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Articles 1 - 30 of 72
Full-Text Articles in Engineering Science and Materials
Leaching Mechanism Of Semiconducting Minerals, Fathi Habashi
Leaching Mechanism Of Semiconducting Minerals, Fathi Habashi
Fathi Habashi
The mechanism of leaching of semiconducting minerals such as PbS, ZnS, UO2, etc., has been the subject of intensive speculation by hydrometallurgists in the early 1950s. The electrochemical mechanism proposed in 1970 by the author in volume 2 of his Principles of Extractive Metallurgy avoids the assumption of forming intermediate complexes that cannot be isolated or identified.
The Roles Of The Width Of Gas/Liquid/Solid Three-Phase Boundary Zone Of Dispersion Water Films In Atmospheric Corrosion Of Metals, Wang Jia, Jing Jiang
The Roles Of The Width Of Gas/Liquid/Solid Three-Phase Boundary Zone Of Dispersion Water Films In Atmospheric Corrosion Of Metals, Wang Jia, Jing Jiang
Journal of Electrochemistry
The roles of TPB(Three-Phase Boundary) width in the corrosion processes of metals under dispersed water films were investigated by electrochemical techniques combined with contact angle measurement.It is found that both cathodic limiting current density and corrosion current density linearly increases with increasing the TPB width,confirming the important role of TPB width in gas/liquid/solid multiphase corrosion systems.Based on above results,the effect of water film thickness on atmospheric corrosion rate was quantitatively evaluated by the TPB width.
Research On Nafion/Sio_2 Composite Membrane In All Vanadium Redox Flow Battery, Dong-Dong Liu, Mao-Cai Lin, Tao Guan, Qing-Chun Yu
Research On Nafion/Sio_2 Composite Membrane In All Vanadium Redox Flow Battery, Dong-Dong Liu, Mao-Cai Lin, Tao Guan, Qing-Chun Yu
Journal of Electrochemistry
The Nafion117/SiO2 composite membrane was prepared by sol-gel method.The results showed that,during composite membrane preparation process,the ratio of MeOH and TEOS did not affect the penetration rate of VO2+ basically,however,the lowest permeability of 427×10-9cm2/s in the membrane was achieved while hydrolysis time was 10 min and natural drying for 24 h after hydrolysis,which reduced by 52 times than that in Nafion117 membrane.The SEM tests proved that SiO2 grains grew bigger in the composite membrane during the natural drying,and most of the holes in Nafion117 were filled.Single cell test showed the battery power efficiency was improved by 2.7 %.
Study On Preparing Technology And Corrosion Resistance Of Ti/Zr Based Chromium-Free Chemical Conversion Coating On Zinc Electroplating Layer, Yong Guan, Jian-Guo Liu, Chuan-Wei Yan
Study On Preparing Technology And Corrosion Resistance Of Ti/Zr Based Chromium-Free Chemical Conversion Coating On Zinc Electroplating Layer, Yong Guan, Jian-Guo Liu, Chuan-Wei Yan
Journal of Electrochemistry
In this paper,we obtained environmental-friendly chromium-free chemical conversion coating on the non-cyanide alkaline zinc electroplating layer by employing the optimized Ti/Zr based conversion technique.At the same time,the performances of the Ti/Zr based conversion coating were compared with chromate colour passivation coating.The corrosion resistances of the conversion coatings were investigated by using neutral salt spray(NSS) test,potentiodynamic polarization and electrochemical impedance spectroscopy(EIS).The results showed that the white rust appeared after 96 hours when the NSS test was performed on the Ti/Zr based conversion coating,which was close to the corrosion resistance rating of chromate colour passivation coating.Compared with the chromate passivation coating,the Ti/Zr …
