Structural Materials Commons^™

Highly Vented Truss Wall Honeycomb Structures, David J. Sypeck

Publications

A vented honeycomb structure with a plurality of honey­comb cells arranged in a hierarchical order and having a plurality of truss walls, each truss wall including a plurality of members. The vented honeycomb structure is fabricated by joining a plurality of sheets of trusses using any one of an expansion, a corrugation, and a slotting process. Fabri­cation can also occur by deposition, casting, additive, extru­sion, or aligning and joining methods. The honeycomb cells, truss walls, truss wall openings, and truss wall members can be functionally graded.

3d Printing – An Insider’S Perspective, Siddharth Sah

The STEAM Journal

The 3D printing market globally is still at its infancy, - or some might argue that there isn’t really a market yet. The knowledge of 3D printing design is still largely limited to engineering design – not product design. At MakeWhale, we are constantly pushing the boundaries of the application of 3D printing technology to consumer products resulting in a beautiful mix of technology and art.

Characterization And Modeling Of Asphalt Concrete For Dynamic Properties And Performances, A S M A. Rahman

Civil Engineering ETDs

The recently developed mechanistic-empirical pavement design guide (MEPDG, also known as Pavement M-E design method) uses the nationally calibrated, binder viscosity-based dynamic modulus predictive model for the design and analysis of asphalt pavements. In this study, this model is assessed for its appropriateness for asphalt-aggregate mixtures typically used in New Mexico. In essence, this study investigates the predictability issue of complex modulus of New Mexico mixes. A total of 54 Superpave mixes with different aggregate gradations, air voids, and binder grades were collected from the mixing plants and from the pavement construction sites. The loose asphalt mixtures were then compacted, …

Modeling Of Dislocation Channel Formation And Evolution In Irradiated Metals, Peter James Doyle

Masters Theses

Defect-free dislocation channel formation has been reported to promote plastic instability during tensile testing via localized plastic flow, leading to a distinct loss of ductility and strain hardening in many low-temperature irradiated materials. In order to study the underlying mechanisms governing dislocation channel width and formation, the channel formation process is modeled via a simple stochastic dislocation-jog process dependent upon grain size, defect cluster density, and defect size. Dislocations traverse a field of defect clusters and jog stochastically upon defect interaction, forming channels of low defect-density. Based upon prior molecular dynamics (MD) simulations and in-situ experimental transmission electron microscopy (TEM) …

A Comparison Study Of Composite Laminated Plates With Holes Under Tension, Joun S. Kim

Master's Theses

A Comparison Study of Composite Laminated Plates with Holes under Tension

A study was conducted to quantify the accuracy of numerical approximations to deem sufficiency in validating structural composite design, thus minimizing, or even eliminating the need for experimental test. Error values for stress and strain were compared between Finite Element Analysis (FEA) and analytical (Classical Laminated Plate Theory), and FEA and experimental tensile test for two composite plate designs under tension: a cross-ply composite plate design of [(0/90)4]s, and a quasi-isotropic layup design of [02/+45/-45/902]s, each with a single, centered hole of 1/8” diameter, and 1/4" diameter (four sets …

Thermodynamic Investigation Of Yttria-Stabilized Zirconia (Ysz) System, Mohammad Asadikiya

FIU Electronic Theses and Dissertations

The yttria-stabilized zirconia (YSZ) system has been extensively studied because of its critical applications, like solid oxide fuel cells (SOFCs), oxygen sensors, and jet engines. However, there are still important questions that need to be answered and significant thermodynamic information that needs to be provided for this system. There is no predictive tool for the ionic conductivity of the cubic-YSZ (c-YSZ), as an electrolyte in SOFCs. In addition, no quantitative diagram is available regarding the oxygen ion mobility in c-YSZ, which is highly effective on its ionic conductivity. Moreover, there is no applicable phase stability diagram for the nano-YSZ, which …

Computational Studies Of Structure–Function Relationships Of Supported And Unsupported Metal Nanoclusters, Hongbo Shi

Doctoral Dissertations

Fuel cells have been demonstrated to be promising power generation devices to address the current global energy and environmental challenges. One of the many barriers to commercialization is the cost of precious catalysts needed to achieve sufficient power output. Platinum-based materials play an important role as electrocatalysts in energy conversion technologies. In order to improve catalytic efficiency and facilitate rational design and development of new catalysts, structure–function relationships that underpin catalytic activity must be understood at a fundamental level. First, we present a systematic analysis of CO adsorption on Pt nanoclusters in the 0.2-1.5 nm size range with the aim …

