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Full-Text Articles in Engineering Science and Materials

Microstructure And Mechanical Properties Of Nanofiller Reinforced Tantalum-Niobium Carbide Formed By Spark Plasma Sintering, Christopher Charles Rudolf May 2016

Microstructure And Mechanical Properties Of Nanofiller Reinforced Tantalum-Niobium Carbide Formed By Spark Plasma Sintering, Christopher Charles Rudolf

FIU Electronic Theses and Dissertations

Ultra high temperature ceramics (UHTC) are candidate materials for high temperature applications such as leading edges for hypersonic flight vehicles, thermal protection systems for spacecraft, and rocket nozzle throat inserts due to their extremely high melting points. Tantalum and Niobium Carbide (TaC and NbC), with melting points of 3950°C and 3600°C, respectively, have high resistivity to chemical attack, making them ideal candidates for the harsh environments UHTCs are to be used in. The major setbacks to the implementation of UHTC materials for these applications are the difficulty in consolidating to full density as well as their low fracture toughness. In …


Electrochemical H2O2Sensor Based On The Co-Immobilization Of Phosphmolybdic Acid And Graphene On Pedot Film Electrode With Nafion, Hao-Xian Zhou, Jun-Ming Zhang, Zhi-Yu Qu, Pan-Yu Zhang, You-Jun Fan Feb 2016

Electrochemical H2O2Sensor Based On The Co-Immobilization Of Phosphmolybdic Acid And Graphene On Pedot Film Electrode With Nafion, Hao-Xian Zhou, Jun-Ming Zhang, Zhi-Yu Qu, Pan-Yu Zhang, You-Jun Fan

Journal of Electrochemistry

With a glassy carbon electrode (GCE) as the substrate, the poly(3,4-ethylenedioxythiophene) (PEDOT) film electrode was prepared through the electrochemical polymerization method, then a novel non-enzymatic electrochemical H2O2 sensor was fabricated by co-immobilizing phosphomolybdic acid and graphene with Nafion on the PEDOT/GCE electrode. The modified electrodes were characterized by scanning electron microscopy (SEM), while the responsive properties of the sensor to H2O2 were investigated by cyclic voltammetry and chronoamperometry. The results demonstrated that, under the optimized conditions, the sensor exhibited good electrocatalytic performance for H2O2 reduction. The current response of the sensor …


Electrochemical Syntheses Of Graphene And Its Composites, Bo Zhao, Li Jiang, Ming-Hui Yuen, Xian-Zhu Fu, Rong Sun, Ching-Ping Wong Feb 2016

Electrochemical Syntheses Of Graphene And Its Composites, Bo Zhao, Li Jiang, Ming-Hui Yuen, Xian-Zhu Fu, Rong Sun, Ching-Ping Wong

Journal of Electrochemistry

Graphene is a kind of ideal two-dimensional flat carbon nanomaterials which have unique chemical and physical properties. The attractive potential applications must be based on the high quality mass production of graphene. However, it remains a huge challenge.An electrochemical approach is a fast, environmental friendly and easy-operating method. single- or multi-layered graphene flakes can easily be produced in short periods of time. In this review, the structure, properties and preparation methods of graphene are first introduced. Accordingly, the electrochemical approaches used for the productions of graphene flakes,graphene/inorganic nanocomposites, graphene/polymer composites and graphene analogues are highlighted. Finally, challenges and opportunities are …


Liquid-Phase Exfoliation Of Two-Dimensional Graphite For Ink-Jet Printing, Monica Michel Jan 2016

Liquid-Phase Exfoliation Of Two-Dimensional Graphite For Ink-Jet Printing, Monica Michel

Open Access Theses & Dissertations

Over the last decade, the study of two-dimensional (2D) materials has seen an incredible growth due to their unique thermal, mechanical and electronic properties. Solution phase manufacturing offers a way in which they can be produced at large scale by creating dispersions from the exfoliated material. Once created, different options for assembling devices exist. One technique for large scale manufacturing of materials in this form is ink-jet printing, which is a form of additive manufacturing that has proven to be attractive for the printed electronics industry. One challenge that ink-jet printing still faces is the shortage of inks with appropriate …