Preparation And Characterization Of The Silane-Phosphonic Acid Composite Passivation Coating For Electrogalvanized Steel, Yong Guan, Jian-Guo Liu, Chuan-Wei Yan
Preparation And Characterization Of The Silane-Phosphonic Acid Composite Passivation Coating For Electrogalvanized Steel, Yong Guan, Jian-Guo Liu, Chuan-Wei Yan
Journal of Electrochemistry
A new silane-phosphonic acid composite passivation coating process has been developed for the protection of electrogalvanized steel based on N-(β-aminoethyl)-γ-aminopropyltrimethoxysilane(AAPTMS),γ-(2,3-epoxypropoxy)propyltrimethoxy-silane(GPTMS) and 1-hydroxy ethylidene-1,1-diphosphonic acid(HEDP).The results of X-ray photoelectron spectroscopy(XPS),Fourier transform infrared spectroscopy(FTIR),potentiodynamic polarization scan,electrochemical impedance spectroscopy(EIS) and neutral salt spray(NSS) tests indicated that the major structure of the prepared silane-phosphonic acid composite passivation coating consisted mainly of Si—O—Si and Si—O—P bonds.The area of white rust was not more than 5% of the total panal after 120 h NSS test,which could be compared favourably with the chromate colour passivation coating.However,the corrosion reaction on the anode of the silane-phosphonic acid composite passivation …
Electrodeposition Of Lead Dioxide From Dluoroborate Solutions, Chun-Mei Kong, Yong-Ming Tang, Wen-Zhong Yang, Xiao-Yuan Yang
Electrodeposition Of Lead Dioxide From Dluoroborate Solutions, Chun-Mei Kong, Yong-Ming Tang, Wen-Zhong Yang, Xiao-Yuan Yang
Journal of Electrochemistry
The PbO2 anodes were prepared on platinum from fluoroborate media and its doped solutions by electrodeposition technique.Elecchemical and pysicochemical properties of these PbO2 films were studied by cyclic voltammetry methods,XRD and SEM.The results showed that the presence of BF4-increased PbO2 electrodeposition rate;the prepared lead dioxide consisted of β-PbO2;the preferential orientation of crystals and surface morphology were affected a lot by doping F-and Fe3+.The FB/F-Fe-PbO2 electrode exhibited regular-shaped layers with compact morphology.Furthermore,increasing current density also change the preferential orientation of PbO2 crystals.
Effects Of Solvents And Electrolyte Salts On The Electrochemical Reduction Of Oxygen In Non-Aqueous Electrolytes, Yan-Yan Tian, Wei Wu, Jun Gao, Yong Yang
Effects Of Solvents And Electrolyte Salts On The Electrochemical Reduction Of Oxygen In Non-Aqueous Electrolytes, Yan-Yan Tian, Wei Wu, Jun Gao, Yong Yang
Journal of Electrochemistry
The electrochemical reduction processes of oxygen in different non-aqueous solvents such as acetonitrile(MeCN),propylene carbonate(PC) and their mixtures were investigated by cyclic voltammetry method.The results indicated a one electron reduction of oxygen to O2-occured in these systems as a first step reduction,no matter whether in tetrabutylammonium hexafluorophosphate(TBAPF6)/MeCN or TBAPF6/PC electrolyte.However,the CV curves in 0.1 mol·L-1 TBAPF6/MeCN showed a couple of reversible redox peaks,indicating that the reduction process of oxygen was irreversible in the 0.1 mol·L-1 TBAPF6/PC electrolyte.In the PC-based electrolyte,the reduction current peak reduced largely and the oxidation peak of O2-almost disappeared as compared to that of the former electrolytes.The possible …
Electrochemical Detection For The Corrosion Of Reinforcing Steel In Concrete During Immersion And Drying Cycles, Bing-Li Jia, Fa-He Cao, An-Na Chen, Jian-Qing Zhang
Electrochemical Detection For The Corrosion Of Reinforcing Steel In Concrete During Immersion And Drying Cycles, Bing-Li Jia, Fa-He Cao, An-Na Chen, Jian-Qing Zhang