Fabrication Of Functional Nano-Structured Materials And Devices Using Supercritical Fluids, Shengkai Li

Doctoral Dissertations

Nano-structured materials possess unconventional properties and enable miniaturization of devices. However, fabrications of such materials and devices are challenging and in many cases cumbersome, and development of nanofabrication techniques are essential to realizing novel designs and commercializing scientific ideas. Supercritical fluids possess a unique combination of gas-like diffusion properties and liquid-like dissolution power, and are suitable reaction media for fabricating materials at the nanometer scale. This dissertation focuses on developing supercritical fluids-related techniques for fast and large-scale fabrication of novel composite materials and devices. Using supercritical fluid deposition (SFD) technique, cobalt thin films were deposited on a variety of substrates, …

3d Printing Of Functional Materials: Surface Technology And Structural Optimization, Dongxing Zhang

Electronic Thesis and Dissertation Repository

There has been a surge in interest of 3D printing technology in the recent 5 years with respect to the equipment and materials, because this technology allows one to create sophisticated and customized parts in a manner that is more efficient regarding both material and time consumption. However, 3D printing has not yet become a mainstream technology within the established manufacturing routes. One primary factor accounting for this slow progress is the lack of a broad variety of 3D printable materials, resulting in limited functions of 3D printed parts.

To bridge this gap, I present an integrated strategy to fabricate …

Comparison Of Pm-Hip To Cast Alloy 625 For Nuclear Applications, Alexander L. Bullens, Keyou Mao, Janelle P. Wharry, Esteban Bautista

The Summer Undergraduate Research Fellowship (SURF) Symposium

PM-HIP, or Powder Metallurgy and Hot Isostatic Pressing, metals have been a low cost alternative to forged and cast structural metals within various industries. The nuclear industry has recently developed interest in PM-HIP alloys, but further research needs to be done to quantify their mechanical properties and characterize the microstructure. Specifically, we must understand the mechanical and microstructural evolution of PM-HIP materials after long-term operation at the elevated temperatures that PM-HIP components will experience in service. We focus on Ni-base alloy Inconel 625, and compare the PM-HIP version to the cast version. Our methodology consists of annealing samples to various …

Cylindrical Shell Based Phase Transforming Cellular Materials: Designing A Recoverable Energy Dissipating Material, Gordon F. Jarrold, David Restrepo, Nilesh Mankame, Pablo Zavattieri

The Summer Undergraduate Research Fellowship (SURF) Symposium

Energy dissipating materials are used in a variety of impact events to protect more important parts of a system; one example of this is a football player’s helmet protecting a brain. A major drawback to classic energy dissipating materials however is that they dissipate energy through plastic deformation, meaning that after a single use, permanent deformations will prevent the material from being reusable to the same capacity as initially. We have designed a 1D cellular material in which geometric phase transformations in cylindrical shell elements are the primary energy dissipating mechanism, allowing for recoverability after use while keeping high energy …

Core-Shell Copper And Nickel Nanofoam: Uniform Electroplating And Properties, Hassan Zbib, David Bahr

The Summer Undergraduate Research Fellowship (SURF) Symposium

Characterizing materials on the nanoscale is a key factor to enhance nanotechnology in diverse applications, ranging from electronics to energy fields. However, controlling the structure of the material at the nanoscale or mimicking the nanoscale features of a structure that already exists requires linking processing conditions to the nanostructure. This work focuses on solids that show porous patterns at the nano-micro scale; these are often called cellular solids and classified into two categories: honeycombs and foams. This study focuses on nanofoams; with ligament dimensions in the sub-micron scale. Electrospinning has been developed to produce nanofoam structures of polymers with controlled …

Viscoelastic Analysis And Fatigue Characterization Of Bituminous Materials In Two Length Scales Under The Influence Of Aging, Santosh Reddy Kommidi

Department of Civil and Environmental Engineering: Dissertations, Theses, and Student Research

Fatigue cracking in asphalt concrete (AC) is of immense importance to pavement design and analysis because it is one of the most important forms of distress that can lead to structural failure in pavement. Once started, these types of cracks can be combined with other environmental factors leading to detrimental effects such as faster rates of pavement deterioration and shortened pavement life and functionality.

