Cast Aluminium Alloys, because of the propensity of aluminium to react with impurities and alloying elements, are prone to developing IM impurities during the solidification process. These IM phases can act, in some fluids, as initiation sites for localised corrosion processes, resulting in degradation phenomena, such as pitting. Whilst Thermal Spray coatings can improve the wear resistance of Cast Aluminium Alloys, their corrosion performance may be hampered by the presence of through porosity within the coating.
The present work details some preliminary studies of the localised corrosion processes occurring at the interface area between a Thermal Spray coating and a …
Three-Dimensional Modeling Of The Plasma Arc In Arc Welding, Gu Xu, J. Hu, Hai-Lung Tsai
Three-Dimensional Modeling Of The Plasma Arc In Arc Welding, Gu Xu, J. Hu, Hai-Lung Tsai
Mechanical and Aerospace Engineering Faculty Research & Creative Works
Most previous three-dimensional modeling on gas tungsten arc welding (GTAW) and gas metal arc welding (GMAW) focuses on the weld pool dynamics and assumes the two-dimensional axisymmetric Gaussian distributions for plasma arc pressure and heat flux. In this article, a three-dimensional plasma arc model is developed, and the distributions of velocity, pressure, temperature, current density, and magnetic field of the plasma arc are calculated by solving the conservation equations of mass, momentum, and energy, as well as part of the Maxwell's equations. This three-dimensional model can be used to study the nonaxisymmetric plasma arc caused by external perturbations such as …