Journal of Electrochemistry
The corrosion behavior of reinforcing steel in concrete under dry-wet cycle condition has been studied by electrochemical noise(EN) compared with the electrochemical impedance spectroscopy(EIS),SEM micrographs and EDS.The statistical method has been employed to analyze the EN data of reinforcing steel in concrete,which revealed three different corrosion stages of reinforcing steel in concrete,including the dissolution of the passive film,the active corrosion and the cumulation of corrosion product.The wavelet transform has also been employed,which indicated that steel in concrete with pH 1 is associated with uniform corrosion,while steel in concrete with pH 3 and pH 7 are associated with localized corrosion,such as …
Photoelectrochemical Properties Of N,S,And Cl Modified Nano Tio_2 Thin Films, Hong Yun, Chang-Jian Lin, Jing Li, Rong-Gui Du
Photoelectrochemical Properties Of N,S,And Cl Modified Nano Tio_2 Thin Films, Hong Yun, Chang-Jian Lin, Jing Li, Rong-Gui Du
Journal of Electrochemistry
The nitrogen(N),sulfur(S) and chlorine(Cl) modified nano TiO2 thin films were prepared by adding Ti(O-n-Bu)4 as the precursor into concentrated HNO3,H2SO4 and HCl Solutions,respectively,on different substrates in a sol-gel process.The photoelectrochemical performances of N,S and Cl modified nano TiO2 thin films have been studied by UV-vis(DRS),photocurrent curves,EIS and OCP-time curves.N-modified TiO2 nano films show better surface structure,which helps to improve the quantum efficiency of nano TiO2 thin films.
Initial Stage Of Atmospheric Corrosion Of Ndfeb(M35) In A Simulated Marine Atmosphere, Chun-Ling Li, Yuan-Tai Ma, Ying Li, Fu-Hui Wang
Initial Stage Of Atmospheric Corrosion Of Ndfeb(M35) In A Simulated Marine Atmosphere, Chun-Ling Li, Yuan-Tai Ma, Ying Li, Fu-Hui Wang
Journal of Electrochemistry
This study detailed the atmospheric corrosion behaviour of sintered NdFeB(M35) in a simulated marine atmosphere with 80% relative humidity(RH).The dissolution and subsequent reaction of NaCl particles cause the attack of NdFeB.The corrosion presented three representative types:if the electrolyte covered magnetic phase and Nd-rich phase,the Nd-rich phase was corroded firstly due to galvanic effect;if the electrolyte covered magnetic phase,magnetic phase was corroded along the grain boundary;if the electrolyte located near the position of defects,corrosion progressed along with the defect because of low concentration of oxygen inside the defect.With corrosion progressing,local corrosion areas were mutually connected,with Nd-rich phase and grain boundary being …
Hydrothermal Reduction Synthesis Of Lifepo_4 And Its Electrochemical Performance, Hong-Li Zou, Guang-Hui Zhang, Pei-Kang Shen
Hydrothermal Reduction Synthesis Of Lifepo_4 And Its Electrochemical Performance, Hong-Li Zou, Guang-Hui Zhang, Pei-Kang Shen
Journal of Electrochemistry
The cathode materials of LiFePO4 were prepared via a hydrothermal reduction method using FeCl3 as Fe source and iron as a reducing agent.The results showed that ferric salt could be reduced to ferrous salt completely under the hydrothermal condition and pure-phase LiFePO4 was obtained based on the test results of XRD and FTIR.Carbon-coated LiFePO4 was synthesized by pyrolysisng glucose at high temperature.The morphologies of pure LiFePO4 displayed cluster-like while the LiFePO4/C displayed sphere-like particles.The electrochemical test showed that the LiFePO4/C had good rate performance,while LiFePO4 delivered much lower discharge capacity.