Currently AASHTO TP101, also known as linear amplitude sweep (LAS) specification, is being widely used to evaluate the ability of an asphalt binder to resist fatigue. The LAS method, although mechanistic in its approach, has certain …

First-Principles Study Of Point Defect Behavior At Interfaces And In-Plane Strain Fields, Jianqi Xi

Doctoral Dissertations

Interfaces in solid materials are the so-called boundaries, separating crystals with the same structure and chemistry but different orientations, e.g. grain boundaries (GBs), different stacking sequences, e.g. stacking faults (SFs), or crystals with different structures and/or chemistries as well as orientations, e.g. the interface between substrate and thin film. In this study, first-principles calculations are used to investigate the defect behavior at different interfaces and in-plane strain fields, such as stacking fault (SF) in silicon carbide (SiC), in-plane strain field near interfaces in potassium tantalate (KTaO₃), and grain boundary in ceria (CeO₂).

Results show that the …

Analysis And Modeling Of The Growth Of Intermetallic Compounds In Aluminum–Steel Joints, Gang Zhang, Manjiao Chen, Yu Shi, Jiankang Huang, Fuqian Yang

Chemical and Materials Engineering Faculty Publications

In this work, we experimentally and numerically studied the microstructures and growth of intermetallic compounds (IMCs) formed in Al–Fe (aluminum–steel) joints welded by a pulsed double electrode gas metal arc welding (DE-GMAW)-brazing method. The IMCs consist of Fe₂Al₅ and FeAl₃, with Fe₂Al₅ being the main compound in the joints. The thickness of an IMC layer increases with an increase of the welding current (heat input) into the base metal. EBSD measurement suggests that the preferred crystal orientation of the Fe₂Al₅ IMC likely provides the necessary path for Al atoms …

Mitigation And Evaluation Of Alkali-Silica Reaction (Asr) And Freezing And Thawing In Concrete Transportation Structures, Richard Albert Deschenes Jr.

Graduate Theses and Dissertations

An evaluation of alkali-silica reaction (ASR) and freezing and thawing (F/T) in concrete transportation structures is presented along with mitigation methods for slowing the rate of deterioration in concrete. A combination of field and laboratory testing confirms ASR deterioration is exacerbated by exposure to F/T. Laboratory testing indicates an aggregate previously deemed inert to ASR, caused ASR deterioration in several concrete pavement and transportation structures. Existing standard test methods deem this aggregate safe for use in concrete. A modified test method shows the concrete can deteriorate rapidly when subjected to cycles of conditions promoting ASR and F/T. Several structures containing …

Optimization Of Concrete Mixtures For Use In Structural Elements, Waleed Almutairi

Graduate Theses and Dissertations

Portland cement is an essential ingredient in concrete. The use of cement is to enhance the strength as well as other hardened properties of concrete mixtures. Determining the accurate amount of cement is important because the required strength may not be achieved if not enough cement is used. By contrast, when using too much cement, concrete cracking may occur that leads to reducing durability. Researchers at the University of Arkansas (UA) have shown that many bridge decks achieve their 28 day design strength of 4000 psi by 7 days of age. Bridge decks having high strength may experience cracking, which …

Deformation Behavior Of Al/A-Si Core-Shell Nanostructures, Robert Andrew Fleming

Graduate Theses and Dissertations

Al/a-Si core-shell nanostructures (CSNs), consisting of a hemispherical Al core surrounded by a hard shell of a-Si, have been shown to display unusual mechanical behavior in response to compression loading. Most notably, these nanostructures exhibit substantial deformation recovery, even when loaded much beyond the elastic limit. Nanoindentation measurements revealed a unique mechanical response characterized by discontinuous signatures in the load-displacement data. In conjunction with the indentation signatures, nearly complete deformation recovery is observed. This behavior is attributed to dislocation nucleation and annihilation events enabled by the 3-dimensional confinement of the Al core. As the core confinement is reduced, either through …

The Mechanism Of Radiation-Induced Nanocluster Evolution In Oxide Dispersion Strengthened And Ferritic-Martensitic Alloys, Matthew John Swenson

