Engineering Science and Materials Commons^™

Engineering Of Earth-Abundant Electrochemical Catalysts, Dylan D. Rodene

Theses and Dissertations

Alternative energy research into hydrogen production via water electrolysis addresses environmental and sustainability concerns associated with fossil fuel use. Renewable-powered electrolyzers are foreseen to produce hydrogen if energy and cost requirements are achieved. Electrocatalysts reduce the energy requirements of operating electrolyzers by lowering the reaction kinetics at the electrodes. Platinum group metals (PGMs) tend to be utilized as electrocatalysts but are not readily available and are expensive. Ni_1-xMo_x alloys, as low-cost and earth-abundant transition metal nanoparticles (NPs), are emerging as promising electrocatalyst candidates to replace expensive PGM catalysts in alkaline media. Pure-phase cubic and hexagonal Ni_{1-x …}

Creep Of Hafnium Diboride -20 Vol% Silicon Carbide At 1500°C In Air, Glen E. Pry

Theses and Dissertations

Refractory metal borides, commonly referred to as Ultra High Temperature Ceramics (UHTCs), exhibit a number of unique properties, such as extremely high melting temperature and hardness, chemical stability, high electrical and thermal conductivity and corrosion resistance. It has been demonstrated that the addition of SiC improves the oxidation resistance of ZrB2- and HfB2-based UHTCs above 1200°C by modifying the composition of the oxide scale. Addition of SiC retards the oxidation rate of ZrB2 and HfB2 by forming a protective layer of borosilicate glass. Creep deformation is one of the critical criterion for structural application of ceramics at elevated temperatures. Compression …

Tensile Properties And Fatigue Behavior Of Geopolymer Matrix Composites With Carbon Fiber Reinforcement At Elevated Temperature, Steffan M.L. Wilcox

Theses and Dissertations

The tensile stress-strain and tension-tension fatigue of geopolymer matrix composites reinforced with 0/90 carbon fibers was investigated at 23 and 300°C in laboratory air. Geopolymers are inorganic polymeric materials composed of alumina, silica, and alkali metal oxides. Because geopolymers are synthesized as a fluid mixture or particles and liquid, they can be cast into a desired shape, and cured at only slightly elevated temperatures. The relative ease of synthesis and low processing temperatures make geopolymers an attractive choice as a matrix material for composite materials. Geopolymers also offer resistance to heat and oxidizing environments. Currently, geopolymer matrix composites are being …

Creep Of Nextel 720/A Ceramic Matrix Composite With Laser Drilled Effusion Holes At 1200°C In Air And In Steam, Savannah N. Minor

Theses and Dissertations

Creep behavior of an oxide-oxide ceramic matrix composite (CMC) containing an array of effusion holes was investigated at 1200⁰C in air and in steam. The composite (N720/A) consisted of a porous alumina matrix reinforced with alumina-mullite NextelTM 720 fibers. Test specimens had an array of 17 effusion holes with 0.5-mm diameter. The effusion holes were drilled through the specimen thickness normal to the specimen surface using a CO2 laser. Effect of the effusion holes on tensile properties was evaluated tension tests to failure at 1200°C in air. Creep of specimens with effusion holes at 1200°C was studied for creep stresses …

Influence Of Coolant Flow Rate Parameters In Scaling Gas Turbine Cooling Effectiveness On A Flat Plate, Jacob P. Fischer

Theses and Dissertations

Effective film cooling relies on the performance of the selected cooling hole shape and placement of the holes on the surface of the blade. To test each holes effectiveness, large scale, low-temperature testing has been used to reduce cost and complexity. The resulting quantity from this testing is called the adiabatic effectiveness (n). The adiabatic effectiveness can then scaled up to engine operating conditions to predict how the selected film cooling hole will perform. This process is complicated by the nonlinear variation of gas properties between coolant and freestream conditions as well as between the experimental and engine conditions. In …

Consuming Digital Debris In The Plasticene, Stephen R. Parks

Theses and Dissertations

Claims of customization and control by socio-technical industries are altering the role of consumer and producer. These narratives are often misleading attempts to engage consumers with new forms of technology. By addressing capitalist intent, material, and the reproduction limits of 3-D printed objects’, I observe the aspirational promise of becoming a producer of my own belongings through new networks of production. I am interested in gaining a better understanding of the data consumed that perpetuates hyper-consumptive tendencies for new technological apparatuses. My role as a designer focuses on the resolution of not only the surface of the object through 3-D …