Corrosion Electrochemical Behavior Of Am60 Magnesium Alloys In Automobile Engine Coolants, Ling-Jie Li, Sha Wang, Yin Xiao, Jun Lan, Jing-Lei Lei, Sheng-Tao Zhang, Fu-Sheng Pan
Corrosion Electrochemical Behavior Of Am60 Magnesium Alloys In Automobile Engine Coolants, Ling-Jie Li, Sha Wang, Yin Xiao, Jun Lan, Jing-Lei Lei, Sheng-Tao Zhang, Fu-Sheng Pan
Journal of Electrochemistry
The polarization measurements and electrochemical impedance spectroscopy(EIS) were used to study the corrosion electrochemical behavior of AM60 magnesium alloys in three kinds of commercial coolants for automobile engine.Results show that the tested commercial coolants are slightly corrosive to AM60 magnesium alloys and their corrosivity varies from coolant to coolant.The coolant C is the least corrosive among the studied commercial coolants and the coolant A is more corrosive than the coolant B and C.The coolant C appears to be the most promising coolant for automobile engine made by magnesium alloys.The coolant resistivity plays an important role in the corrosion of AM60 …
The Sol-Gel Synthesis And Electrochemical Performance Of Li_3v_2(Po_4)_3/C Cathode Material For Lithium Ion Battery, Li-Ying Liu, Lian Chen, Hai-Yan Zhang, Yu-Chun Zhai
The Sol-Gel Synthesis And Electrochemical Performance Of Li_3v_2(Po_4)_3/C Cathode Material For Lithium Ion Battery, Li-Ying Liu, Lian Chen, Hai-Yan Zhang, Yu-Chun Zhai
Journal of Electrochemistry
Li3V2(PO4)3/C was synthesized by sol-gel method with citric acid as chelate and C sources.Physical and electrochemical performances of as-prepared materials were characterized through XRD,SEM and galvanostatic charge-discharge tests,etc.The results showed that products produced by calcining at 800 ℃ for 12 h had a single phase crystal structure and relatively small particle sizes with uniform distribution.At 0.1 C,0.5 C and 1 C,the initial specific discharge capacities were 153.0,143.1 and 130.6 mAh·g-1,respectively,and capacity efficiencies were 93.1%,85.4% and 77.3% after 50 cycles,respectively.Charge efficiencies were all above 80% and discharge voltages were higher.
Effect Of Cldh On Rebar Corrosion Behavior In Chloride Contaminated Neutral Pore Solutions, Yu-Ming Tang, Le Niu, Yu Zuo
Effect Of Cldh On Rebar Corrosion Behavior In Chloride Contaminated Neutral Pore Solutions, Yu-Ming Tang, Le Niu, Yu Zuo
Journal of Electrochemistry
The effect of calcined LDH-MgAl-CO3 on rebar corrosion behavior in chloride ion contaminated neutral concrete pore solutions was investigated in this paper.Corrosion potentials of rebars in pore solutions after treatment with CLDH were higher than before treatment.According to polarization tests,passivated region of rebars in pore solutions after treatment with CLDH was found apparently instead of activation.EIS tests showed that CLDH made the impedance of specimens increase.The measurements of pH and chloride ion concentration after treatment indicated that / of pore solutions decreased by 4～5 magnitude orders.
Energetyka Niskoemisyjna, Wojciech M. Budzianowski
Energetyka Niskoemisyjna, Wojciech M. Budzianowski
Wojciech Budzianowski
No abstract provided.
Electrooxidation Of Carbon Monoxide On Pd Thin Film-Coated Au Electrodes:Film Thickness Dependence, Yuqing Yang, Shouzhong Zou
Electrooxidation Of Carbon Monoxide On Pd Thin Film-Coated Au Electrodes:Film Thickness Dependence, Yuqing Yang, Shouzhong Zou
Journal of Electrochemistry
The adsorption and electrooxidation of CO on Pd-coated Au electrodes were studied by cyclic voltammetry and surface-enhanced Raman spectroscopy (SERS) . It is found that CO oxidation activity is film thickness dependent. Cyclic voltammograms (CVs) showed that CO oxidation peak potential shifted positively with the increase of the Pd thickness. SERS showed a redshift of the C—O stretching frequency with increasing Pd film thickness. These observations were explained by the dband theory. The strain effect strengthens CO adsorption and stabilizes adsorbed CO,while the ligand effect weakens CO adsorption and eases its oxidation. The ligand effect overpowers the strain effect.