Boise State University Theses and Dissertations

The objective of this study is to evaluate the mechanism of irradiation-induced nanoparticle evolution in a model Fe-9%Cr oxide dispersion strengthened steel and commercial ferritic-martensitic alloys HCM12A and HT9. Each alloy is irradiated with Fe²⁺ ions, protons, or neutrons to doses ranging from 1-100 displacements per atoms at 500°C. The morphology of nanoclusters are characterized using atom probe tomography. The evolution of clusters in each alloy are notably different with each irradiating particle, and the competing effects of ballistic dissolution and radiation-enhanced, diffusion-driven growth are attributed to the respective differences in cluster evolution. A phase evolution model, originally theorized …

Development Of High Early-Strength Concrete For Accelerated Bridge Construction Closure Pour Connections, Stephanie Castine

Masters Theses

Accelerated bridge construction (ABC) has become a popular alternative to using traditional construction techniques in new bridge construction and existing bridge deck replacement because of the reduction of time spent in field activities. A key feature of bridges built using ABC techniques is the extensive use of prefabricated components. Prefabricated components are joined in the field using small volume closure pours involving high performance materials (steel and concrete) to ensure adequate transfer of forces between components. To date, the materials developed for closure pours have been based on proprietary components, so a need has arisen for development of mixes that …

Synthesis,Structure And Properties Of Ruthenium Polypyridyl Metalloligand Based Metal-Organic Frameworks, Mamatha Polapally

Masters Theses & Specialist Projects

Metal-organic frameworks (MOFs) have been extensively studied because of their amazing applications in gas storage, purification, photocatalysis, chemical sensing, and imaging techniques. Ruthenium polypyridyl complexes have been broadly considered as photosensitizers for the conversion of solar energy and photoelectronic materials. With this aspect, we have synthesized three new ruthenium polypyridyl based MOFs ([Ru(H2bpc)Cu(bpc)(Hbpc)2(H2O)]·5H2O (1), [Ru(H2bpc)(Fe(bpc)(Hbpc)2(H2O)2]·6H2O (2) and [Ru(H2bpc)Ni(bpc)(Hbpc)2(H2O)2]·6H2O (3)) from ruthenium(III) chloride, bpc (2,2’- bipyridine-4,4’-dicarboxylic acid) ligand, and 3d M(II) metal ions (M(II)= Cu(II), Fe(II), Ni(II)). These MOFs were synthesized under hydro or solvothermal conditions by using water, ethanol or methanol as solvents. The crystal structures of the new compounds …

A Study In The Use Of Elastic Materials In Expandable Containment Units, Andrew J. Eisenman, Joby Anthony Iii, David Satagaj

Montview Journal of Research & Scholarship

The rigidity of materials in conjunction with the aspect of elasticity has been a concern of modern technologies and construction in recent centuries because of the advantages that expandable storage would bring to the fields of containment units with respect to population growth and space exploration. The world population is currently growing at an exponential rate, and as our population grows, the more important it will become to have containment units that can both contain large volumes of material as well as minuscule amounts of material without wasting space. In order accomplish this, we will need a new type of …

Characterization Of Slm Printed 316l Stainless Steel And Investigation Of Microlattice Geometry, Finley H. Marbury

Materials Engineering

The goal of this project was firstly to characterize Cal Poly’s SLM printed 316L stainless steel. SEM analysis showed Cal Poly’s as-printed 316L material to have a cellular dendritic microstructure containing mostly austenite and a small amount of δ-ferrite. After being heat treated to eliminate warp, its yeild and ultimate tensile strength were on par with the literature, however higher modulus and lower elongation were observed. XRD analysis confirmed residual stresses in the material, and that grains are preferentially oriented in both heat treated and non heat treated samples. The amount of porosity in the material was found to be …

Invariant-Based Method For Improving Efficiency Of Mechanical Testing In Aerospace Certification Of Carbon Fiber-Epoxy Composites, Alyssa Rina Gruezo, Erika Gabrielle Hansen

Materials Engineering

The current challenge with qualification of carbon fiber composites in the aerospace industry would be the low efficiency of testing hundreds of samples. The Trace Theory strives to streamline the qualification process by utilizing a material’s Trace to predict properties of composites using Excel programs and basis data. To test this theory, predicted properties from the program, QuickLam, were compared to experimental data. Unidirectional 0° (T1), unidirectional 90° (T2), quasi-isotropic (T3), and hard quasi-isotropic (T4) laminates were made using HexTowR carbon fiber and TC250 resin provided by TenCate Advanced Composites. Tensile and compression tests were done according to ASTM D3039 …

Development Of Low Cost Braze Alloys For Aerospace Applications, Alyssa M. Elliott, Sandy Babich, Blake Whitmee