Stressed Oxidation Of Hafnium Diboride In Air At 1500°C, Thomas A. Bowen

Theses and Dissertations

Hypersonic vehicles with narrow airfoils produce thin boundary layers and shock temperatures in excess of 2000°C, exceeding the operating limits of traditional aerospace materials. The use of ultra-high temperature ceramics (UHTCs) allows for operating temperatures far exceeding those of metallic alloys. One such UHTC is hafnium diboride (HfB₂). Transition metal diborides generally experience significant oxidation degradation at elevated temperatures. The use of additives, such as silicon carbide (SiC) has been shown to reduce the oxidation of transition metal diborides. This research focused on the compressive creep of HfB₂ with varying amounts of SiC in air at 1500°C. …

Tunable Terahertz Metamaterials With Germanium Telluride Components, Christopher H. Kodama

Theses and Dissertations

Terahertz (THz) technology is an emerging field with many exciting applications. THz waves can be used to locate explosives and illicit drugs in security applications, or DNA and other molecule resonances in medical applications. THz frequencies represent the next level of modern, high-speed computing, but they also can be used for covert battlefield communications links. Metamaterials are an integral part of THz technology because they can be used to create exotic material properties—permittivities and permeabilities—in a part of the frequency spectrum that is otherwise rather empty and passive. This work aims to acquire a fuller understanding of THz metamaterials in …

Finite Element Analysis (Fea) Study Of The Thermal Stress Concentrations In Planar-Type Sodium Sulfur (Nas) Secondary Batteries, Jeffrey P. Colker

Theses and Dissertations

The importance of a reliable and safe way to store energy, and allow for on-demand usage, has led to much research in the field of secondary battery development. The thesis herein explores a technology that has shown promising results when implemented in large-scale energy grid applications. Though the technology has proven viable in both load-leveling on existing grids as well as serving to legitimize renewable energy sources, the development of such advanced battery systems is not without challenge. Sodium-sulfur (NaS) secondary cells have shown promising results when implemented in the aforementioned energy storage applications. One of the main drawbacks to …

Field And Laboratory Study Of The Flàajökull Glacier, Iceland, William Russell Jacobson, Jr.

Theses and Dissertations

The increased surface melting of the outlet glaciers of the Vatnajökull Ice Cap has a profound affect on the dynamics of the ice-bed couple and landform genesis. Soft-bedded glaciers are largely inaccessible, which creates a problem. One challenge is to understand the complex interactions of the glacier bed and its resultant depositional and deformational landform systems. This study investigates an outlet glacier from the Vatnajökull Ice Cap, described herein as the Fláajökull glacier system. To circumvent some of these problems, three separate projects were conducted in this dissertation: (1) magnetic fabric study of effective pressure (difference between the ice-overburden pressure …

A Nonequilibrium Finite-Rate Carbon Ablation Model For Radiating Earth Re-Entry Flows, Christopher R. Alba

Theses and Dissertations

Vehicles entering planetary atmospheres at high speed require an ablative heat shield in order to withstand the high thermal energy flux to the body. The interaction between the ablative products and the flow field is not well characterized. Numerical simulations were conducted to investigate the influence of carbon ablation on shock layer radiation. Data collected from experiments performed in the X-2 expansion tunnel at the University of Queensland was used to compare to the simulations. The model was a short half-cylinder made of isomolded graphite and was tested in 8.6 km/s Earth entry flow. The model surface was heated within …

A Study To Evaluate Non-Uniform Phase Maps In Shape Memory Alloys Using Finite Element Method, Naren Motte

Theses and Dissertations

The unique thermo-mechanical behavior of Shape Memory Alloys (SMAs), such as their ability to recover the original shape upon heating or being able to tolerate large deformations without undergoing plastic transformations, makes them a good choice for actuators.