The Mechanism Of ~(13)Co_(Ad)/~(12)Co Isotope Exchange At Pt Electrode,A Combined Study By Electrochemical In-Situ Infrared Spectroscopy And Dipole-Dipole Coupling Analysis, Sang-Zi Liang, Shao-Xiong Liu, Ling-Wen Liao, Qian Tao, Jing Kang, Yan-Xia Chen
The Mechanism Of ~(13)Co_(Ad)/~(12)Co Isotope Exchange At Pt Electrode,A Combined Study By Electrochemical In-Situ Infrared Spectroscopy And Dipole-Dipole Coupling Analysis, Sang-Zi Liang, Shao-Xiong Liu, Ling-Wen Liao, Qian Tao, Jing Kang, Yan-Xia Chen
Journal of Electrochemistry
In this contribution,we have analyzed the IR spectra of saturated CO adlayer at rough Pt film electrode as a function of fractional surface coverage of 13COad/12COad recorded during 13COad /12CO isotope exchange process according to dipole-dipole coupling theory and coherent potential approximation. By properly choosing the parameters of adlayer structure and dipole-dipole coupling interaction under coherent potential approximation, we demonstrated that we can successfully simulate the IR spectra as a function of the surface coverage of CO adlayer at rough Pt film electrodes by assuming that COad molecules with low C—O stretching frequencies are dis- placed preferentially during the 13COad/12CO …
Preliminary Investigation Of Iron Protoporphyrin Sams On Platinum Electrodes By Surface Enhanced Vibrational Spectroscopies, Min Ma, Yao-Yue Yang, Han-Xuan Zhang, Wen-Bin Cai
Preliminary Investigation Of Iron Protoporphyrin Sams On Platinum Electrodes By Surface Enhanced Vibrational Spectroscopies, Min Ma, Yao-Yue Yang, Han-Xuan Zhang, Wen-Bin Cai
Journal of Electrochemistry
In situ SERS and ATR-SEIRAS were applied to investigate the electrochemical and structural properties of iron protoporphyrin IX (FePP) self-assembled monolayers (SAMs) on Pt electrodes in 0. 1 mol· L -1 HClO4. The potential dependent SERS spectra of the FePP SAM on a roughened Pt electrode with the enhancement factor of ca. 40 were acquired with the excitation line of 514 nm. Analyses of SERS data over the potential region from 0. 5 to -0. 3 V enabled to obtain potential dependent adsorption isotherms,from which the formal redox potential could be estimated to be ca. - 0. 2 V. Up-tilted …
Studies Of Oxidation Processes Of Adsorbed And Solution Co On Pt(110) Electrode By Cyclic Voltammetry And In Situ Ftirs, Li Tian, Jun-Tao Li, Jin-Yu Ye, Chun-Hua Zhen, Shi-Gang Sun
Studies Of Oxidation Processes Of Adsorbed And Solution Co On Pt(110) Electrode By Cyclic Voltammetry And In Situ Ftirs, Li Tian, Jun-Tao Li, Jin-Yu Ye, Chun-Hua Zhen, Shi-Gang Sun
Journal of Electrochemistry
The oxidation processes of adsorbed CO (COad) and solution phase CO (COsol) on Pt(110) electrode were investigated by cyclic voltammetry and in-situ FTIR spectroscopy. It has revealed that in comparison with COad on Pt(110) in a CO-free solution,the oxidation current peak of COsol in a CO-saturated solution is positively shifted ca. 168 mV,and the peak current density has been increased by 6. 70 times. Linear adsorbed CO (COL) is determined by in-situ FTIR spectroscopy as the main species,which is uniformly distributed on Pt (110) surface. In a CO-free solution,the onset potential of COL is measured by in-situ FTIRS ca. 0. …
Multi-Electron Redox Materials For High Energy Density Electrodes, Xin-Ping Ai, Han-Xi Yang
Multi-Electron Redox Materials For High Energy Density Electrodes, Xin-Ping Ai, Han-Xi Yang
Journal of Electrochemistry
Various new energy technologies being developed require electrochemical energy batteries to have a real breakthrough in energy density and rate capability,which imposes a great challenge for electrochemists and materials chemists. Multi-electron redox reactions seem to open a promising avenue to create new batteries with dramatically enhanced energy densities. This paper describes simply our research works on the multi-electron redox systems,including metal boride anode,lithium alloying compounds and electrochemical conversion materials, and also discusses the problems hindering these systems for battery applications.
