Engineering Science and Materials Commons^™

Cmas/Volcanic Ash Infiltration Performance Of Yttria Rich-Zirconia Thermal Barrier Coatings Produced By Electron Beam Physical Vapor Deposition, Juan Jose Gomez Chavez

Open Access Theses & Dissertations

For many years the use of thermal barrier coatings (TBC) in gas turbine engines has allowed a significant increase in engine operating temperatures which are above the Ni-based super alloys' melting point. The base material for TBCs is the state of the art 7 wt % yttria stabilized zirconia (YSZ) which provides the thermal protection. Current industry demands for increased engine efficiency has pushed TBCs to the limits where significant technological constrains have been identified. One of the main ones represents the high temperature corrosion of the TBC material due to the ingestion of silicate based airborne particles commonly referred …

Understanding Of Deformation And Fracture Behavior In Next Generation High Strength-High Ductility Steels, Venkata Sai Yashwanth Injeti

Open Access Theses & Dissertations

The industrial demand for low density high strength steels without compromising on ductility in is endless. In this regards, grain refinement and austenitic stability considered to the practical approach in order to meet the needs. The concept of phase reversion involving sever cold deformation of metastable austenite to generate strain-induced martensite, followed by time-temperature annealing sequence, was used to obtain varying grain size from nanograined/ultrafine-grained (NG/UFG) to coarse-grained (CG) regime. This concept was used to obtain "high strength-high ductility" combination in nano/ultrafine-grained (NG/UFG) austenite stainless steel. Using this concept, the objective of the study here is to elucidate the dependence …

Tailoring The Mechanical And Optical Properties Of Silicon-Niobium-Nitride Composite Coatings, Cristian Orozco

Open Access Theses & Dissertations

Nitride nanocomposite thin films have generated significant attention as a result of their robust mechanical properties, excellent triobology, and good chemical (corrosion) stability. Due to their excellent hardness and high wear resistance NbN coatings have found use in a wide variety of applications such as the coating of cutting tools and to strengthen the surface mechanical properties of superconducting cavities. The mechanical properties of NbN can be further improved through mixing with Si3N4, leading to the formation of a nanocomposite structure. NbN-Si3N4 nanocomposite coatings have been actively studied due to their high hardness, high elastic modulus, and high resistance to …

Investigating Using Titanium Zirconium Molybdenum For Additively Manufacturing Aerospace Components, Justin Hunter Vanhoose

Open Access Theses & Dissertations

Mankind throughout history has possessed an innate characteristic to explore, migrating to new frontiers.The requirement for this travel is most broadly associated with the need to pursue more resources. Rockets have been used as a means of weapons since the Sung Dynasty in the thirteenth empire and have now been integrated for travel/transport. The sophistication of rocketry and propulsion has reached a level to where it is plausible that mankind will be a multi-planetary species. The space industry has grown significantly with the advancement of the sophistication of these rocket technologies. However, a specific challenge to overcome in the space …

A Method For Iron Determination During Copper Electrometallurgy And Its Application To The Calculation Of Current Efficiency, Daniel Pedro Cruz

Open Access Theses & Dissertations

With the objective of developing statistical models that describe iron kinetics under typical copper electrolytes as well as its effects on current efficiency and influence in cathodic and anodic behavior, a detailed electrochemical analysis is done in this work as a contribution to implement hydrometallurgical processes in the refining or winning process to produce high purity copper.

This Thesis evaluates the oxidation-reduction potential (ORP) of the Fe3+/Fe2+ couple in the H2SO4-Fe2(SO4)3-FeSO4-H2O and H2SO4-CuSO4-Fe2(SO4)3-FeSO4-H2O systems, with addition of different copper concentrations and temperatures up to 70°, typically employed in the industry. This study further validates and expands a thermodynamic expression developed …

Tailoring Physical Properties Of Shape Memory Polymers For Fdm-Type Additive Manufacturing, Paulina Aileen Quinonez

Open Access Theses & Dissertations

Shape memory polymers (SMPs) have found applicability in biomedical settings as well as other uses that can take advantage of objects that can change shape upon exposure to stimulus. Integrating polymers with shape memory characteristics into additive manufacturing technologies such as fused deposition modeling (FDMâ?¢) can increase the number of applications this manufacturing platform can be utilized. Currently, polyurethane and polylactic acid (PLA) are two FDMâ?¢-compatible materials that possess shape memory properties. On their own these materials do not have tunable shape memory properties, namely shape recovery and shape fixation. The work presented here entails the development and characterization of …

Processing, Structure And Mechanical Behavior Of Advanced Engineering Steels, Bing Yu