This work studies their application in the aerospace and defense industries where SMA components can serve as release mechanisms for gates of enclosures that have to be deployed remotely. This work provides a novel approach in evaluating the stress and heat induced change of phase in a SMA, in terms of the transformation strain tensor. In particular, the FEA tool

ANSYS has …

Primary Creep In Astm A325 Bolts Under Simulated Fire Loading, Mohammad Matar

Theses and Dissertations

At room temperature, small creep effects are present on steel structures. This is not the case at fire condition where the temperature is much higher than room temperature; in this case creep can be significant, and should be taken into consideration. Since fire hazard can happen in any building, creep effect must be taken into consideration when designing a building. Creep strain behaves as a function of time, temperature and stress. As the temperature increases, the creep strain increases. Similarly, the longer the temperature at a given stress on the structure, the more the creep strain present.

The smallest component …

Characterization Of Carbon-Fiber Reinforced Polyetherimide Thermoplastic Composites Using Mechanical And Ultrasonic Methods, Mohannad A. Alhaidri

Theses and Dissertations

Continuous fiber-reinforced thermoplastics (CFRT) have the potential for being a mass-produced material for high-performance applications. The primary challenge of using CFRT is achieving fiber wet-out due to the high viscosity of thermoplastics. This results in higher temperatures and pressures required for processing the composites. Co-mingling thermoplastic fibers with a reinforcing fiber, potentially, can enable better wetting by reducing the distance the matrix needs to flow. This could result in shorter cycle times and better consolidation at lower temperatures and pressures. In this study, a polyetherimide (PEI) fiber was comingled with carbon fibers (CF). The resultant fibers were woven into fabrics …

Experimental And Analytical Characterization Of Regenerated/Nano Cellulose Composites, Issam I A Qamhia

Theses and Dissertations

Fiber-reinforced composite materials are increasingly used for structural and engineering purposes. In particular, composites reinforced with natural fiber systems are becoming more and more popular due to their biodegradability and abundance; added to that other properties such as transparency, dimensional stability and good mechanical behavior. However, major issues remain to properly understand their behavior and enable their widespread use.

In this thesis, the mechanical behavior of cellulose fiber/epoxy composites is investigated. The natural fiber systems studied fall into three categories: unidirectional regenerated cellulose fibers, triaxially braided quasi-isotropic regenerated cellulose fibers and micro-fibrillated cellulose in the form of nanocellulose scaffolds. Different …

Experimental Investigation Of Mechanical Behavior Of An Oxide/Oxide Ceramic Composite In Interlaminar Shear And Under Combined Tension-Torsion Loading, Skyler R. Hilburn

Theses and Dissertations

Creep behavior in interlaminar shear of an oxide-oxide ceramic composite, Nextel 720™/aluminosilicate (N720/AS), was investigated at 1100°C in laboratory air and in steam. The interlaminar shear strength (ILSS) was determined as 7.65 MPa. The creep behavior was examined for interlaminar shear stresses in the 2-6 MPa range. Primary and secondary creep regimes were observed in all tests conducted in air and in steam. Tertiary creep was noted in the tests performed at 6 MPa. Larger creep strains and higher creep strain rates were produced in steam. Surprisingly, the presence of steam had a beneficial effect on creep lifetimes. It appears …

Modeling Reliability Growth In Accelerated Stress Testing, Jason K. Freels

Theses and Dissertations

Qualitative accelerated test methods improve system reliability by identifying and removing initial design flaws. However, schedule and cost constraints often preclude sufficient testing to generate a meaningful reliability estimate from the data obtained in these tests. In this dissertation a modified accelerated life test is proposed to assess the likelihood of attaining a reliability requirement based on tests of early system prototypes. Assuming each prototype contains an unknown number of independent competing failure modes whose respective times to occurrence are governed by a distinct Weibull law, the observed failure data from this qualitative test are shown to follow a poly-Weibull …

Characterization And Processing Evaluation Of Starch/High-Density Polyethylene Materials In Extrusion Blow Molding, Bradley Dale Bacigalupi