In Situ Surface-Enhanced Raman Scattering Spectroscopic Study Of Sulfur Adsorption On Polycrystalline Platinum Electrode Surface, Bolian Xu-, In-Su Park, Ying Li, De-Jun Chen, Yuye J. Tong
In Situ Surface-Enhanced Raman Scattering Spectroscopic Study Of Sulfur Adsorption On Polycrystalline Platinum Electrode Surface, Bolian Xu-, In-Su Park, Ying Li, De-Jun Chen, Yuye J. Tong
Journal of Electrochemistry
The paper reports the first in situ surface enhanced Raman scattering (SERS) spectroelectrochemistry study of sulfur adsorption and electro-oxidation on highly roughened polycrystalline Pt surface in both acidic and basic supporting electrolytes. The SERS spectra were taken at a constant electrode potential after accumulative electro-oxidation CVs of the Pt electrode with pre-adsorbed sulfur species and at different electrode potentials that were varied stepwise of the Pt electrode immersed in sulfur-containing electrolytes without pre-adsorbed sulfur species. In both cases,a dominant vibrational band at 299 cm -1 in acidic electrolyte but at 310 cm-1 in basic electrolyte was observed,which was assigned to …
Solid State Nmr Studies Of Lithium Manganese Silicate As Positive Electrode Materials For Li-Ion Batteries, Hu Cheng, Zi-Geng Liu, Yi-Xiao Li, Zhong Chen, Yong Yang
Solid State Nmr Studies Of Lithium Manganese Silicate As Positive Electrode Materials For Li-Ion Batteries, Hu Cheng, Zi-Geng Liu, Yi-Xiao Li, Zhong Chen, Yong Yang
Journal of Electrochemistry
The Li2MnSiO4 cathode material for lithium ion batteries was synthesized by sol-gel assisted hydrothermal method. XRD,FTIR and SS-NMR were used to study the phase,structure and morphology of obtained samples. Electrochemical performance of cathode material was tested. The results show that the main phase of sample prepared was Li2MnSiO4,whereas a small amount of impurities ( Li2CO3) were existed. The Li2MnSiO4 cathode material gave an initial discharging capacity of about 190 mAh·g -1. But this capacity faded rapidly during the cycling process due to the decomposition of Li2MnSiO4.