Open Access Theses & Dissertations

The concept of low lattice misfit and high-density of nanoscale precipitates obtained through solution treatment was adopted to obtain ultrahigh strength maraging steel without compromising elongation. An "ultrahigh strength-high toughness" combination was successfully obtained in 19Ni3Mo1.5Ti maraging steel with ultimate strength of ~1858 MPa and static toughness of ~110 MJ·m-3. Maraging steel had extremely high density (2.3Ã?1024 m-3) of nanoscale precipitates with minimum lattice misfit of less than 1% at the solutionization temperature of 820 oC. Two kinds of nanoscale precipitates, namely, η-Ni3(Ti,Mo) and B2-Ni(Mo,Fe) contributed to ultrahigh strength. The size of nanoscale precipitates governed the movement of dislocations, cutting …

Direct Write 3d Printing Of Functional Ceramics, Jorge Angel Diaz

Open Access Theses & Dissertations

Humidity sensors are used in many industries and are important for ensuring quality and safety. Ceramic sensors are preferred because of their quick response time, ability to withstand high temperatures and excellent Chemical and mechanical stability. The manufacturing world has been moving toward additive manufacturing which is a form of synthesizing 3D tangible layer by layer in witch minimal waste is produced. Additive manufacturing also is known as 3D printing has opened new possibilities to design engineers by giving them design freedom and access to the layers of a part to allow embedded sensors. There is a category of ceramics …

Computational Studies On Perovskite-Metallofullerene Interface And Magnetic Properties Of Mn-Based Mixed Olivines, Bethuel Omutiti Khamala

Open Access Theses & Dissertations

Methyl ammonium lead halide (MAPbX3) perovskite based solar cells have recently emerged as promising class of materials for photovoltaic applications with efficiencies reaching over 22%. Designing interfaces with strong binding is vital to developing efficient, high-performing solar cells. Fullerene-based materials are widely employed as efficient electron acceptors and can serve as electron transporting layer in perovskite based solar cells. We have studied interfaces of methyl ammonium lead iodide MAPbI3 with Sc3N@C80 fullerene and Sc3N@C80PCBM fullerene derivate within the density functional formalism. Different surface terminations and orientations of the methyl ammonium are examined for binding of the fullerene layer. Our calculated …

Microstructure Evolution Of Chalcogenide Materials Via Molecular Dynamics, Sharmin Abdullah

Open Access Theses & Dissertations

The properties of a material are defined by its granular microstructure which is determined by its grain evolution and the types of grain boundaries present in the structure. For example, the performance of Cadmium Sulfide/Cadmium Telluride (CdS/CdTe) solar cells can be affected by the presence of grain boundaries which makes the study of grain structure evolution a very important part of solar cell performance optimization. Grain boundary mobilities are important properties in material science and engineering as they determine grain structures under given processing and operating conditions.

In this thesis, several computational tools were used to analyze the formation and …

Development And Characterization Of Polyethylene Terephthalate (Pet)-Cotton Natural Fiber-Reinforced Composites From Waste Materials, Israel Alejandro Carrete

Open Access Theses & Dissertations

Unprecedented levels of production and consumption have caused a rapid exhaustion of the Earth's virgin resources, which is coupled with a fast accumulation of contaminants in the form of solid waste, especially in landfills. Two significant landfill constituents come from textile waste and discarded plastic bottles. Since there is a finite amount of space that can be feasibly used for landfills, solutions that make use of these post-consumer products are imperative. This study presents one possible solution by using surface modifications of cotton fibers to produce a natural fiber-reinforced polymer composite (NFRPC) from post-consumer textile waste and polyethylene terephthalate (PET) …

Comparative Study Of Analytical Models Of The Gruneisen Parameter Of Metals As Function Of Pressure, Celia Garcia Amparan

Open Access Theses & Dissertations

Commonly used Gruneisen parameter (γ) models only hold accurate in limited regimes making them inapplicable for use over wide temperature-pressure conditions. The accuracy of these analytical models of γ and of the thermal expansion of solids are of particular interest as these are considered proxies for quantifying anharmonicity, which may be a significant contribution to the thermal pressure at high temperatures. This work reviews various definitions of γ and their relations to the equations of state and apply them to two simple metals: Tantalum (Ta) and Copper (Cu), for which a high body of experimental data exists. Classical Molecular Dynamics …

Exploration And Optimization Of Biomaterials And Cells Required For The Fabrication Of A "Cardiac Patch", Shweta Anil Kumar

Open Access Theses & Dissertations

Cardiac failure induced by myocardial infarction is believed to be one of the primary causes of morbidity and mortality all over the world. Affecting more than 26 million people worldwide, its prevalence has been observed to increase steadily. Myocardial infarction, which intitially begins as the occlusion of of a coronary artery, results in the death of millions of cardiomyocytes by obstructing blood flow to the serviced regions of the myocardium. The dead myocardium is replaced by a dense,collagenous scar which reduces the contractility of the heart, gradually leading to heart attacks. Most of the existing treatment therapies are palliative in …