Theses and Dissertations

The growing negative impacts of non-biodegradable plastics derived from non-renewable materials have created increasing interest throughout the world for new materials that are both biodegradable and renewable, that can be combined with or replace traditional plastics. Plant-based thermoplastic starch (TPS), a promising alternative material to traditional petroleum based resin, is both biodegradable and renewable and has great potential for use in plastic manufacturing processes. Two major obstacles that prevent more widespread use of TPS include; TPS base material, which is typically manufactured in a flake or powder, is incompatible with standard plastics production equipment that require pelletized resin, the second …

Measuring And Modeling The Mechanical Properties Of Bicycle Tires, Andrew Erwin Dressel

Theses and Dissertations

It has been shown that tire deformation can play an important role in the stability and handling of a bicycle. It is expected that an accurate understanding of tire behavior is necessary for correct understanding of rider behavior and that correct understanding of rider behavior is necessary for optimizing bicycle design. That certainly has been the case for motorcycles.

Several instances of published bicycle tire stiffness data exist, but they seldom agree with each other, do not all measure the same properties, and often are missing key pieces of test configuration data, such as tire size, rim width, inflation pressure, …

Starch Resin Moisture Level Effect On Injection Molding Processability And Molded Part Mechanical Properties With Pure Starch Resin And Polymer Blends, Jordan M. Ellingson

Theses and Dissertations

The current and forecasted global consumption of plastic packaging and products through the 21st century combined with the already reported and growing negative impact of plastics on the environment due to plastics being synthesized from nonrenewable resources that do not biodegrade is of serious concern. However, recent advances in starch technology including the development of thermoplastic starch (TPS) materials —polymers that are both renewable and biodegradable—have brought hope to reducing this impact. The mechanical properties of thermoplastic starch have often been improved by blending with synthetic polymers. One issue that arises with blending is volatilization of the melt from moisture …

Material Behavior Characterization Of A Thin Film Polymer Used In Lithium-Ion Batteries, Michael James Martinsen

Theses and Dissertations

The use of lithium-ion batteries in the automotive industry has become increasingly popular. As more hybrid and electric vehicles take to the road an understanding of how these batteries will behave structurally will be of greater concern. Impact testing can give a valuable overview of the strengths and weaknesses of a battery's design, however, these tests can be time consuming, expensive, and dangerous. Finite element analysis can deliver a reliable low cost approximation of physical testing results. The accuracy of FE results depends greatly on the mathematical representation of the material properties of Li-ion battery components. In this study, the …

Analysis Of Multi-Directional Recycled Jute Fiber Composite Behavior Using Experimental, Numerical, And Analytical Methods, Patrick Severson

Theses and Dissertations

Composite materials are increasing in popularity as a material of choice in many engineering applications. Major industries using composites include automotive, construction, and sports equipment. Most of the knowledge, research, and technology that will help decrease the cost of composite materials have been aimed at developing synthetic fibers as the reinforcing constituent.

This thesis characterizes jute fibers obtained as a byproduct from the coffee industry to determine if they can be viable in composite manufacturing. Experimental analysis, finite element analysis, and analytical modeling are used to characterize jute fiber based composites. Experimental analysis consists of jute fiber bundle tensile testing …

Friction Stir Spot Welding Of Ultra-High Strength Steel, Trent J. Hartman

Theses and Dissertations

Friction stir spot welding (FSSW) is quickly becoming a method of interest for welding of high strength steel (HSS) and ultra high strength steel (UHSS). FSSW has been shown to produce high quality welds in these materials, without the drawbacks associated with fusion welding. Tool grade for polycrystalline cubic boron nitride (PCBN) tools has a significant impact on wear resistance, weld quality, and tool failure in FSSW of DP 980 steel sheet. More specifically, for a nominal composition of 90% CBN, the grain size has a significant impact on the wear resistance of the tool. A-type tools performed the best, …

Design, Fabrication And Testing Of Tunable Rf Meta-Atoms, Derrick Langley

Theses and Dissertations

Metamaterials are engineered structures designed to alter the propagation of electromagnetic waves incident upon the structure. The focus of this research was the effect of metamaterials on electromagnetic signals at radio frequencies. RF meta-atoms were investigated to further develop the theory, modeling, design and fabrication of metamaterials. Comparing the analytic modeling and experimental testing, the results provide a deeper understanding into metamaterials which could lead to applications for beam steering, invisibility cloaking, negative refraction, super lenses, and hyper lenses. RF meta-atoms integrated with microelectromechanical systems produce tunable meta-atoms in the 10 - 15 GHz and 1 - 4 GHz frequency …