Comparative Study Of Nanoporous Pt,Ptru And Ptruir Catalysts Using Electrochemical Ftir Spectroscopy, M. Amussen Robert, Holt-Hindle Peter, Nigro Samantha, Chen Aicheng
Comparative Study Of Nanoporous Pt,Ptru And Ptruir Catalysts Using Electrochemical Ftir Spectroscopy, M. Amussen Robert, Holt-Hindle Peter, Nigro Samantha, Chen Aicheng
Journal of Electrochemistry
In recent years much effort has been put towards developing efficient Pt-based electrocatalysts for applications in fuel cells. With the rising cost of precious metals such as Pt,the need to enhance the activity and to decrease the load of catalysts is prominent. Herein we report on the synthesis and comparative study of nanoporous Pt,PtRu and PtRuIr electrocatalysts. The nanoporous electrodes were fabricated using a hydrothermal method and characterized by scanning electron microscopy (SEM) ,energy dispersive spectroscopy (EDS) ,X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS) . The electrocatalytic activity of the fabricated nanopo- rous materials was evaluated using both CO …
An In Situ Fourier Transform Infrared Spectroelectrochemical Study On Alcohols Electrocatalytic Oxidation At Pd Electrode In Acidic Solution, Hai-Ping Huang, Lian-Qin Wang, Pei-Kang Shen
An In Situ Fourier Transform Infrared Spectroelectrochemical Study On Alcohols Electrocatalytic Oxidation At Pd Electrode In Acidic Solution, Hai-Ping Huang, Lian-Qin Wang, Pei-Kang Shen
Journal of Electrochemistry
The methanol and ethylene glycol electrooxidation on palladium electrode in acidic solution has been investigated by cyclic voltammetry and in situ Fourier transform infrared spectroelectrochemistry. It shows that the oxidation of methanol and ethylene glycol at Pd electrode cannot proceed until over 1. 5 V in acidic and neutral media. The overpotential decreases and the peak current density increases with the reduction in pH values. The formation of the oxygen-containing species significantly affects the alcohol oxidation on Pd electrode. The in situ FTIR spectroscopic measurements show that the oxidation products of ethylene glycol on Pd electrode are CO2 and oxalic …
In-Situ Surface Enhanced Raman Scattering Electrochemical Investigation Of 4-Aminoantipyrine On Silver Electrode, Li-Jun Zhang, Wei Song, Ling Chen, Zong-Rang Zhang, Hai-Feng Yang
In-Situ Surface Enhanced Raman Scattering Electrochemical Investigation Of 4-Aminoantipyrine On Silver Electrode, Li-Jun Zhang, Wei Song, Ling Chen, Zong-Rang Zhang, Hai-Feng Yang
Journal of Electrochemistry
In this paper,4-AAP was self-assembled on silver surface to form monolayers. Surface-enhanced Raman Spectroscopy ( SERS) was used to in-situ investigate the adsorption mechanism of the 4-aminoantipyrine( 4-AAP) on silver surface dependent on shifting potentials and the effect of solution pH. Based on density functional theory( DFT) calculation of vibration modes,approximate assignment of 4-AAP SERS spectrum was conducted. In situ SERS spectral electrochemical experiments indicated that the 4-AAP monolayers experience a dynamic adsorption process from a tilted fashion to a more vertical mode for benzene ring and more parallel for pyrine ring with the potential applied toward more negative voltages. …
Nano/Micro-Structured Electrode Materials For Lithium-Ion Batteries, Yu-Guo Guo, Zhong-Li Wang, Xing-Long Wu, Wei-Ming Zhang, Li-Jun Wan
Nano/Micro-Structured Electrode Materials For Lithium-Ion Batteries, Yu-Guo Guo, Zhong-Li Wang, Xing-Long Wu, Wei-Ming Zhang, Li-Jun Wan
Journal of Electrochemistry
Nanostructured materials are currently of interest as high performance anodes and cathodes for rechargeable lithium-ion batteries because of their novel nano-size effects and significantly enhanced kinetics. This review paper describes some recent developments in this field,addressing the size effects,morphology effects,as well as the functions of carbon coating layers toward lithium storage. Several"kinetically stabilized"nano/microstructured electrode materials and high-rate electrode materials with mixed-conducting networks based on the work of the authors are highlighted for illustration.
High-Rate Cyclic Properties Of Hollow Carbon Hemisphere As Anode Materials For Lithium Ion Batteries, Guang-Hui Zhang, Zao-Xue Yan, Hong-Li Zou, Pei-Kang Shen
High-Rate Cyclic Properties Of Hollow Carbon Hemisphere As Anode Materials For Lithium Ion Batteries, Guang-Hui Zhang, Zao-Xue Yan, Hong-Li Zou, Pei-Kang Shen
Journal of Electrochemistry
High surface area hollow carbon hemispheres ( HCHs) covered with hard carbon layers have been synthesized by using polystyrene spheres ( PSs) as templates under hydrothermal method combined with the intermittent microwave heating ( IMH) method. The morphologies of the materials are characterized by SEM and TEM. The electrochemical properties of the HCHs are tested. Comparing with graphite and mesocarbon microbeads ( MCMB) ,the HCHs show higher capacity and excellent cyclic life performance.
