Mechanical Engineering Commons^™

Effects Of Concentration And Temperature On The Coupled Heat And Mass Transport In Liquid Mixtures, Yaşar Demirel, Stanley I. Sandler

Papers in Thermal Mechanics

Using published experimental data on the thermal conductivity, mutual diffusivity, and heats of transport, the degree of coupling between heat and mass flows has been calculated for binary and ternary nonideal liquid mixtures. The binary mixtures consist of two types: the first is six systems of six-to-eight-carbon straight and branched chain alkanes in chloroform and in carbon tetrachloride; and the second is mixtures of carbon tetrachloride with benzene, toluene, 2-propanone, n-hexane, and 11-octane. The ternary mixture considered is toluene-chlorobenzene-bromobenzene. The published data are available at 35°C, 30°C, and 35°C and ambient pressure. Using the linear nonequilibi-ium thermodynainics (LNET) and the …

Linear-Nonequilibrium Thermodynamics Theory For Coupled Heat And Mass Transport, Yaşar Demirel, Stanley I. Sandler

Yaşar Demirel Publications

Linear-nonequilibrium thermodynamics (LNET) has been used to express the entropy generation and dissipation functions representing the true forces and flows for heat and mass transport in a multicomponent fluid. These forces and flows are introduced into the phenomenological equations to formulate the coupling phenomenon between heat and mass flows. The degree of the coupling is also discussed. In the literature such coupling has been formulated incompletely and sometimes in a confusing manner. The reason for this is the lack of a proper combination of LNET theory with the phenomenological theory. The LNET theory involves identifying the conjugated flows and forces …

Mathematical Modeling For Fabricating A Microstructure With A Pre-Specified Geometry Using Laser -Induced Chemical Vapor Deposition, Chaoyang Zhang

Doctoral Dissertations

Laser-induced chemical vapor deposition (LCVD) is an emerging new technique with many practical applications. To optimize the system for fabricating a microstructure with a pre-specified geometry in pyrolytic LCVD, a three-dimensional mathematical model is developed for predicting temperature distributions and laser dwell times across the substrate scanned by the laser beam. A microstructure is fabricated layer by layer, and for each layer the laser beam moves from one pixel to the next. The complicated correlations among temperature distribution, deposit growth rate, and laser dwell time are investigated. A purely heterogeneous reaction is assumed and any gas-phase transport is ignored.

A …