A High Bandwidth Non-Destructive Method For Characterizing Simple Media, Matthew L. Szuster

Theses and Dissertations

The relative complex permittivity can be extracted with time domain data from a perfect electrical conductor (PEC) backed sample of a low-loss, non-dispersive dielectric using dual ridged waveguide aperture probes with attached PEC flange plates of the same geometry and different dimensions. The temporal domain measurement of interest is the ability to detect the reflection from the edge of the flange plate in the parallel region created by the flange plate and the PEC backing on the dielectric sample. Signal processing windows are applied to the data in order to exploit this edge reflection. The types of signal processing methods …

Silicon Carbide Capacitive High Temperature Mems Strain Transducer, Richard P. Weisenberger

Theses and Dissertations

Air Force Research Lab Air Vehicles directorate performs research on hypersonic vehicles. To verify materials or designs of hypersonic vehicles, they have a need to measure strain at temperatures exceeding 700°C. Strain sensors have the ability to measure strain. Strain is the deformation of materials due to internal stresses in a material. Internal stresses occur when a material is subjected to a force. Traditional strain sensors use Piezoresistive effects to measure strain, which is temperature dependent and making them unusable at high temperatures. This paper discusses a novel strain sensing device, sensing capacitance instead of piezoresistance. The strain sensor is …

High Speed Friction Stir Spot Welding On Dp 980 Steel:Joint Properties And Tool Wear, Nathan David Saunders

Theses and Dissertations

With the desire to improve passenger safety and fuel efficiency, Ultra High Strength Steels (UHSS) have been developed for use in the automotive industry. UHSS are high strength steels with high ductility and strength. DP 980 is one of these UHSS being applied in automobile manufacturing. DP 980 is difficult to join with Resistance Spot Welding (RSW) because of the high carbon content and alloying in this material. The weld becomes brittle when it solidifies during the welding process. With the desire and motivation of widely using UHSS, new welding processes are needed to be developed in order to effectively …

Investigation Of Gallium Nitride Transistor Reliability Through Accelerated Life Testing And Modeling, Bradley D. Christiansen

Theses and Dissertations

Gallium nitride high electron mobility transistors are attractive to the DoD for their ability to operate at high frequencies, voltages, temperatures, and power. Yet, there are concerns about the reliability of these devices. Various degradation mechanisms and their causes are proposed in the literature. A variety of reliability tests were conducted to understand these mechanisms and causes. A multi-stressor experiment revealed different failure mechanisms than are in the literature. In particular, the devices tested at high voltage in the OFF state did not degrade significantly as suggested by others' reports. The validity of temperature-accelerated life testing when applied to GaN …

Friction Bit Joining Of 5754 Aluminum To Dp980 Ultra-High Strength Steel: A Feasibility Study, Britney Weickum

Theses and Dissertations

In this study, the dissimilar metals 5754 aluminum and DP980 ultra-high strength steel were joined using the friction bit joining (FBJ) process. The friction bits were made using one of three steels: 4140, 4340, or H13. Experiments were performed in lap shear, T-peel, and cross tension configurations, with the 0.070" thick 5754 aluminum alloy as the top layer through which the friction bit cut, and the 0.065" thick DP980 as the bottom layer to which the friction bit welded. All experiments were performed using a computer controlled welding machine that was purpose-built and provided by MegaStir Technologies. Through a series …

Tool Life Of Various Tool Materials When Friction Spot Welding Dp980 Steel, Christopher Shane Ridges

Theses and Dissertations

In this study, friction spot welding was used to join DP980 steel sheet. Four different ultra-hard tool materials were used with the objective of determining which tool material produced the highest number of acceptable-strength welds. Three of the tools were composed of various mixtures of polycrystalline cubic Boron Nitride (PCBN), Tungsten, and Rhenium. These materials are referred to herein as Q60, Q70, and Q80, the "Qxx" designation denoting the percentage of the volume of the tool material composed of PCBN. The fourth tool tested was composed entirely of PCBN. The Q70 tool produced approximately 1100 welds of acceptable strength before …