Research On Electrochemical Performance Of Lithium-Ion Battery Cathode Material Lini_(1/3)Co_(1/3)Mn_(1/3)O_2 In Aqueous Lino_3 Solution, Jun Zheng, Xin Jia, Chong Wang, Ming-Sen Zheng, Quan-Feng Dong
Research On Electrochemical Performance Of Lithium-Ion Battery Cathode Material Lini_(1/3)Co_(1/3)Mn_(1/3)O_2 In Aqueous Lino_3 Solution, Jun Zheng, Xin Jia, Chong Wang, Ming-Sen Zheng, Quan-Feng Dong
Journal of Electrochemistry
The cathode material of LiNi1/3Co1/3Mn1/3O2 synthesized by sol-gel method shows excellent high rate performance,and high output power density during discharge process. A well-ordered layered α-NaFeO2 structure was confirmed by XRD and a primary particle size of about 500 nm was indicated by SEM. Galvanostatic charge-discharge test indicates that LiNi1/3Co1/3Mn1/3O2 in 2 mol·L-1 LiNO3 aqueous solution with pH 12 reached a ca-pacity of 147 mAh/g while charged and discharged at 2C. The capacities were 64、33、16 mAh/g with 80C ( 14. 4 A/g) 、150C( 27 A/g) and 220C ( 39. 6 A/g) charge/discharge rates,while the power densities of the battery were 2574 …
Synthesis Of Cosalen Composite In Apo-5 And Its Electrocatalytic Behaviour For Reaction Of Dioxygen Reduction, Rong Zhang, Li-Hua Tang, Bin-Bin Fan, Jing-Hong Ma, Rui-Feng Li
Synthesis Of Cosalen Composite In Apo-5 And Its Electrocatalytic Behaviour For Reaction Of Dioxygen Reduction, Rong Zhang, Li-Hua Tang, Bin-Bin Fan, Jing-Hong Ma, Rui-Feng Li
Journal of Electrochemistry
CoAPO-5 molecular sieve was hydrothermally synthesized. The Cobalt ions in CoAPO-5 were coordinated with the SALEN ligend diffusing into the channels of the molecular sieve to form CoSALEN complexes. The electrochemical behaviors and electrocatalysis for dioxygen reduction of the CoSALEN complex immobilized in APO-5 modified glassy carbon electrodes ( GCEs) have been investigated by cyclic voltammetry( CV) and chronoamperometry ( CA) in differrent pH aqueous solutions. The results showed that the PS/CoSALEN/APO-5 /GC modified electrode is of the high electrocatalytic activity towards dioxygen reduction in pH 6. 86 buffer solution with a reduced overpotential of 447 mV lower than bare …
Failure Reaction Mechanism Of Internal Short-Circuit For Lithium-Ion Batteries, He Li, Shen-Jun Yu, Zhi-Kui Chen, Guang-Chuan Liang
Failure Reaction Mechanism Of Internal Short-Circuit For Lithium-Ion Batteries, He Li, Shen-Jun Yu, Zhi-Kui Chen, Guang-Chuan Liang
Journal of Electrochemistry
In this work,the battery impact testing machine has been used to study the failure progress of internal short-circuit ( ISC) for lithium ion batteries. The reaction mechanisms between cathode/anode and electrolyte in the battery at different temperatures were characterized by differential scanning calorimetry ( DSC) ,gas chromatography/mass spectrometry ( GC/MS) and X-ray diffraction ( XRD) . The experimental results show that the ISC failure of the battery was mainly due to the reaction between cathode Li0.5CoO2 and electrolyte. The decomposition and oxygen evolution reactions of cathode occurred when the temperature reached a certain value. At the same time a fierce …