Materials Engineering

Non-precious metal braze alloys can help lower the cost of brazing, which is a commonly-used joining process in the aerospace industry. A-286, a stainless steel superalloy, and Inconel© 718, a nickel-based superalloy, are both commonly used alloys at Aerojet Rocketdyne. Both alloys were brazed into butt joints using nickel-based braze alloys: AMS 4776, 4777, and 4778. The brazed samples were machined into a modified version of the ASTM E8 subsize specimen samples and tensile tested to compare the strength and calculated elongation of the brazed samples to the base metals’ properties. All of the brazed samples fractured at the joint, …

Bear Minimum: Ultralight Composite Bear Canister, Rama B. Adajian, Adam C. Eisenbarth

Mechanical Engineering

The ultralight backpacking community needs a strong, easy to use, safe bear canister that is lighter than current market products for trekking in the backcountry. A full design of the lid for the bear canister is to be completed. This includes the locking mechanism to ensure it is bear proof, the interface between the lid and the canister, and the structure of the lid so it passes the strength and weight specifications. The lid, along with the already designed canister body, is to be manufactured with formal documentation. The lid will initially be tested separately and then with the canister …

Investigating The Classical And Non-Classical Mechanical Properties Of Gan Nanowires, Mohammad Reza Zamani Kouhpanji

Electrical and Computer Engineering ETDs

Study and prediction of classical and non-classical mechanical properties of GaN is crucial due to the potential application of GaN nanowires (NWs) in piezoelectric, probe-based nanometrology, and nanolithography areas. GaN is mainly grown on sapphire substrates whose lattice constant and thermal expansion coefficient are significantly different from GaN. These discrepancies cause mechanical defects and high residual stresses and strains in GaN, which reduce its quantum efficiency.

Specifically, for nanoscale applications, the mechanical properties of materials differ significantly compared to the bulk properties due to size-effects. Therefore, it is essential to investigate the mechanical properties of GaN NWs using the non-classical …

Study Of Knowledge-Based System (Kbs) And Decision Making Methodologies In Materials Selection For Lightweight Aircraft Metallic Structures, Pashupati R. Adhikari, Reza Mirshams

Journal of Applied Science & Engineering Technology

This paper presents an overview of knowledge-based system (KBS) in the context of decision making methodologies used in materials selection for the design of light weight aircraft metallic structures. Overall aircraft weight reduction means substantially less fuel consumption and better efficiency. Part of the solution to this problem is to find a way to reduce overall weight of metallic structures in the aircraft. Two distinct multiple criteria decision making (MCDM) methodologies are presented with examples featuring a set of short-listed materials suitable in the design of the structures. Pre-defined constraint values, mainly mechanical properties, are employed as relevant attributes satisfying …

Experimental And Computational Investigation Of High Entropy Alloys For Elevated-Temperature Applications, Haoyan Diao

Doctoral Dissertations

To create and design novel structural materials with enhanced creep-resistance, fundamental studies have been conducted on high-entropy alloys (HEAs), using (1) thermodynamic calculations, (2) mechanical tests, (3) neutron diffraction, (4) characterization techniques, and (5) crystal-plasticity finite-element modeling (CPFEM), to explore future candidates for next-generation power plants.

All the constituent binary and ternary systems of the Al-Cr-Cu-Fe-Mn-Ni and Al-Co-Cr- Fe-Ni systems were thermodynamically modeled within the whole composition range. Comparisons between the calculated phase diagrams and literature data are in good agreement. The Al_xCrCuFeMnNi HEAs have disordered [face-centered-cubic (FCC) + body-centered-cubic (BCC)] crystal structures. Excessive alloying of the Al …

Effect Of Chain Rigidity On Network Architecture And Deformation Behavior Of Glassy Polymer Networks, Kyler Reser Knowles

Dissertations

Processing carbon fiber composite laminates creates molecular-level strains in the thermoset matrix upon curing and cooling which can lead to failures such as geometry deformations, micro-cracking, and other issues. It is known strain creation is attributed to the significant volume and physical state changes undergone by the polymer matrix throughout the curing process, though storage and relaxation of cure-induced strains remain poorly understood. This dissertation establishes two approaches to address the issue. The first establishes testing methods to simultaneously measure key volumetric properties of a carbon fiber composite laminate and its polymer matrix. The second approach considers the rigidity of …